Temperature adaptability of the soluble lead flow battery using different solutions of fluoborate,perchlorate, methanesulfonate and trifluoromethanesulfonate

The evaluation of cell's weatherability is of practical interest. To further improve the soluble lead flow battery's weatherability, physiochemical properties of electrolytes containing fluoborate, perchlorate, methanesulfonate and trifluoromethanesulfonate are investigated from ?60 to 50 °C. Activities of CF₃SO₃H and HClO₄ are poor in trifluoromethanesulfonate and perchlorate solutions due to common anion effect. The solubility of lead salt can be improved by increasing temperature, but worsened by increasing acid's content. With the temperature increasing, the conductivity is enhanced, and the viscosity is lowered for four solutions. The same results have been found by increasing acid's content except for CF₃SO₃H. The high energy efficiency can be achieved for cells over ?40–0 °C using fluoborate and perchlorate solutions, 73.2% at ?40 °C and 78.1% at ?30 °C respectively. Over the temperature range of 20–50 °C, the cells with methanesulfonate and trifluoromethanesulfonate solutions have good performance, 77.4% and 73.7% at 50 °C respectively.     

COIL中BHP浓度对发生O_2(~1△)的影响

本文实验研究了BHP的浓度对产生O2（1△）的影响。实验结果表明：当BHP浓度大于3.5M时，Cl2利用率以及O2（1△）的产率将不依赖于BHP浓度的变化而变化，同时，实验结果表明，使用低浓度的BHP对COIL的操作是可行的。     

Ce对共晶Mg-Al合金组织的影响

模拟AZ9l镁合金半固态液相凝固后期的成分，分析了共晶成分镁铝合金添加不同含量的稀土元素Ce后，铸态显微结构的变化。结果表明：Ce的加入改变了合金的组织，增加了初晶α相的含量，细化了β相并减少了β相的含量。随着稀土Ce加入量的增加，在Ce的加入量为0．6％时，所得的组织最好；在Ce含量大于0．6％时，随着Ce加入量的增加，细化效果反而变差。     

Na2SiO3—KOH—（NaPO3）6溶液中Ti6Al4V微弧氧化陶瓷膜研究

用非平衡交流微弧氧化法于Na2SiO3-KOH-(NaPO3)6溶液中在Ti6Al4V表面形成氧化物陶瓷膜。分别用扫描电镜、电子探针及X射线衍射研究了陶瓷膜的组织形貌、元素分布和相组成。相对致密均匀的膜层主要由TiO2(钙钛矿相及金红石相)及非晶相组成。厚约20μm的膜可分为3层：过渡层、致密层与疏松层。电解液所含元素Si，P进入到膜层中，表明电解液组元急烈参与微弧氧化反应，这为通过选择电解液来设计膜层的相组成进而对膜层进一步改性提供途径。     

面向非平衡数据集的金融欺诈账户检测研究

针对非平衡金融数据集,提出一种银行欺诈账户检测框架iForest-SMOTE。基于账户的动态交易特点,从统计、时序、监督信息维度抽取账户交易行为特征。针对过采样技术ADASYN在金融账户数据集中存在的跨区域样本合成问题,提出一种基于iForest算法的数据集均衡预处理策略,通过iForest算法对数据进行混合采样,在去除多数类噪声数据的同时降低分类器对少数类的学习难度。在此基础上,设计随机森林分类器实现金融欺诈账户检测。在真实金融账户交易数据集上进行实验,结果表明,与ADASYN、SMOTE等采样技术相比,iForest-SMOTE在召回率和准确率方面具有明显优势,F-value值至少能够提升2.13个百分点。     

面向统一数据源的企业信息编码体系设计与实现

企业统一数据源是企业数据表达、存储、交换的中心.信息编码是信息共享的基础,企业信息编码体系是企业统一数据源的基础,也是企业信息化的基础.本文从信息编码基础标准、编码规则、编码管理规范和计算机辅助编码管理系统4个方面描述了企业信息编码体系的构成,并结合企业实例构建了完整的企业信息编码体系.依据企业应用系统的集成需求,提出了基于信息编码的企业统一数据源应用模型.     

AZ91D合金SIMA形变组织与共晶熔化激活能的研究

研究了SIMA法制备半固态AZ91D镁合金坯料过程中形变率对形变组织的影响, 并采用DSC技术研究了形变率与共晶熔化激活能的关系.结果表明:随着形变率的增大,合金的原始组织由树枝晶演变为碎块晶,晶粒内存在位错、孪晶缺陷;合金的共晶熔化激活能随形变率的增大而变小,当形变率达到40%时,共晶熔化激活能下降很少;共晶熔化开始温度随形变率的增大略有下降.     

Input-to-state-stability modular command filtered back-stepping attitude control of a generic reentry vehicle

A command filtered back-stepping attitude controller is exploited and analyzed to design a dynamic state-feedback controller for a generic Reentry Vehicle. A novel back-stepping control that obviates the need to compute analytic derivatives in the traditional back-stepping design is presented by combining command filtered back-stepping method, sliding-mode-based integral filters and inputto-state stability (ISS) analysis. The ISS-modular approach provides a simple and effective way for controlling non-linear Reentry Vehicle satisfying the strict-feedback form, simultaneously solving the problem of “explosion of complexity” in traditional back-stepping approach. The stability analysis of the closed-loop system and the convergence of the aerodynamic angles are verified based on the smallgain theorem. Numerical simulations are included to demonstrate the effectiveness of the proposed control scheme.     

双闭环真空硅微陀螺仪设计及测试性能分析

所设计的硅微陀螺仪工作在10 Pa,品质因素达到3000,采用CAN金属壳封装形式,测控线路采用闭环自激驱动,力反馈式闭环检测方式.驱动采用单边驱动单边检测,尽量使线路简化;检测采用双重分解和重构回路.测试结果表明:有用信号和正交信号实现很好的相位解耦,互不影响.在实现标度因素10 mY/(°)S-1的情况下,零偏稳定性已达到了60°/h;线性度已达到了400 ppm;带宽仿真达到150 Hz;这较以前设计的空气下闭驱开检方式下的硅微陀螺性能提高了近2个数量级.     

Ultra-Stable and Sensitive Ultraviolet Photodetectors Based on Monocrystalline Perovskite Thin Films

The detection of ultraviolet (UV) radiation with effective performance and robust stability is essential to practical applications. Metal halide single-crystal perovskites (ABX₃) are promising next-generation materials for UV detection. The device performance of all-inorganic CsPbCl₃ photodetectors (PDs) is still limited by inner imperfection of crystals grown in solution. Here wafer-scale single-crystal CsPbCl₃ thin films are successfully grown by vapor-phase epitaxy method, and the as-constructed PDs under UV light illumination exhibit an ultralow dark current of 7.18 pA, ultrahigh ON/OFF ratio of ≈5.22 × 10⁵, competitive responsivity of 32.8 A W⁻¹, external quantum efficiency of 10867% and specific detectivity of 4.22 × 10¹² Jones. More importantly, they feature superb long-term stability toward moisture and oxygen within twenty-one months, good temperature tolerances at low and high temperatures. The ability of the photodetector arrays for excellent UV light imaging is further demonstrated.