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1
1.
The spectrum of the light emitted at 10 200 Å by an NO laser is photographed with high resolution. The rotational analysis fully confirms the assignment made earlier to the transitionF^{2}Delta-C^{2}Pi(1, 1) between two electronically excited levels of the NO molecule, both of which are configurationally mixed with valence levels.  相似文献   
2.
Reactions involving reactive species produced in electric discharges are frequently characterized by the emission of visible light of many different colors. Some typical afterglows and atomic flames have been photographed, and the observed colors (or spectral distributions) are discussed with regard to the reactions from which they arise. Laboratory studies of this sort are helpful for the understanding of the energy transfer processes which occur in flames, in electrical discharges, and in the upper atmosphere.  相似文献   
3.
Four experiments with 113 C57BL/6J and 80 DBA/2J female mice showed that pregnant DBA/2J Ss built significantly larger and more completely enclosed nests than did pregnant C57BL/6J Ss. This strain difference was restricted to the last half of gestation and was not observed during either the virgin state or lactation. Genotype-based differences in pregnancy-induced nest building were not related to circulating levels of progesterone (P), core temperature, or body weight. Exposure to supplemental P (100, 200, or 400 μg, sc) during pregnancy elevated nest building exhibited by pregnant C57BL Ss but did not induce DBA-like levels of the behavior. Also, virgin DBA Ss built larger nests in response to P than did C57BL Ss. Findings suggest that differences in the sensitivity of central neural tissue to steroid hormones may account for genotypically determined variation in patterns of pregnancy-induced nest building. (27 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
4.
This report describes the results of language therapy initiated 1 to 6 years after the onset of aphasia in 14 patients. During the course of treatment, each of the 14 patients improved strongly in their communicative abilities (PICA), according to clinical observation and reports from family, hospital ward personnel, or both.  相似文献   
5.
The problem considered involves the use of a sequence of noisy monocular images of a three-dimensional moving object to estimate both its structure and kinematics. The object is assumed to be rigid, and its motion is assumed to be smooth. A set of object match points is assumed to be available, consisting of fixed features on the object, the image plane coordinates of which have been extracted from successive images in the sequence. Structure is defined as the 3-D positions of these object feature points, relative to each other. Rotational motion occurs about the origin of an object-centered coordinate system, while translational motion is that of the origin of this coordinate system. In this work, which is a continuation of the research done by the authors and reported previously (ibid., vol.PAMI-8, p.90-9, Jan. 1986), results of an experiment with real imagery are presented, involving estimation of 28 unknown translational, rotational, and structural parameters, based on 12 images with seven feature points  相似文献   
6.
Infrared absorption spectra of CO in the region of the first overtone have been observed in dilute (approximately 1 to 10 parts in 1000) liquid solutions of oxygen, nitrogen, and argon, and clear crystalline nitrogen and argon matrices. The overtone band was found at 4249.0, 4252.4, and 4252.0 cm−1 with half widths of 18.4, 17.8, and 13.7 cm−1 in liquid oxygen, nitrogen, and argon solutions at 82, 78, and 82 °K, respectively. The half width in liquid oxygen varied from 18.4 to 10.0 cm−1 in the temperature range 82 to 57 °K. The band position was the same but its width was smaller in the crystalline nitrogen matrix. Two bands were observed in the clear crystalline argon solid at 4245 and 4256 cm−1. The solution results cannot be interpreted with the recent theory of Buckingham.Infrared absorption spectra of carbon monoxide in the region of the first overtone have been observed in the liquid solvents oxygen, nitrogen, and argon. In addition, the spectra have been obtained in clear crystalline solutions of argon and of nitrogen near the triple points of these solvents. The purpose of these experiments was to determine the influence of temperature, phase changes, and solvents on half width, position, and shape of the CO absorption band.A Perkin-Elmer model 99 monochromator with a 2000 lines/cm grating blazed at 10° (1.7μ in first order) was used in the first order with a spectral slit width of about 1 cm−1. An antireflection coated germanium filter eliminated the higher orders from the 1000 w tungsten filament lamp used as the light source. The quartz absorption cell used, recently described by Bass and Broida [1], was modified slightly by recessing the windows further into the coolant tube. The resultant increased thermal contact between the refrigerant and the solution greatly simplified the growing of the clear crystalline matrices. The temperature of the refrigerant, liquid oxygen, was regulated by pumping on it with a small vacuum pump (capacity 14 liters/min). The vapor pressure of the liquid oxygen refrigerant, measured with an aneroid type gauge, provided an indication of the temperature. The direct measurement of the vapor pressure above the solution with a mercury manometer also provided an indication of the temperature. Solutions were prepared from the gases which had been mixed in the ratios of 1 to 10 parts carbon monoxide to 1000 parts of the various solvents. The position, the half width, and the shape of the spectral band did not depend on the concentration in this range. The clear solid solutions were grown slowly from the liquids at or near the triple points of the solvents.The measured frequencies and half widths of the 0–2 transition of CO in condensed oxygen, nitrogen, and argon are summarized in 2]). There were no changes in the position or the shape of the band in liquid oxygen at temperatures from 57 to 82 °K. However the half-band width varied from 10.0 to 18.4 cm−1 in this temperature range. In liquid argon the band is slightly asymmetric with more absorption on the high-frequency side.

Table 1

The 0–2 transition of CO in condensed oxygen, nitrogen and argon
SolventPhaseTvΔp½





