Nonlinear viscoelastic modeling of soft polymers

A one‐dimensional phenomenological constitutive model, representing the nonlinear viscoelastic behavior of polymers is developed in this study. The proposed model is based on a modification of the well‐known three element standard solid model. The linear dashpot is replaced by an Eyring type one, while the nonlinearity is enhanced by a nonlinear, strain dependent spring constant. The new constitutive model was proved to be capable of capturing the main aspects of nonlinear viscoelastic response, namely, monotonic and cyclic loading, creep and stress relaxation, with the same parameter values. Model validation was tested on the experimental results at various modes of deformation for two elastomeric type materials, performed elsewhere. A very good agreement between model simulations and experimental data was obtained in all cases. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42141.     

A Composite Index of Compliance for Chronic In‐Center Hemodialysis Patients

We developed a composite compliance index as the sum of the compliance scores for interdialytic weight gain (IDWG), pre‐dialysis serum potassium and phosphorus concentrations (each scored from zero to 3, with 3 indicating the poorest compliance), and skipping hemodialysis sessions (scored from zero to 9, with 9 indicating the poorest compliance). We used this composite score to prospectively evaluate compliance in 25 prevalent hemodialysis patients over a period of 1 year. We then followed these patients for another 3.5 years. The patients studied were divided into two groups: group A (poor compliance) consisted of 9 subjects with composite score ≥ 9 (13.2 ± 3.2); group B (better compliance) consisted of 16 subjects with composite score < 9 (4.7 ± 1.8). Age, duration of hemodialysis, and frequency of diabetes mellitus did not differ between the groups. Group A contained higher fractions of subjects with history of alcoholism (66.7% vs 12.5%, p = 0.010), other substance addiction (44.4% vs 0%, p = 0.010), and severe psychosocial problems (88.9% vs 18.8%, p = 0.002). Mean survival from the beginning of observation, estimated by actuarial life‐table survival analysis, was 1.19 years in group A and 2.60 years in group B (p = 0.0265). A composite compliance index incorporating domains indicating adherence to diet, medications, and dialysis schedule identified other behavioral problems in poorly compliant patients. Hemodialysis patients characterized by this composite index as poorly compliant had shortened survival.     

Criteria and methodology for the evaluation of conservation interventions on treated porous stone susceptible to salt decay

Susceptibility of stone to salt decay is directly related to its microstructural and mechanical characteristics. In the present work, a porous stone from a quarry in Cyprus was examined. Samples of this stone were consolidated and protected with certain conservation materials. The modification of microstructural characteristics of the stone was evaluated by mercury intrusion porosimetry, while its mechanical characteristics were measured by compressive and bending strength tests. From these data, the susceptibility of Cyprus stone to salt (NaCl) decay was estimated. The values of crystallization pressure of NaCl were calculated and compared to the experimentally measured compressive and tensile strength of the stone, in order to examine the probability of stone disruption due to salt crystallization. The development of the phenomenon after coarse pores’ filling with crystals, i.e. crystallization of salts in capillaries or mechanical failure of the stone, was determined by thermodynamic analysis. Additionally, artificial weathering tests of marine salt spray were performed for the evaluation of stone’s durability after the conservation. The treated stone proved to be resistant to salt decay, as it presented ameliorated microstructural and mechanical characteristics, concerning decay due to soluble salt crystallization. The most possible thermodynamic scenario was small pores repletion with crystals, avoiding mechanical failure of the stone.     

R-CURVE MODEL OF CERTAIN CERAMIC COMPOSITES

Abstract— The influence of crack-bridging on the R -curve for certain types of ceramic composites is modeled. Small scale bridging conditions are assumed. A recurrence procedure is used to solve the governing coupled integral equations, resulting in R -curves (stress intensity factor versus crack growth) that depend on well defined microstructural parameters. In addition, the bridging stresses and the crack opening diplacements were computed for all stages of the R -curve development. The numerical scheme is quite general and can be used for a variety of bridging laws. The convergence of the solution method is uniform, and the accuracy is a priori controlled. The results are normalized so that they can be applied for a large variety of composites with different micromechanical parameters. R -curves were computed for different bridiging laws, and were found to be sensitive to the specific bridging law used each time. Some strength-toughness relations are also discussed. The results are particularly suitable for slow crack growth analysis.     

