Inverted Solution Processable OLEDs Using a Metal Oxide as an Electron Injection Contact.

A new type of bottom‐emission electroluminescent device is described in which a metal oxide is used as the electron‐injecting contact. The preparation of such a device is simple. It consists of the deposition of a thin layer of a metal oxide on top of an indium tin oxide covered glass substrate, followed by the solution processing of the light‐emitting layer and subsequently the deposition of a high‐workfunction (air‐stable) metal anode. This architecture allows for a low‐cost electroluminescent device because no rigorous encapsulation is required. Electroluminescence with a high brightness reaching 5700 cd m^–2 is observed at voltages as low as 8 V, demonstrating the potential of this new approach to organic light‐emitting diode (OLED) devices. Unfortunately the device efficiency is rather low because of the high current density flowing through the device. We show that the device only operates after the insertion of an additional hole‐injection layer in between the light‐emitting polymer (LEP) and the metal anode. A simple model that explains the experimental results and provides avenues for further optimization of these devices is described. It is based on the idea that the barrier for electron injection is lowered by the formation of a space–charge field over the metal‐oxide–LEP interface due to the build up of holes in the LEP layer close to this interface.     

Synthesis of silicon carbide whiskers using the vapour-liquid-solid mechanism in a silicon-rich droplet

SiC whiskers can be produced from 1350–1500 °C by carbothermal reduction of the silica in a fixed bed percolated by a hydrogen flow. At 1450 °C and above, the addition of iron to the silica-carbon mixture leads to the formation of submicrometre whiskers in the bed, ending with a silicon-rich droplet. The iron has evaporated and condensed at a lower temperature, a few centimetres downstream from the bed, allowing the formation of silicon carbide whiskers ending with an iron droplet according to the vapour-liquid-solid (VLS) mechanism. Submicrometre whiskers are also obtained without iron over a broader range of temperatures. Silicon carbide whisker production in a fixed bed is then possible using a (VLS) mechanism in a silicon-rich droplet and may be controlled without the addition of transition metals, thus improving the purity.Supported by Pechiney Electrometallurgie and the European Communities, Brite project RIIB.A267C.     

Surface Pretreatments of Silicon Nitride for CVD Diamond Deposition

The efficiency of different surface pretreatments (four standard chemical etchings and four diamond powder abrasive procedures) on silicon nitride (Si₃N₄) substrates for chemical vapor deposition (CVD) of diamond has been systematically investigated. Blank Si₃N₄ samples were polished with colloidal silica (∼0.25 μm). Diamond nucleation and growth runs were conducted in a microwave plasma chemical vapor deposition apparatus for 10 min and 6 h, respectively. Superior results concerning nucleation density ( N _d∼ 10¹⁰ cm⁻² after 10 min), film uniformity, and grain size (below 2 μm after 6 h) were obtained for the mechanically microflawed samples, revealing that chemical etchings (hot and cold strong acids, molten base or CF₄ plasma) are not crucial for good CVD diamond quality on Si₃N₄.     

Detecting Fixed Patterns in Chordal Graphs in Polynomial Time

The Contractibility problem takes as input two graphs G and H, and the task is to decide whether H can be obtained from G by a sequence of edge contractions. The Induced Minor and Induced Topological Minor problems are similar, but the first allows both edge contractions and vertex deletions, whereas the latter allows only vertex deletions and vertex dissolutions. All three problems are NP-complete, even for certain fixed graphs H. We show that these problems can be solved in polynomial time for every fixed H when the input graph G is chordal. Our results can be considered tight, since these problems are known to be W[1]-hard on chordal graphs when parameterized by the size of H. To solve Contractibility and Induced Minor, we define and use a generalization of the classic Disjoint Paths problem, where we require the vertices of each of the k paths to be chosen from a specified set. We prove that this variant is NP-complete even when k=2, but that it is polynomial-time solvable on chordal graphs for every fixed k. Our algorithm for Induced Topological Minor is based on another generalization of Disjoint Paths called Induced Disjoint Paths, where the vertices from different paths may no longer be adjacent. We show that this problem, which is known to be NP-complete when k=2, can be solved in polynomial time on chordal graphs even when k is part of the input. Our results fit into the general framework of graph containment problems, where the aim is to decide whether a graph can be modified into another graph by a sequence of specified graph operations. Allowing combinations of the four well-known operations edge deletion, edge contraction, vertex deletion, and vertex dissolution results in the following ten containment relations: (induced) minor, (induced) topological minor, (induced) subgraph, (induced) spanning subgraph, dissolution, and contraction. Our results, combined with existing results, settle the complexity of each of the ten corresponding containment problems on chordal graphs.     

A fuzzy optimization model for planning integrated terrestrial carbon management networks

Clean Technologies and Environmental Policy - Biochar application and enhanced weathering are negative emission technologies (NETs) with the potential for large-scale deployment for the removal of...     