°Kcm−1cm−1
gas3004260. 0
O2liq574249.0 ±0.510.0 ±0.5
O2liq824249. 0 ±0. 518.4 ±0.5
N2liq784252. 4 ±0. 517.8 ±0.5
Arliq824252.0 ±0.513. 7 ±0. 5
N2solid624252. 0 ±0. 512.3 ±0.5
Arsolid67 [4245.0±1.04256.0±1.0]25.0 ±2.0
Open in a separate windowAlthough the position of the band in clear crystalline solid nitrogen is not greatly different from that of the corresponding liquid solution, the half width is reduced by one-third and the shape is asymmetric and broader on the high-frequency side in the solid matrix. The absorption in the wings of the band is less than one would expect for a Lorentzian band shape. This observation is in apparent agreement with Wieder and Dows [3] who recently have observed vibrational bands of solid C2H4 and C2D4 which had shapes between the Gaussian and Lorentzian forms. In clear crystalline argon, the band is split into two overlapping peaks with the high-frequency peak about 50 percent more intense than the other peak.Results for the band positions obtained in this study are in good agreement with the recently published results of Vu, Atwood, and Vodar [4]. The band contours which are shown by them appear quite similar to the ones observed in this study but half widths were not listed, so that a further comparison of our results with theirs is not possible. These workers did not study the influence of temperature on the spectrum.In an effort to find an explanation for the observations of the 0–2 band of CO in condensed phases, several theoretical models have been tried. Unfortunately none of these theories easily account for the band shapes and shifts.Ewing [5] has observed the CO fundamental vibration in the liquid phase, in nitrogen and argon solutions. The bands he observed were not only asymmetric but also broader than the 0–2 bands observed in this study. The carbon monoxide fundamental had half widths of 26 cm−1 and 18 cm−1 in liquid nitrogen and argon, respectively, at temperatures comparable to those in this study. Ewing ascribed the asymmetry and increased absorption to the high-frequency side of the bands to a low barrier to rotation. From the asymmetry he estimated the barrier to be 42 cm–1 in pure liquid carbon monoxide, while slightly lower and slightly higher barriers were estimated for carbon monoxide solutions in liquid nitrogen and argon, respectively. A comparison with the present results (6, 7]. The observed dependence is clearly a function of a higher power of the temperature.If hindered rotation is responsible for the band width, then an increase in half-band width and asymmetry to the high-frequency side of the band is to be expected with a rise in temperature if the barrier is comparable to kT. If the barrier is much higher than kT the band width is independent of temperature. Since the population of the J levels of a rotator is proportional to T1/2, one would expect the width of the band to vary roughly as T1/2 if free or hindered rotation is causing the observed breadth. The observed dependence of approximately T3/2 coupled with the lack of asymmetry seems to rule out this explanation for CO in oxygen.It has recently been suggested by Rakov in application to organic materials that the width of bands could be represented by an exponential of the form Δv1/2A exp (?E/RT)(1)where E is the potential barrier for reorientation of the molecules [8, 9]. Rakov lias further indicated that if Brownian motion is responsible for the observed band widths this E should be equivalent to the energy of viscous flow, Evis, which is defined by Glasstone, Laidler, and Eyring [10] through the relationship ηB exp (Ev is/RT)(2)where η is the viscosity of the liquid medium. Using the data in eq (1). This value of E is about a factor of two smaller than the Evis calculated for liquid oxygen in this temperature range from the available data on the viscosity of liquid oxygen [11]. It appears therefore that this theory does not fit the phenomena observed in this study.Recently Buckingham [12, 13, 14] presented a theory to account for solvent effects on vibrational transitions of diatomic molecules. One of the unique predictions of this theory is that the (s—1) overtone of a diatomic molecule should be s times as broad as the fundamental. The half widths observed in this study of the first overtone of carbon monoxide are decidedly smaller than the widths of the fundamental in these same solvent systems observed by Ewing [5]. This indicates the failure of Buckingham’s theory in predicting band widths for the simple system carbon monoxide in nitrogen and argon solutions. The solvent shifts (vvapvsol’n) observed for the carbon monoxide harmonic in nitrogen is 7.6 cm−1, which is about 2.5 times the solvent shift of 3 cm−1 for the fundamental observed by Ewing. Buckingham’s theory as well as the earlier theory of Kirkwood, Bauer, and Magat [15, 16] predicts that the solvent shift of the harmonic should be twice that of the fundamental.In conclusion, the first overtone of carbon monoxide has been observed in condensed phases of oxygen, nitrogen, and argon. Both the shape and half width are significantly changed in the transition of liquid solution to solid solution, while the band position is not appreciably altered in the phase change. (Changes were not observed for the methane-argon system [17].) The recent theory of Buckingham as well as the earlier theory ascribed to Kirkwood, Bauer, and Magat have been found not to apply to these systems. No explanation is apparent for the two overlapping bands observed for carbon monoxide in the clear crystalline argon solid. The explanation of Vu et al. [4] implies that a combination band involving the fundamental band and a lattice mode is more intense than the respective fundamental. This explanation is not consistent with the observation of one band for the vibration of methane in a clear crystalline argon solid [17]. The variation of the half width of the 0–2 band of CO in liquid oxygen in the temperature range of 57 to 82 °K cannot be readily explained with existing theories.  相似文献   
7.
Estimation of object motion parameters from noisy images   总被引:2,自引:0,他引:2  
An approach is presented for the estimation of object motion parameters based on a sequence of noisy images. The problem considered is that of a rigid body undergoing unknown rotational and translational motion. The measurement data consists of a sequence of noisy image coordinates of two or more object correspondence points. By modeling the object dynamics as a function of time, estimates of the model parameters (including motion parameters) can be extracted from the data using recursive and/or batch techniques. This permits a desired degree of smoothing to be achieved through the use of an arbitrarily large number of images. Some assumptions regarding object structure are presently made. Results are presented for a recursive estimation procedure: the case considered here is that of a sequence of one dimensional images of a two dimensional object. Thus, the object moves in one transverse dimension, and in depth, preserving the fundamental ambiguity of the central projection image model (loss of depth information). An iterated extended Kalman filter is used for the recursive solution. Noise levels of 5-10 percent of the object image size are used. Approximate Cramer-Rao lower bounds are derived for the model parameter estimates as a function of object trajectory and noise level. This approach may be of use in situations where it is difficult to resolve large numbers of object match points, but relatively long sequences of images (10 to 20 or more) are available.  相似文献   
8.
CH lines in the solar spectrum have been identified by direct comparison of measured laboratory and solar wavelengths and intensities. The comparisons of individual rotational lines are included in a series of tables arranged according to electronic and vibrational transitions.A detailed investigation of the presence of CH lines in the solar spectrum has been carried out recently as part of the preparation of a current edition of solar spectrum data to replace the 1928 compendium [1].1 Along with the study of atomic lines, a parallel survey of molecules in the sun is required for any complete revision of the “Solar Spectrum.” A preliminary résumé of the number of CH, OH, and CN lines in the solar spectrum was recently published [2].Many lines of CH are familiar features in the solar spectrum. In his original table, Rowland [3] attributed some of these lines to “C,” and numerous CH lines were included in the 1928 edition [1]. Several authors have carried the work further. For example, Hunaerts [4] and Richardson [5] have each published a list of solar lines which may be ascribed to CH.The present results are based on a study of the rotational structure of individual bands, together with relative laboratory intensities measured along the different branches. It reveals more CH lines in the sun than have been recognized heretofore. A summary of the counts is included in 2] they referred to solar lines. Consequently, if two CH lines contribute to one solar line, each CH line is counted here as a blend. Exception has been made in the case of
Table No.Laboratory
Sun
Electronic transitionVibrational transitionWavelength range ATotal number linesReferencesStrongest solar int. Δλ/λSummary of counts
PresentBlendMaskedAbsentTotal