Synergism of Toughening Mechanisms in Whisker-Reinforced Ceramic-Matrix Composites

The improved fracture resistance of whisker-reinforced ceramic-matrix composites involves more than one energy-absorbing mechanism. The possible mechanisms are reviewed and a micromechanical model evaluating the relative contributions to the overall toughness is presented. The mechanisms involve microcracking, load transfer, bridging, and crack deflection. The synergism of these mechanisms is examined using an energy release rate balance equation. The basic assumption of the proposed model is that the load transfer between the matrix and the whiskers is due to Coulomb friction. The model has been applied to an Al₂O₃/SiC whisker composite and shows reasonable agreement with reported experimental results. The role of the thermal residual stresses is also examined in light of the frictional load transfer assumption.     

Towards a consolidated model for a collaborative courseware authoring system

Abstract In an effort to reduce the expensive resource requirements in courseware production and to allow effective management of, and communication and collaboration between authors, a model is needed to harmonize the diverse theoretical backgrounds such a process requires. To this end we look at five abstract models which where chosen for their apparent appropriateness within the general area of collaborative authoring and reuse of multimedia courseware. These models consist of a functional model of hypertext, an infrastructure model for an open collaborative authoring system, two object-oriented communication models, and a courseware production model. We attempt a consolidation of these models and ultimately make several conclusions, which are exposed during a conceptual harmonisation. The principal conclusion is that a hypermedia logical model is not by itself adequate to support collaboration and reuse. Our modeling conclusions have driven the design of a system which will be implemented and tested.     

The Association of Human Herpesviruses with Malignant Brain Tumor Pathology and Therapy: Two Sides of a Coin

The role of certain viruses in malignant brain tumor development remains controversial. Experimental data demonstrate that human herpesviruses (HHVs), particularly cytomegalovirus (CMV), Epstein–Barr virus (EBV) and human herpes virus 6 (HHV-6), are implicated in brain tumor pathology, although their direct role has not yet been proven. CMV is present in most gliomas and medulloblastomas and is known to facilitate oncomodulation and/or immunomodulation, thus promoting cancer cell proliferation, invasion, apoptosis, angiogenesis, and immunosuppression. EBV and HHV-6 have also been detected in brain tumors and high-grade gliomas, showing high rates of expression and an inflammatory potential. On the other hand, due to the neurotropic nature of HHVs, novel studies have highlighted the engagement of such viruses in the development of new immunotherapeutic approaches in the context of oncolytic viral treatment and vaccine-based strategies against brain tumors. This review provides a comprehensive evaluation of recent scientific data concerning the emerging dual role of HHVs in malignant brain pathology, either as potential causative agents or as immunotherapeutic tools in the fight against these devastating diseases.     

Comparison of various modeling methods for analysis of powder compaction in roller press

Recently used models relating basic properties of the feed material, roller press design and its operating parameters are reviewed. In particular, we discuss the rolling theory for granular solids proposed by J.R. Johanson in the 1960s, later trials utilizing slab method and newly developed final element models. These methods are compared in terms of efficiency and accuracy of predicting the course of basic process variables like nip angle, pressure distribution in roll nip region, neutral angle, roll torque and roll force.

The finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions. This enables to perform realistic computer experiments minimizing costs, time and resources needed for process and equipment optimization.     

MILLING PERFORMANCE OF COATED INSERTS WITH VARIABLE COATING THICKNESS ON THEIR RAKE AND FLANK

During the Physical Vapour Deposition of coatings, the orientation of cemented carbides insert surfaces to the plasma flux direction affects the occurring film thickness distribution on the rake and flank, which in turn might influence the wear propagation in cutting processes. In the present paper the cutting performance in milling of PVD coated cemented carbides inserts with variable film thickness on the rake and flank is introduced and with the aid of FEM-supported calculations explained. The investigation results revealed that a thicker film on the tool rake in comparison to the existing one on the flank and moreover a thick and uniformly deposited film in the cutting wedge region significantly enhances the cutting performance in milling.     

Thickness control in structural optimization via a level set method

In the context of structural optimization via a level-set method we propose a framework to handle geometric constraints related to a notion of local thickness. The local thickness is calculated using the signed distance function to the shape. We formulate global constraints using integral functionals and compute their shape derivatives. We discuss different strategies and possible approximations to handle the geometric constraints. We implement our approach in two and three space dimensions for a model of linearized elasticity. As can be expected, the resulting optimized shapes are strongly dependent on the initial guesses and on the specific treatment of the constraints since, in particular, some topological changes may be prevented by those constraints.