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1.
The spectrum of the light emitted at 10 200 Å by an NO laser is photographed with high resolution. The rotational analysis fully confirms the assignment made earlier to the transitionF^{2}Delta-C^{2}Pi (1, 1) between two electronically excited levels of the NO molecule, both of which are configurationally mixed with valence levels. 相似文献
2.
Arnold M. Bass H. P. Broida 《Journal of research of the National Institute of Standards and Technology》1963,(4):379-388
Reactions involving reactive species produced in electric discharges are frequently characterized by the emission of visible light of many different colors. Some typical afterglows and atomic flames have been photographed, and the observed colors (or spectral distributions) are discussed with regard to the reactions from which they arise. Laboratory studies of this sort are helpful for the understanding of the energy transfer processes which occur in flames, in electrical discharges, and in the upper atmosphere. 相似文献
3.
Four experiments with 113 C57BL/6J and 80 DBA/2J female mice showed that pregnant DBA/2J Ss built significantly larger and more completely enclosed nests than did pregnant C57BL/6J Ss. This strain difference was restricted to the last half of gestation and was not observed during either the virgin state or lactation. Genotype-based differences in pregnancy-induced nest building were not related to circulating levels of progesterone (P), core temperature, or body weight. Exposure to supplemental P (100, 200, or 400 μg, sc) during pregnancy elevated nest building exhibited by pregnant C57BL Ss but did not induce DBA-like levels of the behavior. Also, virgin DBA Ss built larger nests in response to P than did C57BL Ss. Findings suggest that differences in the sensitivity of central neural tissue to steroid hormones may account for genotypically determined variation in patterns of pregnancy-induced nest building. (27 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
4.
H Broida 《Canadian Metallurgical Quarterly》1977,58(6):248-253
This report describes the results of language therapy initiated 1 to 6 years after the onset of aphasia in 14 patients. During the course of treatment, each of the 14 patients improved strongly in their communicative abilities (PICA), according to clinical observation and reports from family, hospital ward personnel, or both. 相似文献
5.
Broida T.J. Chellappa R. 《IEEE transactions on pattern analysis and machine intelligence》1991,13(6):497-513
The problem considered involves the use of a sequence of noisy monocular images of a three-dimensional moving object to estimate both its structure and kinematics. The object is assumed to be rigid, and its motion is assumed to be smooth. A set of object match points is assumed to be available, consisting of fixed features on the object, the image plane coordinates of which have been extracted from successive images in the sequence. Structure is defined as the 3-D positions of these object feature points, relative to each other. Rotational motion occurs about the origin of an object-centered coordinate system, while translational motion is that of the origin of this coordinate system. In this work, which is a continuation of the research done by the authors and reported previously (ibid., vol.PAMI-8, p.90-9, Jan. 1986), results of an experiment with real imagery are presented, involving estimation of 28 unknown translational, rotational, and structural parameters, based on 12 images with seven feature points 相似文献
6.
Stanley Abramowitz H. P. Broida 《Journal of research of the National Institute of Standards and Technology》1964,(3):331-333
Infrared absorption spectra of CO in the region of the first overtone have been observed in dilute (approximately 1 to 10 parts in 1000) liquid solutions of oxygen, nitrogen, and argon, and clear crystalline nitrogen and argon matrices. The overtone band was found at 4249.0, 4252.4, and 4252.0 cm−1 with half widths of 18.4, 17.8, and 13.7 cm−1 in liquid oxygen, nitrogen, and argon solutions at 82, 78, and 82 °K, respectively. The half width in liquid oxygen varied from 18.4 to 10.0 cm−1 in the temperature range 82 to 57 °K. The band position was the same but its width was smaller in the crystalline nitrogen matrix. Two bands were observed in the clear crystalline argon solid at 4245 and 4256 cm−1. The solution results cannot be interpreted with the recent theory of Buckingham.Infrared absorption spectra of carbon monoxide in the region of the first overtone have been observed in the liquid solvents oxygen, nitrogen, and argon. In addition, the spectra have been obtained in clear crystalline solutions of argon and of nitrogen near the triple points of these solvents. The purpose of these experiments was to determine the influence of temperature, phase changes, and solvents on half width, position, and shape of the CO absorption band.A Perkin-Elmer model 99 monochromator with a 2000 lines/cm grating blazed at 10° (1.7μ in first order) was used in the first order with a spectral slit width of about 1 cm−1. An antireflection coated germanium filter eliminated the higher orders from the 1000 w tungsten filament lamp used as the light source. The quartz absorption cell used, recently described by Bass and Broida [1], was modified slightly by recessing the windows further into the coolant tube. The resultant increased thermal contact between the refrigerant and the solution greatly simplified the growing of the clear crystalline matrices. The temperature of the refrigerant, liquid oxygen, was regulated by pumping on it with a small vacuum pump (capacity 14 liters/min). The vapor pressure of the liquid oxygen refrigerant, measured with an aneroid type gauge, provided an indication of the temperature. The direct measurement of the vapor pressure above the solution with a mercury manometer also provided an indication of the temperature. Solutions were prepared from the gases which had been mixed in the ratios of 1 to 10 parts carbon monoxide to 1000 parts of the various solvents. The position, the half width, and the shape of the spectral band did not depend on the concentration in this range. The clear solid solutions were grown slowly from the liquids at or near the triple points of the solvents.The measured frequencies and half widths of the 0–2 transition of CO in condensed oxygen, nitrogen, and argon are summarized in 2]). There were no changes in the position or the shape of the band in liquid oxygen at temperatures from 57 to 82 °K. However the half-band width varied from 10.0 to 18.4 cm−1 in this temperature range. In liquid argon the band is slightly asymmetric with more absorption on the high-frequency side.