  2A 2Δ–X 2Π0, 04133 to 4413309639.6155924616309
  31, 14185 to 4446235624.370687215225
  42, 24238 to 4468188626.65436618159
  50, 14726 to 494119870.65314931
  61, 24741 to 4913149700

Total1,07928419919348724
  7B 2Σ— X 2Π0, 03871 to 4084106649.44341202106
  81, 03627 to 371054613181022454
  91, 14025 to 41195067.6161122150

Total210Rowl. est.7762647210
10C 2Σ+—X 2Π0, 03086 to 3219119±8[2]314118696
111, 13119 to 3222508[0]81324550

Total169±39544211146
Open in a separate window

Table 5

CH in the Solar Spectrum A 2Δ—X 2Π (0, 1)
LaboratorySun

Q1cQ1dQ2cQ2dR1cdR1dcR2cdR2dcIntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
1616221150.364726.734
1616221141.134728.797
15321098.504738.351
15321098.304738.396
1515321090.294740.196
14321047.634749.804
14321047.184749.906
1414421040.28*4751.463
13320998.064761.118
13320997.21*4761.219
13320991.334762.545
13320991.074762.602
24220952.79*4771.305
12420948.904772.189
12420948.054772.384
12420943.284773.470
12420942.984773.538
24120931.954776.054
23220914.78*4779.975
23220912.79*4780.429
11420901.204783.081
11420900.284783.292
2311420896.394784.181
2311420895.804784.317
22120878.044788.386
22220876.514788.737
2222120860.864792.330
10420854.804793.724
10420853.604793.999
10420850.714794.663
10420849.844794.862
21120842.574796.536
21120841.934796.684
2121120827.314800.050
9420809.644804.164
20209620808.154804.472
9420806.184804.925
9420805.124805.171
20220795.314807.437
20220794.704807.578
1919320775.594812.001
8520765.81*4814.267
8620764.24*4814.630
19220763.514814.800
198720763.02*4814.913
8620761.64*4815.233
1818420743.874819.359
18220733.144821.853
18220732.674821.962
7520723.414824.117
77720721.434824.577
7520719.614825.001
1717420713.574826.409
17320703.794828.687
17320703.314828.800
16320684.764833.131
16320684.564833.177
6420682.624833.630
6520681.024834.004
6620680.254834.185
6520678.884834.505
1616520675.54*4835.285
15420657.224839.573
15420656.754839.684
1515520648.924841.520
5520643.444842.804
5520642.364843.058
5520640.664843.457
5520639.684843.686
14520631.094845.704
14620630.61*4845.817
1414620623.714847.438
13620606.45*4851.499
134720605.894851.630
4620605.36*4851.755
4520602.474852.435
4520601.784852.598
1313620599.914853.038
12520583.504856.908
12620582.64*4857.110
12620577.874858.236
12620577.424858.343
3420570.664859.939
3420570.134860.065
120566.394860.949
3620565.744861.103
3620565.434861.176
11520562.104861.963
11620561.044862.213
11620557.264863.107
11620556.644863.255
10620542.324866.644
10620541.104866.932
10620538.264867.606
1022820537.454867.7994867.87411.5u+ 0.075Co iM
220531.584869.190
22720530.444869.4604869.4694.1u+ 0.009Fe iM
9620524.304870.9164870.940.8+ 0.02Ni iM
9620522.844871.263A
9620520.914871.7214871.6833.1−0.038A
9620519.814871.9824871.9359.2u−0.047Fe i pM
11520515.744872.950A
8620508.014874.7864874.7934.3w?+ 0.007Ni iM
8620506.314875.1904875.1980.6+ 0.008CH?P
8620505.264875.4394875.4928.4S+ 0.053V iM
8620503.874875.7714875.7390.7−0.032Fe i pM
320497.984877.172
11720496.23*4877.5894877.5904.3u+ 0.001Fe iM
7620493.484878.2434878.22524.2w−0.018Fe iM
77920491.434878.7304878.7210.6−0.009CHP
7G20489.564879.1754879.1500.4−0.025CH?P
6520480.80*4881.2624881.2670.4+ 0.005CH?P
6620479.27*4881.627A
6G20478.34*4881.849A
6720476.93*4882.1854882.14813.9u−0.037Fe iM
5520470.054883.826A
5520468.834884.117A
120468.244884.258
5620467.004884.5554884.5984.3o+ 0.043Cr iiM
5720465.984884.7984884.8031.5+ 0.005CH?—B
4520461.264885.9244885.9502.4s+ 0.026Cr iM
4620460.464886.1164886.0860.2−0.030CH?P
120459.834886.266
120458.124886.674
4720457.36*4886.8564886.8450.6s−0.011V i—CH?B
4620456.67*4887.0214887.00912.9s−0.012‖Cr i Ni iM
3420454.604887.5144887.5331.0+ 0.019M
3420454.114887.631A
120453.374887.808
22320450.574888.477
3620449.344888.768A
3620449.014888.8504888.8291.5−0.021—CH?B
120444.504889.930
22420442.89*4890.315
3220367.914908.318
3220367.114908.510
120366.174908.737
120365.414908.919
3220361.984909.746
3220361.464909.871
4120345.304913.773
4120344.314914.011
120343.194914.283
4220340.944914.827
4220340.234914.997
5220325.134918.650
5220323.984918.927
220323.264919.101
5320321.824919.451
5320320.854919.686
6220307.324922.963
6220305.764923.342
6220304.634923.614
6320303.264923.948
22120301.044924.487
22120299.584924.839
7420291.614926.775
77520289.454927.299
7420287.514927.770
21220285.934928.154
22220285.354928.294
2221220284.554928.489
8420277.974930.088
8420276.174930.526
8420275.204930.762
82020520273.674931.134
21120272.334931.460
21120271.164931.744
9420266.414932.901
9420264.884933.273
19919520263.124933.702
9420261.844934.013
20220260.694934.294
20220260.044934.453
10320256.944935.206
10320255.704935.509
1818320254.614935.773
10320252.964936.176
10420251.994936.412
19320251.354936.569
19320250.774936.710
11320249.644936.986
11420248.494937.265
1717320248.074937.369
11320244.804938.166
11, 1812420244.164938.321
121816520243.384938.511
16320242.974938.613
13320241.034939.085
15320240.554939.202
13, 15420240.224939.282
14320239.854939.373
14320239.264939.518
12320238.704939.654
12, 1717420238.134939.792
13320234.424940.700
13, 1616520234.214940.750
14, 1514, 15520232.344941.208
Open in a separate window*Blend.Satellite lines as follows:
DesignationJLaboratory
Wave No.Wavelength

