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1.
Adya P. Singh Anni Ratz Bernard S. W. Dawson 《Journal of Coatings Technology and Research》2007,4(2):207-210
A new method was developed which enabled us to obtain high-resolution images of the distribution of an oil-borne stain in
a saw-textured plywood surface. The method involved treating 90 μm thick plywood sections, which had been cut transversely
through the wood-coating interface using a sliding microtome, with osmium tetroxide (OsO4) prior to examination with a field-emission scanning electron microscope (FE-SEM) operating in backscattered electron imaging
(BEI) mode. The combination of OsO4 staining and use of FE-SEM-BEI afforded excellent contrast differentiation between the coating and wood cell walls, revealing
coating penetration into even nano-size cell wall cracks and delaminations formed during band-sawing of the plywood. The novel
technique described adds a new dimension to probing wood–coating interface. 相似文献
2.
Topics in Catalysis - This Synthetic Gas Bench (SGB) study focuses on the effect of cell geometry and wall thickness on the gasoline NO x trap functionality. The data show that besides a NO x trap... 相似文献
3.
In this study, we explored how stereoscopic depth affects performance and user experience in a mobile device with an autostereoscopic touch display. Participants conducted a visual search task with an image gallery application on three layouts with different depth ranges. The task completion times were recorded, and the participants were asked to rate their experiences. The results revealed that the image search times were facilitated by a mild depth effect and that too great a depth slowed search times and decreased user-experience ratings. 相似文献
4.
Sassi Wafa Mrad Mouna Behera Debasis Ammar Salah Hihn Jean-Yves 《Journal of Applied Electrochemistry》2021,51(11):1591-1604
Journal of Applied Electrochemistry - The choice of the electroplating conditions of Ni-based alloys has always been a serious research question. In this study, an artificial neural network based... 相似文献
5.
Anni Mikkelsen Leif H. Skibsted 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1995,200(3):171-177
The pH dependence of iron(II)/iron(III) product distribution, following reduction of the hypervalent iron in equine ferrylmyoglobin by the protein moiety of the pigment (so-called autoreduction) and by NADH (nicotinamide adenine dinucleotide, reduced) and the rate of reduction was found to depend different on pH. Autoreduction is specific acid catalysed and has a more modest temperature dependence than autoxidation of oxymyoglobin, with the activation parameters H
#=58.5±0.4 kJ·mol–1 and S
#=2.7±0.1 J·mol–1·K–1 in 0.16 mol·1–1 NaCl. The product of autoreduction is the iron(III) pigment metmyoglobin, which is slightly modified in the protein moiety. The reaction has a positive kinetic salt effect from which it is deduced that the reactive centre of ferrylmyoglobin has a charge of +1 in agreement with the structure Fe(IV)=O. Reduction by NADH involves parallel reactions of two pigment forms in acid/base equilibrium with each other with a pK
a equal to 4.9, both forms yielding metmyoglobin as well as the iron(II) pigment, oxymyoglobin, as products. The protonated form reacts faster than the deprotonated form, and two-electron transfer has greater importance for the protonated form with a limiting Fe(II)/Fe(III) product ratio of 0.6 in acidic solution compared to 0.12 in alkaline solution. A square root dependence of rate on NADH concentration suggests involvement of NAD·radicals with a disproportionation as the termination reaction.
Säure-katalysierte Reduktion von Ferrylmyoglobin. Produktdistribution und Kinetik der Autoreduktion und Reduktion von NADH
Zusammenfassung Die Reaktionsgeschwindigkeit und das Eisen(II)/Eisen(III)-Verhältnis des Produkts nach Reduktion von hypervalentem Eisen in Ferrylmyoglobin aus Pferden zeigt eine unterschiedliche pH-Abhängigkeit der sogenannten Autoreduktion (Reduktion am Proteinteil des Pigments) sowie der Reduktion durch NADH. Die Autoreduktion weist eine spezifische Säure-Katalyse auf sowie eine moderate Temperaturabhängigkeit im Vergleich zur Autooxidation von Oxymyoglobin mit den Aktivierungsparametern H #=58.5±0.4 kJ·mol–1 und S #=2.7±0.1 J·mol–1·K–1 in 0.16 mol·1–1 NaCl. Das Produkt der Autoreduktion ist das Eisen(III)-Pigment Metmyoglobin mit leicht modifiziertem Proteinanteil. Die Reaktion hat einen positiv kinetischen Salzeffekt, woraus zu erschließen ist, daß das reaktive Zentrum im Ferrylmyoglobin die Ladung +1 übereinstimmend mit der Struktur Fe(IV)=O besitzt. Die Reduktion durch NADH weist auf parallele Reaktionen von zwei Pigmentformen in einem Säure/Base-Gleichgewicht mit pk a=4.9 hin, beide Formen ergeben Metmyoglobin sowie das Eisen(II)-Pigment Oxymyoglobin als Produkt. Die protonisierte Form reagiert schneller als die deprotonisierte Form, und eine zwei-Elektronenübertragung hat größere Bedeutung für die protonisierte Form mit einem Fe(II)/Fe(III) Produktverbrauch von 0.6 in der Säurelösung und 0.12 in der Baselösung. Die Quadratwurzel Abhängigkeit der Geschwindigkeit von NADH deutet auf eine Teilnahme von NAD-Radikalen mit Disproportionierung als Schlußreaktion.相似文献
6.
Lung cancer is one of the deadliest diseases in the world. Non‐small cell lung cancer (NSCLC) is the most common and dangerous type of lung cancer. Despite the fact that NSCLC is preventable and curable for some cases if diagnosed at early stages, the vast majority of patients are diagnosed very late. Furthermore, NSCLC usually recurs sometime after treatment. Therefore, it is of paramount importance to predict NSCLC recurrence, so that specific and suitable treatments can be sought. Nonetheless, conventional methods of predicting cancer recurrence rely solely on histopathology data and predictions are not reliable in many cases. The microarray gene expression (GE) technology provides a promising and reliable way to predict NSCLC recurrence by analysing the GE of sample cells. This study proposes a new model from GE programming to use microarray datasets for NSCLC recurrence prediction. To this end, the authors also propose a hybrid method to rank and select relevant prognostic genes that are related to NSCLC recurrence prediction. The proposed model was evaluated on real NSCLC microarray datasets and compared with other representational models. The results demonstrated the effectiveness of the proposed model.Inspec keywords: lung, cancer, lab‐on‐a‐chip, genetics, patient diagnosisOther keywords: NSCLC recurrence prediction, microarray data, GE programming, nonsmall cell lung cancer, cancer recurrence, histopathology data, microarray gene expression, prognostic genes 相似文献
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8.
对C/S和B/S结构体系进行了分析比较,然后提出了一种新的基于C/S和B/S的混合系统结构的管理信息系统运行模式。 相似文献
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