Open in a separate windowAlthough the position of the band in clear crystalline solid nitrogen is not greatly different from that of the corresponding liquid solution, the half width is reduced by one-third and the shape is asymmetric and broader on the high-frequency side in the solid matrix. The absorption in the wings of the band is less than one would expect for a Lorentzian band shape. This observation is in apparent agreement with Wieder and Dows [3] who recently have observed vibrational bands of solid C2H4 and C2D4 which had shapes between the Gaussian and Lorentzian forms. In clear crystalline argon, the band is split into two overlapping peaks with the high-frequency peak about 50 percent more intense than the other peak.Results for the band positions obtained in this study are in good agreement with the recently published results of Vu, Atwood, and Vodar [4]. The band contours which are shown by them appear quite similar to the ones observed in this study but half widths were not listed, so that a further comparison of our results with theirs is not possible. These workers did not study the influence of temperature on the spectrum.In an effort to find an explanation for the observations of the 0–2 band of CO in condensed phases, several theoretical models have been tried. Unfortunately none of these theories easily account for the band shapes and shifts.Ewing [5] has observed the CO fundamental vibration in the liquid phase, in nitrogen and argon solutions. The bands he observed were not only asymmetric but also broader than the 0–2 bands observed in this study. The carbon monoxide fundamental had half widths of 26 cm−1 and 18 cm−1 in liquid nitrogen and argon, respectively, at temperatures comparable to those in this study. Ewing ascribed the asymmetry and increased absorption to the high-frequency side of the bands to a low barrier to rotation. From the asymmetry he estimated the barrier to be 42 cm–1 in pure liquid carbon monoxide, while slightly lower and slightly higher barriers were estimated for carbon monoxide solutions in liquid nitrogen and argon, respectively. A comparison with the present results (6, 7]. The observed dependence is clearly a function of a higher power of the temperature.If hindered rotation is responsible for the band width, then an increase in half-band width and asymmetry to the high-frequency side of the band is to be expected with a rise in temperature if the barrier is comparable to kT. If the barrier is much higher than kT the band width is independent of temperature. Since the population of the J levels of a rotator is proportional to T1/2, one would expect the width of the band to vary roughly as T1/2 if free or hindered rotation is causing the observed breadth. The observed dependence of approximately T3/2 coupled with the lack of asymmetry seems to rule out this explanation for CO in oxygen.It has recently been suggested by Rakov in application to organic materials that the width of bands could be represented by an exponential of the form
Δv1/2 = A exp (?E/RT)(1)where E is the potential barrier for reorientation of the molecules [8, 9]. Rakov lias further indicated that if Brownian motion is responsible for the observed band widths this E should be equivalent to the energy of viscous flow, Evis, which is defined by Glasstone, Laidler, and Eyring [10] through the relationship
η = B exp (Ev is/RT)(2)where η is the viscosity of the liquid medium. Using the data in eq (1). This value of E is about a factor of two smaller than the Evis calculated for liquid oxygen in this temperature range from the available data on the viscosity of liquid oxygen [11]. It appears therefore that this theory does not fit the phenomena observed in this study.Recently Buckingham [12, 13, 14] presented a theory to account for solvent effects on vibrational transitions of diatomic molecules. One of the unique predictions of this theory is that the (s—1) overtone of a diatomic molecule should be s times as broad as the fundamental. The half widths observed in this study of the first overtone of carbon monoxide are decidedly smaller than the widths of the fundamental in these same solvent systems observed by Ewing [5]. This indicates the failure of Buckingham’s theory in predicting band widths for the simple system carbon monoxide in nitrogen and argon solutions. The solvent shifts (vvap —vsol’n) observed for the carbon monoxide harmonic in nitrogen is 7.6 cm−1, which is about 2.5 times the solvent shift of 3 cm−1 for the fundamental observed by Ewing. Buckingham’s theory as well as the earlier theory of Kirkwood, Bauer, and Magat [15, 16] predicts that the solvent shift of the harmonic should be twice that of the fundamental.In conclusion, the first overtone of carbon monoxide has been observed in condensed phases of oxygen, nitrogen, and argon. Both the shape and half width are significantly changed in the transition of liquid solution to solid solution, while the band position is not appreciably altered in the phase change. (Changes were not observed for the methane-argon system [17].) The recent theory of Buckingham as well as the earlier theory ascribed to Kirkwood, Bauer, and Magat have been found not to apply to these systems. No explanation is apparent for the two overlapping bands observed for carbon monoxide in the clear crystalline argon solid. The explanation of Vu et al. [4] implies that a combination band involving the fundamental band and a lattice mode is more intense than the respective fundamental. This explanation is not consistent with the observation of one band for the vibration of methane in a clear crystalline argon solid [17]. The variation of the half width of the 0–2 band of CO in liquid oxygen in the temperature range of 57 to 82 °K cannot be readily explained with existing theories. 相似文献
Table 1
The 0–2 transition of CO in condensed oxygen, nitrogen and argonSolvent | Phase | T | v | Δp½ |
---|---|---|---|---|
|
|
|
|
|
°K | cm−1 | cm−1 | ||
gas | 300 | 4260. 0 | ||
O2 | liq | 57 | 4249.0 ±0.5 | 10.0 ±0.5 |
O2 | liq | 82 | 4249. 0 ±0. 5 | 18.4 ±0.5 |
N2 | liq | 78 | 4252. 4 ±0. 5 | 17.8 ±0.5 |
Ar | liq | 82 | 4252.0 ±0.5 | 13. 7 ±0. 5 |
N2 | solid | 62 | 4252. 0 ±0. 5 | 12.3 ±0.5 |
Ar | solid | 67 | 25.0 ±2.0 |
7.