RQ 2c 1d; RQ2d 1c3; 320566.394860.949
RQ 2c 1d; RQ2d 1c2; 220531.584869.190
RQ 2c 1d; RQ2d 1c1; 120497.984877.172
QR 1 2d520468.244884.258
QR 1 2d420460.464886.116
QR 1 2d420459.834886.266
QP 1 2d420458.124886.674
QP 1 2d420457.364886.856
QR 1 2c; QR 1 2d3; 320453.374887.808
QP 2 1c; QP 2 1d3; 320450.574888.477
QR 1 2c; QR 1 2d2; 220449.014888.850
QP 2 1c; QP 2 1d2; 220444.504889.930
PQ 1d 2c320366.174908.737
PQ 1c 2d320365.414908.919
PQ 1c 2d420343.194914.283
PQ 1c 2d520323.264919.101
Open in a separate window

Table 10

CH in the Solar Spectrum C 2Σ+—X 2Π (0, 0)
LaboratorySun

P1P2Q1Q2R1R2IntensityWave number cm−1Wavelength AWavelength ADisk int. Rowl. est.⊙—lab. ASolar identificationNotes
26  0.232388.473086.6223086.636[−1]+0.014M
26  0.232387.243086.7393086.787[ 4]+0.048Co iA
25    0.2532384.233087.0273086.988[−2]−0.039M
25    0.2532383.113087.133A
24    0.3532377.113087.7053087.693[−1]−0.012M
24    0.3532376.033087.8093087.843[ 0Nd?]+0.034Co i—Cr ii?M
23  0.532367.583088.6153088.610[−1]−0.005M
23  0.532366.423088.7253088.752[ 2]+0.027M
22132355.733089.7463089.745[ 2]−0.001OHM
22132354.533089.8603089.868[ 2]+0.008OHM
21  1.532341.553091.1003091.071[ 4]−0.029Mg iM
21232340.553091.1963091.213[ 1N]+0.017CH OH‖B
20232325.753092.6123092.598[−3]−0.014CH OHB
20  2.532324.783092.7043092.712[ 4]+0.008Al iM
19  2.532308.243094.2883094.295[ 1]+0.007CH—B
19  3.532307.553094.3543094.364[−1]+0.010CHP
18} 5 {32289.1432288.603096.119}3096.138[ 2] {+0.0190.031} OH Cr iiM
183096.169
17} 6 {32268.9232268.353098.0583098.072[ 0]+0.014CHP
173098.113A
16} 8 {32247.4732247.153100.119}3100.150[−1N] {+0.031+0.001} CH CH
163100.149
151510  32224.583102.3213102.299[ 3]−0.022CH—V iiB
141411  32201.353104.5593104.571[ 2N]+0.012CH—Ti ii?B
131313  32177.153106.8943106.907[ 1]+0.013CHP
121214  32152.073109.3183109.333[ 3]+0.015OH CHB
1111    14.532126.563111.7863111.814[ 2]+0.028Fe i CHB
10} 13.5 {32100.3832100.053114.3243114.316[ 2]−0.008Fe ii CHB
103114.3563114.353[ 1]−0.003CHP
9} 13.5 {32073.6732073.163116.9193116.917[ 0]−0.002CHP
983116.9683116.982[ 1]+0.014CHP
932046.633119.5483119.504[ 3]−0.044Fe iM
879  32045.49*3119.6593119.678[ 1]+0.019OH CH Cr iB
9  32019.32*3122.2093122.219[ 0]+0.010OH CHB
7932018.183122.3203122.317[ 1]−0.003Fe i CHB
611  31991.553124.9203124.918[ 2]−0.002CH OHB
611    31990.06*3125.0653125.053[ 2]−0.012Cr ii—CHB
5931963.713127.6413127.671[ 2d?]+0.030|OH CH Ti i?B
5931961.623127.8463127.846[ 1]0.000CHP
4731935.883130.3673130.415[ 1]+0.048Be iiM
4731933.063130.5433130.567[ 1]+0.024|OH Fe iiM
3531908.033133.0993133.066[ 1]−0.033‖Fe ii—Sc iiM
3531904.233133.4723133.491[ 0]+0.019Zr iiM
2  2.531880.743135.781A
2331874.923136.3543136.345[−1]−0.009CHP
1331844.933139.3083139.306[ 0]−0.002CHP
1616} 90 {31802.9531802.831802.7531802.631802.3531802.23143.452} 3143.486 {+0.034+0.020+0.0150.0010.0250.040} V ii CHM
153143.466
153143.471
1717  3143.487[ 2N]B
143143.511
143143.526
13} 77 {31801.7531801.6531801.453143.570} 3143.575 {+0.0050.0050.025CH
1818  3143.580[ 1N]B
133143.600
12} 61 {31801.0531800.531800.331800.253143.640A
123143.694A
1919  3143.714} 3143.764 {+0.050+0.0450.0190.039}M
113143.719
11} 51 {31799.631799.43143.783[ 4]‖Ti ii CH—OHB
103143.803
10} 55 {31798.631798.53143.88} 3143.896 {+0.02+0.010.03CH Cr ii
93143.89[ 0]B
2020  } 57 {31798.131797.631797.53143.93
831,43.98} 3143.996[ 2] {+0.02+0.01CH Fe iB
93143.99
7} 55 {31796.731796.431796.031795.93144.07A
83144.10}3144.116 {+0.020.020.03CH
63144.14[ 0]B
23144.15A
75} 74 {31795.331795.131795.03144.21} 3144.236 {+0.03+0.010.00CH
2121  3144.23[ 0]B
4, 33144.24
636  31794.13144.333144.326[ 0]0.00  CH OH|B
525  31793.03144.443144.453[ 1]+0.01  CH Cr iB
422  31792.03144.533144.501[ 1]−0.03  Fe i CHB
3, 222226  31790.933144.6403144.629[ 0]−0.011CHP
216  31789.783144.7543144.737[ 1]−0.017Ti ii V ii—Fe ii|M
1831788.133144.9173144.925[ 1+0.008CH Fe iB
2323631786.063145.1223145.091[ 3]−0.031|Fe i—Cr ii (CH)M
24} 4 {31779.5931779.12 {3145.7633145.8093145.791[ 1] {+0.0280.018Cr ii? CH—CHB
24
25} 3 {31771.4831770.96 {3146.5663146.6173146.598[ 1] {+0.0320.019CH—CH OHB
25
26231761.53 {3147.5513147.6093147.599[ 1] {+0.0480.010Fe i—CHB
26231760.95
1431759.343147.7683147.784[ 1]+0.016Fe iM
27131749.883148.706A
