General formula for bending beam determination of case II diffusion in polymer-containing bilayer structures

An exact formula has been presented to correlate the bending curvature cariation ratio, Ω, of any given bilayer structure comprising a solvent-swellable polymer layer with diffusion time, t, under case II diffusion. The formula can be used to determine the diffusion front velocity, v, for layered structures comprising a thick polymer film on a thin substrate or vice versa when subjected to solvent diffusion. According to this formula, there is little effect from plasticization or swelling in the transverse direction on the diffusion curve of Ω vs. t if the polymer layer to be investigated is relatively thin and its intrinsic hygroscopic strain ratio is less than unity. By using this model, the diffusion of N-methyl pyrollidinone (NMP) in a 18-μm rodlike pyromellitic dianhydride p-phenylene-diamine (PMDA-PDA) polymide film, coated on a 75-μm silicon substrate, is found to be case II with a diffusion front velocity of 1.84 × 10^-7 cm/s. © 1995 John Wiley & Sons, Inc.     

Synthesis of substituted poly (arylene vinylene) films by vapor deposition polymerization

Summary An efficient method for the synthesis of PPV based polymers, poly ( 2,5-dimethyl-1,4-phenylene vinylene) (DMe-PPV) and poly (2,5-dimethoxy-1,4-phenylene vinylene) (DOMe-PPV) were developed using 2,5-dimethyl-1,4-bis ( chloromethyl ) benzene and 2,5-dimethoxy 1,4-bis ( chloromethyl ) benzene via vapor phase pyrolysis and followed by vapor deposition polymerization. The structure of polymer films were confirmed by FT-IR, solid state NMR and elemental analysis. Thermal gravimetry analysis reveals that the precursor polymer films form a conjugated polymer after thermal conversion at 250°C. The optical and electrical properties of the polymer films were investigated by UV-Vis absorption and photoluminescence spectroscopies. Electroluminescent devices were fabricated using these polymers. Received: 18 May 2000/Revised version: 21 July 2000/Accepted: 28 July 2000     

Improving routing distance for geographic multicast with Fermat points in mobile ad hoc networks

In mobile ad hoc networks (MANETs), each node has the ability to transmit, receive, and route packets, and also moves through the field either randomly or in accordance with a pre-planned route. For enhancing the performance of MANETs, reducing the routing distance is a primary concern. For either ad hoc or static networks, the problem of minimizing the overall routing distance during multicasting is NP-complete. Therefore, it is difficult to determine an optimal solution. This paper presents an efficient geographic multicast protocol, designated as GMFP, based on the use of Fermat points. The objective of GMFP is to improve the overall routing distance for multicast tasks. Through a series of simulations, it is shown that GMFP outperforms the conventional Position-Based Multicast protocol and FERMA protocol in terms of the total routing distance, the packet transmission delay, the packet delivery ratio, and the node energy consumption. The performance improvements provided by GMFP are apparent as the scale of the network topology increases.     

空间红外探测用30 K单级脉管制冷机高能效研究

建立了阻抗匹配模型,同时从冷指及压缩机两方面对制冷机性能进行优化.基于热声理论,构建了30 K温区脉管冷指的一维Delta EC理论模型,优化了惯性管型单级脉管制冷机冷指和压缩机耦合的工作参数.从机理上分析了回热器填料、双段惯性管长度及气库体积对冷指声学阻抗及压缩机声功转化效率的耦合关系.搭建实验测试平台,测试结果表明此单级脉管制冷机可以获得24.24 K的最低温度,输入功227 W时可以在30 K获得1 W冷量,可较好的满足空间红外探测器应用.