Ligand‐Free Synthesis of Aluminum‐Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color‐Tuned Highly Efficient Organic Solar Cells

The color of polymer solar cells using an opaque electrode is given by the reflected light, which depends on the composition and thickness of each layer of the device. Metal‐oxide‐based optical spacers are intensively studied in polymer solar cells aiming to optimize the light absorption. However, the low conductivity of materials such as ZnO and TiO₂ limits the thickness of such optical spacers to tenths of nanometers. A novel synthesis route of cluster‐free Al‐doped ZnO (AZO) nanocrystals (NCs) is presented for solution processing of highly conductive layers without the need of temperature annealing, including thick optical spacers on top of polymer blends. The processing of 80 nm thick optical spacers based on AZO nanocrystal solutions on top of 200 nm thick polymer blend layer is demonstrated leading to improved photocurrent density of 17% compared to solar cells using standard active layers of 90 nm in combination with thin ZnO‐based optical spacers. These AZO NCs also open new opportunities for the processing of high‐efficiency color tuned solar cells. For the first time, it is shown that applying solution‐processed thick optical spacer with polymer blends of different thicknesses can process solar cells of similar efficiency over 7% but of different colors.     

A non-conventional approach for crack problems in piezoelectric media under electromechanical loading

In this paper the elastostatic solution of an inclined crack problem has been analyzed. The approach is analogous to the one proposed over the past years for orthotropic materials by Piva andViola (1988) (Eng Fract Mech, 29: 535–548), and it may be considered an alternative to the mathematical formalisms currently used. A general expression of the stress field is determined in terms of complex potentials. The stress distribution and the displacement field in the proximity of the crack tip are finally obtained. An expression of the energy release rate is provided in terms of the field intensity factors. Numerical results are presented and discussed under different remote electro-mechanical loading conditions and varying the crack inclination. Particular attention has been focused on the effect of the lateral load on the fracture quantities and on the direction of the incipient branching angle.     

Interdisciplinary safety analysis of complex socio-technological systems based on the functional resonance accident model: An application to railway trafficsupervision

This paper presents an application of functional resonance accident models (FRAM) for the safety analysis of complex socio-technological systems, i.e. systems which include not only technological, but also human and organizational components. The supervision of certain industrial domains provides a good example of such systems, because although more and more actions for piloting installations are now automatized, there always remains a decision level (at least in the management of degraded modes) involving human behavior and organizations. The field of application of the study presented here is railway traffic supervision, using modern automatic train supervision (ATS) systems. Examples taken from railway traffic supervision illustrate the principal advantage of FRAM in comparison to classical safety analysis models, i.e. their ability to take into account technical as well as human and organizational aspects within a single model, thus allowing a true multidisciplinary cooperation between specialists from the different domains involved.A FRAM analysis is used to interpret experimental results obtained from a real ATS system linked to a railway simulator that places operators (experimental subjects) in simulated situations involving incidents. The first results show a significant dispersion in performances among different operators when detecting incidents. Some subsequent work in progress aims to make these “performance conditions” more homogeneous, mainly by ergonomic modifications. It is clear that the current human-machine interface (HMI) in ATS systems (a legacy of past technologies that used LED displays) has reached its limits and needs to be improved, for example, by highlighting the most pertinent information for a given situation (and, conversely, by removing irrelevant information likely to distract operators).     

Heterodyne lidar returns in the turbulent atmosphere: performance evaluation of simulated systems

Simulations of beam propagation in three-dimensional random media were used to study the effects of atmospheric refractive turbulence on coherent lidar performance. By use of the two-beam model, the lidar return is expressed in terms of the overlap integral of the transmitter and the virtual (backpropagated) local oscillator beams at the target, reducing the problem to one of computing irradiance along the two propagation paths. This approach provides the tools for analyzing laser radar with general refractive turbulence conditions, beam truncation at the antenna aperture, beam-angle misalignment, and arbitrary transmitter and receiver configurations. Simplifying assumptions used in analytical studies, were tested and treated as benchmarks for determining the accuracy of the simulations. The simulation permitted characterization of the effect on lidar performance of the analytically intractable return variance that results from turbulent fluctuations as well as of the heterodyne optical power and system-antenna efficiency.     

Optical Frequency Metrology of an Iodine-Stabilized He-Ne Laser Using the Frequency Comb of a Quantum-Interference-Stabilized Mode-Locked Laser

We perform optical frequency metrology of an iodine-stabilized He-Ne laser using a mode-locked Ti:sapphire laser frequency comb that is stabilized using quantum interference of photocurrents in a semiconductor. Using this technique, we demonstrate carrier-envelope offset frequency fluctuations of less than 5 mHz using a 1 s gate time. With the resulting stable frequency comb, we measure the optical frequency of the iodine transition [¹²⁷I₂ R(127) 11-5 i component] to be 473 612 214 712.96 ± 0.66 kHz, well within the uncertainty of the CIPM recommended value. The stability of the quantum interference technique is high enough such that it does not limit the measurements.