27131749.323148.7623148.797[ 0N]+0.035M
2531738.483149.8373149.852[ 2]+0.015OHM
2631732.623150.4193150.417[−1]−0.002CHP
3631709.123152.7543152.737[ 1Nd?]−0.017Co i—CHB
3631705.163153.1483153.191[ 3]+0.043|Fe i OHM
4731680.543155.5983155.622[ 0]+0.024CHP
4731677.603155.8913155.905[ 0]+0.014CHP
514    31652.28*3158.4163158.403[ 1]−0.013CHP
511  31650.113158.6323158.633[ 0]+0.001CHP
610  31624.453161.1953161.204[ 3]+0.009Ti iiM
G13    31622.73*3161.3673161.382[ 1]+0.015Fe i CHB
712  31596.933163.9493163.930[ 1]−0.019Cr ii—CHB
713  31595.593164.0833164.068[ 0]−0.015CHP
812  31569.753166.6733166.674[ 1]+0.001CH Fe iiB
813  31568.733166.7753166.767[ 0]−0.008CHP
914  31542.823169.3763169.366[ 1]−0.010CHP
915  31542.223169.4383169.427[ 1]−0.011CHP
10} 18 {31516.2731515.923172.0473172.051[ 3] {+0.004+0.005‖Fe i Cr ii (CH)M
103172.0823172.087[ 4]
111120  31489.893174.7043174.697[ 2]−0.007CHP
121218  31464.033177.3133177.302[ 2]−0.001Co i—CHB
131319  31438.333179.9113179.901[ 0]−0.010CHP
141417  31412.943182.4813182.471[ 2]−0.010CHP
151515  31387.763185.0343185.022[ 1N]−0.012CHP
16}11 {31363.0031362.71 {3187.5493187.5783187.556[ 0Nd?] {+0.0070.022CH—CHB
16
17} 10 {31338.2531337.823190.0663190.042[ 1]−0.024Fe i—CHB
173190.1103190.104[ 1]−0.006CHP
18} 8 {31313.6531313.073192.5733192.534[−1]−0.039—CH?B
183192.6323192.617[−1]−0.015CHP
19631289.073195.0803195.085[ 0]+0.005CH OHB
19731288.283195.1613195.140[−1]−0.021Ru ii CHB
20431264.333197.6093197.596[−1]−0.013Y ii?—CHB
208  31263.44*3197.7003197.710[ 1N]+0.010CHP
21331239.603200.1403200.137[−1]−0.003CHP
21431238.633200.2403200.295[ 2Nd?]+0.055Y iiM
22331214.623202.7013202.695[ 0]−0.006CH OHB
22431213.573202.8093202.822[ 0]−0.013CHP
231.531189.123205.3203205.333[−1]+0.013CHP
23231188.043205.4313205.408[ 2]−0.023Fe i—CHB
24131163.393207.9673207.989[ 0]+0.022CH—B
24  1.531162.113208.0983208.094[ 0]−0.004CHP
25131136.683210.7193210.724[−1]+0.005CH OHB
25131135.453210.8453210.836[ 2]−0.009Fe iM
26131108.983213.5773213.564[−2]−0.013Ti ii Fe iM
26131107.643213.7163213.694[−1]−0.022M
27131080.423216.5303216.546[ 0]+0.016Cr iiM
27131079.033216.6743216.694[ 1]+0.020Y iiM
28  0.531050.363219.645A
28131049.003219.7863219.805[ 3]+0.019Fe iM
Open in a separate window*Blend.The individual rotational bands are described in to11.11. Data on the laboratory analyses are given on the left hand side of each table, and the solar data are entered on the right. In LaboratorySun
Q1cQ1dQ2cQ2dR1dcR1cdR2dcR2cdIntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes351   24184.33  4133.743  4133.7221.7−0.021  CH? CN?B342   24182.46  4134.063  A341.524181.09  4134.297  4134.34720.3s+ 0.050  Fe iM332   24175.90  4135.185  4135.1731.5−0.012  CH?P332   24174.40  4135.441  4135.4584.6uN+ 0.017  CH?—CN?B322.524165.49  4136.966  4137.00525.1u+ 0.039  Fe iM322   24163.75  4137.264  4137.27411.6s+ 0.010  Ti iM313.524151.56  4139.352  4139.3713.4+ 0.019  CHP313   24150.15  4139.594  4139.6103.4+ 0.016  CHP304   24134.77  4142.232  A304   24133.31  4142.482  4142.47411.6u−0.008  Cr iM297   24115.36  4145.566  4145.5597.7w−0.007  —CHB296   24113.94  4145.810  A287.524093.65  4149.301  4149.37026.8u+ 0.069  Fe iM287   24092.32  4149.530  4149.5382.9+ 0.008  CHP27} 4    {24091.2924090.63  4149.708  4149.6991.0−0.009  CHP274149.821  A2711   24069.93  4153.390  4153.3898.7ud?−0.001  CH Fe iB279.524068.63  4153.614  4153.6205.8s+ 0.006  CH—B26} 12    {24064.6524064.24  4154.301  4154.2874.8u−0.014  CHP264154.372  4154.3797.0+ 0.007  CHP2614   24044.50  4157.783  4157.78830.5u+ 0.005  Fe iM2613   24043.24  4158.001  4158.0077.0+ 0.006  CHP2522    {24036.4524036.15  4159.175  4159.18626.7w+ 0.011  (CH)M254159.227  4159.2400.6+ 0.013  CHP2517   24017.48  4162.460  4162.4607.0o?0.000  |CH—CN?B2516   24016.32  4162.661  4162.6608.2u−0.001  CH—CN?B24} 32    {24007.0324006.79  4164.272  4164.2638.9u−0.009  CN Fe i p—CHB244164.314  4164.3307.9u+ 0.016  CN CHB2421   23989.16  4167.374  4167.4005.8+ 0.026  CHP2420   23988.04  4167.569  4167.57113.2u+ 0.002  CHP23} 44    {23976.3923976.15  4169.594  } 4169.61512.9ud? {+0.0210.021  } CH—CHB234169.636  2327   23959.62  4172.513  4172.48212.0u−0.031  CHP2326   23958.65  4172.682  4172.64425.4u*−0.038  