Estimation of object motion parameters from noisy images 总被引:2,自引:0,他引:2
Broida TJ Chellappa R 《IEEE transactions on pattern analysis and machine intelligence》1986,(1):90-99
An approach is presented for the estimation of object motion parameters based on a sequence of noisy images. The problem considered is that of a rigid body undergoing unknown rotational and translational motion. The measurement data consists of a sequence of noisy image coordinates of two or more object correspondence points. By modeling the object dynamics as a function of time, estimates of the model parameters (including motion parameters) can be extracted from the data using recursive and/or batch techniques. This permits a desired degree of smoothing to be achieved through the use of an arbitrarily large number of images. Some assumptions regarding object structure are presently made. Results are presented for a recursive estimation procedure: the case considered here is that of a sequence of one dimensional images of a two dimensional object. Thus, the object moves in one transverse dimension, and in depth, preserving the fundamental ambiguity of the central projection image model (loss of depth information). An iterated extended Kalman filter is used for the recursive solution. Noise levels of 5-10 percent of the object image size are used. Approximate Cramer-Rao lower bounds are derived for the model parameter estimates as a function of object trajectory and noise level. This approach may be of use in situations where it is difficult to resolve large numbers of object match points, but relatively long sequences of images (10 to 20 or more) are available. 相似文献
8.
Charlotte E. Moore Herbert P. Broida 《Journal of research of the National Institute of Standards and Technology》1959,(1):19-53
CH lines in the solar spectrum have been identified by direct comparison of measured laboratory and solar wavelengths and intensities. The comparisons of individual rotational lines are included in a series of tables arranged according to electronic and vibrational transitions.A detailed investigation of the presence of CH lines in the solar spectrum has been carried out recently as part of the preparation of a current edition of solar spectrum data to replace the 1928 compendium [1].1 Along with the study of atomic lines, a parallel survey of molecules in the sun is required for any complete revision of the “Solar Spectrum.” A preliminary résumé of the number of CH, OH, and CN lines in the solar spectrum was recently published [2].Many lines of CH are familiar features in the solar spectrum. In his original table, Rowland [3] attributed some of these lines to “C,” and numerous CH lines were included in the 1928 edition [1]. Several authors have carried the work further. For example, Hunaerts [4] and Richardson [5] have each published a list of solar lines which may be ascribed to CH.The present results are based on a study of the rotational structure of individual bands, together with relative laboratory intensities measured along the different branches. It reveals more CH lines in the sun than have been recognized heretofore. A summary of the counts is included in 2] they referred to solar lines. Consequently, if two CH lines contribute to one solar line, each CH line is counted here as a blend. Exception has been made in the case of Table No. Laboratory
Sun
Electronic transition Vibrational transition Wavelength range A Total number lines References Strongest solar int. Δλ/λ Summary of counts
Present Blend Masked Absent Total
2 A 2Δ–X 2Π 0, 0 4133 to 4413 309 6 39.6 155 92 46 16 309 3 1, 1 4185 to 4446 235 6 24.3 70 68 72 15 225 4 2, 2 4238 to 4468 188 6 26.6 54 36 61 8 159 5 0, 1 4726 to 4941 198 7 0.6 5 3 14 9 31 6 1, 2 4741 to 4913 149 7 0 0
Total 1,079 284 199 193 48 724 7 B 2Σ−— X 2Π 0, 0 3871 to 4084 106 6 49.4 43 41 20 2 106 8 1, 0 3627 to 3710 54 6 13 18 10 22 4 54 9 1, 1 4025 to 4119 50 6 7.6 16 11 22 1 50
Total 210 Rowl. est. 77 62 64 7 210 10 C 2Σ+—X 2Π 0, 0 3086 to 3219 119± 8 [2] 31 41 18 6 96 11 1, 1 3119 to 3222 50 8 [0] 8 13 24 5 50
Total 169± 39 54 42 11 146