Fe iM222258   23944.63*4175.125  4175.13015.8wN+ 0.005  CH—CNB2236   23929.08  4177.838  4177.84911.5wN+ 0.011  |CH—CNB2233   23928.19  4177.994  4177.9992.4+ 0.005  CHP212173   23912.18*4180.791  4180.81119.1+ 0.020  CHP2142   23897.65  4183.333  4183.3268.6u−0.007  Ti i—CHB2140   23896.84  4183.475  4183.45718.6u−0.018  |V ii—CHB202092   23878.86*4186.625  4186.62222.7uN−0.003  Ce ii—CH iB2058   23865.52  4188.965  4188.97817.2+ 0.013  Ni i—CHB2050   23864.77  4189.096  4189.10211.0+ 0.006  CHP1919108   23845.01*4192.568  4192.57215.7u+ 0.004  CHP1970   23832.66  4194.741  4194.73610.5uN−0.005  CN—CHB1967   23831.96*4194.864  4194.84815.5u−0.016  CHP1818128   23810.55*4198.636  4198.63830.5u+ 0.002  CH—Fe iB1890   23799.25  4200.629  4200.60113.3−0.028  CHP1890   23798.74  4200.719  4200.7007.1u?−0.019  CHP1717136   23775.85*4204.764  4204.75316.4−0.011  CHP17} 114    {23765.4823765.15  4206.599  4206.57810.5u−0.021  CHP174206.657  4206.70230.0s+ 0.045  |Fe i CHB1616142   23740.66*4210.997  4210.96723.7−0.030  CHP16} 146    {23731.4323731.18  4212.634  } 4212.64222.1uN {+0.0080.037  } CH–CHB164212.679  15} 142    {23705.7423705.45  4217.200  4217.21414.0+ 0.014  CHP154217.251  4217.26814.0+ 0.017  CHP1515188   23697.18*4218.723  4218.72518.5+ 0.002  CHP14} 136    {23670.4823669.97  4223.482  4223.48613.5+ 0.004  CHP144223.573  4223.57415.9+ 0.001  CHP1414192   23662.79*4224.854  4224.86022.7+ 0.006  CH Cr iiB13124   23635.22  4229.782  4229.77427.2s−0.008  Fe i (CH)M13120   23634.53  4229.906  4229.91416.3+ 0.008  CHP1313197   23628.33*4231.016  4231.02622.4u+ 0.010  Ni i (CH)M12128   23599.94  4236.106  4236.12212.0+ 0.016  CHP12130   23599.14  4236.249  4236.26323.8+ 0.014  CHP12} 182    {23594.0723593.74  4237.160  4237.18228.8u+ 0.022  Fe i CHB124237.219  4237.25414.2s?+ 0.035  CHP11142   23564.69*4242.443  4242.45520.0+ 0.012  CHP11132   23563.71  4242.619  4242.60420.5u−0.015  Fe i—CHB11154   23559.70  4243.341  4243.36535.6u+ 0.024  CH—Fe iB11156   23559.04  4243.460  4243.45416.3u?−0.006  CHP10132   23529.79  4248.736  4248.72619.1−0.010  CHP10140   23528.63  4248.945  4248.94416.5−0.001  CHP10144   23525.58  4249.497  4249.49414.6−0.003  CHP10160   23524.74*4249.648  4249.63723.0ud−0.011  —CHB9136   23495.17*4254.996  4254.97927.0ud−0.017  Fe i—CHB9144   23493.76  4255.252  4255.25116.9−0.001  CHP9136   23491.66  4255.632  4255.63716.0+ 0.005  CHP9140   23490.58  4255.828  4255.83919.5s+ 0.011  CH—Fe iB8136   23460.81  4261.228  4261.22316.0−0.005  CHP8156   23459.13  4261.533  4261.53116.4w−0.002  CHP8140   23458.02  4261.734  4261.73815.7wd?+ 0.004  CHP8154   23456.59  4261.995  4261.97814.5−0.017  CHP319   23437.17  4265.526  4265.5424.7w+ 0.016  CH—B318   23436.50  4265.648  4265.6795.9s+ 0.031  Ti iM3016? 23431.23  4266.607  4266.6234.7w?+ 0.016  CHP3030? 23430.54*4266.733  4266.74210.3+ 0.009  CHP7134   23426.93  4267.391  4267.38914.1−0.002  CHP7} 270    {23424.91*23424.68  4267.759  4267.74913.1uN−0.010  CHP74267.801  4267.82726.7u+ 0.026  |Fe i CHB297168   23422.97*4268.112  4268.11217.80.000  CHP28M   23415.01  4269.563  4269.5857.2u+ 0.022  CHP28M   23414.29  4269.694  4269.74017.8u+ 0.046  M277? 23405.14  4271.363  4271.37416.2u+ 0.011  CHP276? 23404.63  4271.456  4271.46010.3+ 0.004  CHP2612? 23394.50  4273.306  4273.33221.5u+ 0.026  |Fe ii Ti i (CH)M266138   23393.53*4273.483  4273.48514.3+ 0.002  CHP6152   23391.87  4273.786  4273.79714.0+ 0.011  CHP6166   23391.10  4273.927  4273.94214.0ud*+ 0.015  CHP6152   23389.65  4274.192  4274.19315.2+ 0.001  CHP27(CH)23383.88*4275.247  4275.25815.0+ 0.011  CHM25(CH)23383.17*4275.377  4275.38624.3+ 0.009  CHM2725M   23382.70*4275.463  A2628   23374.27  4277.005  4276.9959.8sd−0.010  V i—CHB2625   23373.07  4277.224  4277.2338.6+ 0.009  CH—B24} 71    {23371.4923371.24   {4277.5134277.559  4277.53516.8ud {+0.0220.024  CH—CHB242536   23364.18  4278.852  4278.85310.8u+ 0.001  |CH—Ce ii?B2535   23363.01  4279.066  4279.0679.1ud+ 0.001  CH Mo iiB5130   23360.76  4279.478  4279.49014.7u+ 0.012  Fe i CHB23235220   23359.51*4279.707  4279.72021.7+ 0.013  CHP5174   23357.76*4280.028  4280.03715.0wd?+ 0.009  CHP5159   23356.73  4280.217  4280.22016.4w+ 0.003  CH Fe iB2456   23353.65*4280.781  4280.78813.7+ 0.007  Sm ii CHB2460? 23352.70*4280.956  4280.96411.4+ 0.008  CHP2222112   23347.15*4281.974  4281.97217.7−0.002  CHP2360   23342.69  4282.792  4282.79613.1w+ 0.004  CHP2356   23341.68  4282.977  4283.01431.0s+ 0.037  Ca iM2121142   23334.86*4284.228  4284.22820.1w0.000  |CHCr iiB2270   23331.56  4284.835  4284.83711.2+ 0.002  CHP2280   23330.64  4285.003  4285.00817.5s+ 0.005  CH Ti i|B4150   23328.63*4285.373  4285.3717.9−0.002  CHP4120   23327.79  4285.527  4285.53815.4+ 0.011  CHP4180   23324.82  4286.073  4286.0906.8+ 0.017  CHP4156   23324.15  4286.196  4286.19614.50.000  CHP2020238   43322.56*2286.488  4286.47726.6uN−0.011  Fe i—CHB2180? 23320.37  4286.891  4286.88413.8u−0.007  Fe i (CH)M2180? 22319.57  4287.038  4287.0516.5u?+ 0.013  CHP1919204   23310.40*4288.724  4288.73617.5+ 0.012  CHP20110   23309.13  4288.958  4288.96217.2u+ 0.004  |Fe i CHB2094   23308.46  4289.081  4289.08017.0s−0.001  Ti i (CH)M1818310   23298.36*4290.941  4290.95631.9s+ 0.015  Ti i (CH)M19} 300    {23298.0023297.42*23296.85*4291.007  4291.01910.2+ 0.012  CHP1934291.113  4291.12126.1u+ 0.008  CHP34291.219  4291.22014.2u+ 0.001  CH Ti iB8   23293.17*4291.897  A3} 260    {23292.36*23291.96  4292.046  4292.05512.3+ 0.009  CHP34292.119  4292.12922.1u?+ 0.010  CH—Fe iB18} 400    {23287.0723286.63*4293.021  4293.03615.1+ 0.015  CHP1718174293.102  4293.11420.5+ 0.012  CHP1717} 240    {23276.2923276.04  4295.009 4295.055  } 4295.04023.0 {+0.0310.015  } CH—CHB16} 260    {23275.3323275.07  4295.186  } 4295.22624.9 {+0.0400.008  } CH—CHB164295.234  2} 200    {23267.5823267.37  4296.617  4296.58424.4w−0.033  Fe ii (CH)M24296.656  4296.68313.3sN+ 0.027  CH—B1616280   23265.75*4296.955  4296.95625.6+ 0.001  CHP15} 250    {23264.3423263.96*4297.215  4297.21922.3+ 0.004  CHP154297.286  4297.29120.9+ 0.005  CHP8   23261.34*4297.769  4297.75112.8sN−0.018  ‖‖ ‖Cr i V i?M22240   23260.14*4297.991  4297.9797.4s−0.012  CHP1515340   23255.76*4298.801  4298.81322.0u+ 0.012  CHP14220   23253.88*4299.148  4299.13824.2u?−0.010  CHP14214   23253.34*4299.248  4299.24949.3sN+ 0.001  |Fe i Ti i (CH)M11160   23247.54*4300.321  4300.31820.2w−0.003  CHP1414370   23246.12*4300.583  4300.57329.3S−0.010  ‖ Ti i—CHB13200   23243.86  4301.001  4301.00023.7uN−0.001  CHP13220   23243.12*4301.138  4301.17418.1uN?+ 0.036  CH—Cr i|B13} 324    {23237.1123236.84  4302.251  } 4302.29731.4 {+0.0460.004  } CH—CHB134302.301  12300   23234.38*4302.756  4302.75424.2−0.002  CHP12200   23233.54  4302.912  4302.91319.0+ 0.001  CHPM   23229.71*4303.621  4303.59515.1s−0.026  Nd iiM12} 450? {23228.59*23227.95*4303.829  4303.83528.6u+ 0.006  CHP12114303.947  4303.93727.6wN−0.010  —CHB11190   23225.55  4304.392  4304.39516.0+ 0.003  CHP11216   23224.53*4304.581  4304.57125.1w−0.010  Fe i—CHB11208   23220.57  4305.315  4305.32213.5+ 0.007  CHP11204   23219.85  4305.449  4305.45628.8u+ 0.007  |Fe i Sr ii (CH)M10300   23217.39  4305.905  4305.91836.2S+ 0.013  Ti i (CH)M10210   23216.11  4306.142  4306.14521.1+ 0.003  CHP10280   23213.13  4306.695  4306.70125.1+ 0.006  CHP10310   23212.33*4306.844  4306.85529.2+ 0.011  CHP9180   23209.82  4307.309  4307.31117.2+ 0.002  CHP9300   23208.37  4307.578  4307.56428.8−0.014  CH?—CHB9200   23206.35  4307.953  4307.912165.7s−0.041  |Fe i Ti ii (CH)M9235   23205.20  4308.167  4308.17616.7+ 0.009  CHP8230   23203.01  4308.574  4308.59525.1+ 0.021  CH—CHB8230   23201.25  4308.901  4308.90520.4+ 0.004  CHP8260   23200.17*4309.101  4309.13113.2+ 0.030  CHP240   23198.68  4309.378  4309.38329.9u+ 0.005  |Fe i CHB7220   23196.97  4309.695  4309.71117.2w?+ 0.016  CHP77400   23194.83*4310.903  4310.10625.0+ 0.013  CHP7250   23192.87*4310.457  4310.46729.2+ 0.010  CHP6200   23191.64*4310.686  4310.70422.7s+ 0.018  CH—B6220   23190.01  4310.989  4310.98424.1−0.005  CHP6300   23189.12*4311.154  4311.16717.9+ 0.013  CHP6} 320    {23187.6223187.27*4311.433  4311.4468.8+ 0.013  CHP54311.498  4311.50939.6+ 0.011  CHP5200   23186.06*4311.723  4311.71819.0−0.005  CHP5} 280    {23184.15*23183.74*4312.078  4312.08623.0+ 0.008  CHP44312.155  4312.15014.8−0.005  CHP54280   23183.00*4312.292  4312.30218.6w?d+ 0.010  B
Open in a separate window
LaboratorySun

P1dcP1cdP2dcP2cdQ1cQ1dQ2cQ2dIntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
3141   23181.39*−0.028  Mn i —CHB
3, 22140   23180.78*4312.706  4312.7098.8+ 0.003  CHP
4200? 23179.75*4312.897  4312.87535.5w?−0.022  |Ti ii—CHB
4200? 23179.05*4313.027  4313.03519.5wN+ 0.008  |CH Fe i pB
M   23177.73  4313.273  4313.2371.5−0.036  A
} 160    {23177.1523176.0423175.66  4313.381  4313.4182.0+ 0.037  A
3 4313.5874313.658}  4313.63118.8 {+0.0440.027}CH—CH
3B
6   23174.46*4313.881  4313.8902.6s+ 0.009  M
22124   23172.72*4314.206  4314.2217.9w+ 0.015  CHP
37   23094.44  4328.829  4328.8452.1u+ 0.016  CHP
36   23093.98  4328.915  4328.9271.3+ 0.012  CHP
20    {23092.7523092.26  4329.146  4329.1441.2−0.002  CHP
4329.238  A
320    {23088.5223088.19  4329.939  A
34330.001  4330.0248.1s+ 0.023  V iM
418   23067.73  4333.842  A
419   23066.89  4334.000  4334.0182.3+ 0.018  CHP
10   23065.80  4334.204  4334.1662.3−0.038  Sm iiM
428   23063.39  4334.658  4334.6723.9+ 0.014  CHP
428   23062.75  4334.778  4334.8003.9s+ 0.022  CH—Ti i|B
540   23042.29*4338.627  4338.6273.20.000  CHP
540   23041.13  4338.845  4338.8296.4ud−0.016  Cr i Fe i pM
545   23038.95  4339.256  4339.2598.1u+ 0.003  Fe i (CH)M
543   23037.92  4339.450  4339.45627.4s+ 0.006  Cr iM
640   23018.16*4343.175  4343.21615.0ud*+ 0.041  |Cr i —Fe i pM
645   23016.49  4343.490  4343.49410.4+ 0.004  CHP
650   23015.42*4343.692  4343.70518.6u+ 0.013  Fe i (CH)M
645   23013.97  4343.966  4343.96811.5u+ 0.002  CHP
754   22995.12  4347.527  4347.5459.0+ 0.018  CHP
77115   22992.82*4347.961  4347.97313.1+ 0.012  CHP
764   22990.84  4348.336  4348.33812.0+ 0.002  CHP
870   22972.96  4351.720  4351.7100.5−0.010  CHP
878   22971.08  4352.076  4352.07216.8−0.004  CHP
866   22970.14  4352.254  4352.26112.2+ 0.007  CHP
877   22968.54  4352.558  4352.55712.2−0.001  CHP
970   22951.90  4355.713  4355.70411.0−0.009  CHP
978   22950.32  4356.013  4356.00016.8−0.013  CHP
977   22948.41  4356.375  4356.36712.6−0.008  CHP
977   22947.14  4356.617  4356.60412.4−0.013  CHP
10110   22931.91*4359.510  4359.49313.8−0.017  CHP
1080   22930.62  4359.755  4359.74415.6w−0.011  Zr ii CHB
1094   22927.76  4360.299  4360.28913.3−0.010  CHP
1094   22926.72  4360.497  4360.48013.5s−0.017  Ti i CHB
11100   22913.02  4363.105  4363.10816.5ud+ 0.003  CH—Cr iB
11103   22911.90  4363.318  4363.29313.8wd−0.025  CHP
11110   22908.07  4364.048  4364.04111.0−0.007  CHP
11110   22907.26  4364.202  4364.18912.1−0.013  CHP
12100   22895.08*4366.524  4366.50014.4−0.024  CHP
12104   22894.13  4366.705  4366.67516.5−0.030  CHP
12120   22889.32*4367.622  4367.59432.7u−0.028  |Fe i—CHB
12110   22888.68  4367.745  4367.7233.2−0.022  CHP
13100   22878.29  4369.728  4369.7146.2u−0.014  Ti i—Fe i p (CH)M
13100   22877.55  4369.870  4369.8662.3−0.004  CHP
13} 150    {22871.4622871.26  4371.033  } 4371.06217.8wd {+0.0290.010  } CH—CHB
134371.072  
14100   22862.50  4372.746  4372.7439.1−0.003  CHP
14100   22861.86  4372.869  4372.84415.8−0.025  CHP
1414130   22854.73*4374.233  4374.22614.4−0.007  CHP
1590   22847.78  4375.563  4375.57815.3+ 0.015  CHP
1590   22847.20  4375.675  4375.65815.8−0.017  CHP
1515150   22838.96*4377.253  4377.23419.9−0.019  CHP
16} 100    {22833.7922833.50  4378.244  } 4378.25519.0 {+0.0110.045  } CH—CH?B
164378.300  
1616120   22824.21*4380.282  4380.3673.4u+ 0.085  Mg i (CH)M
1717125   22820.85*4380.727  4380.72421.0−0.003  CH—B
17} 90    {  22810.49 22810.334382.716  4382.6895.7−0.027  CHP
174382.747  4382.76422.4+ 0.017  CH—Fe i|B
181890   22808.95*4383.012  4382.99816.4−0.014  —CHB
1919} 130    {22798.05*22797.6622797.15  4385.108  4385.12414.1+ 0.016  CHP
184385.183  A
184385.281  4385.25412.1u−0.027  |Fe i—CHB
202080   22787.78*4387.084  4387.06313.4−0.021  CHP
1960   22785.64  4387.496  4387.49713.9s+ 0.001  Cr i (CH)M
1955   22785.10  4387.600  4387.5959.6−0.005  CHP
212166   22778.38*4388.894  4388.87010.7−0.024  CHP
2050   22774.41  4389.660  4389.63810.2−0.022  CHP
2040   22773.73  4389.791  4389.7766.8−0.015  CHP
222260   22769.83*4390.543  4390.5458.9+ 0.002  CHP
2145   22763.95  4391.677  4391.66811.8u?−0.009  Ce ii—CHB
2144   22763.20  4391.821  4391.76815.2s−0.053  Cr i (CH)M
232344   22761.77*4392.097  4392.07112.3s−0.026  V i CHB
22242460   22754.30*4393.539  4393.52416.2ud?−0.015  —CHB
2235? 22753.39  4393.715  4393.7006.4w−0.015  Fe i p—CHB
252534   22747.36*4394.879  4394.85211.6s−0.027  Ti iM
2348   22745.11  4395.314  4395.2893.4−0.025  Fe i CHB
2345   22744.16  4395.498  4395.50415.0ud+ 0.006  CH—Fe iB
26} 20    {22741.0922740.72  4396.091  4396.0795.0−0.012  CHP
264396.163  4396.1534.1−0.010  —CHB
2436   22736.52  4396.975  4396.96110.2−0.014  CHP
24} 22    {22735.6022734.82  4397.153  4397.1435.0u−0.010  CHP
274397.304  A
2722734.38  4397.389  4397.3813.4u−0.008  M
252824   22728.58*4398.511  4398.4917.7−0.020  CH V iiB
2816   22727.97  4398.629  4398.6215.4w−0.008  Ni i CHB
2514   22727.44  4398.732  4398.7124.3w−0.020  CHP
2614   22720.92  4399.994  4399.9894.8−0.005  CHP
2620   22719.74  4400.223  4400.1859.3−0.038  Ni i CH?B
2722713.45  4401.441  4401.45115.0u+ 0.010  Fe iM
2722712.19  4401.685  4401.6682.5−0.017  CH?P
2822706.19  4402.848  4402.8414.1u−0.007  CHP
2822704.86*4403.106  4403.0774.5uN−0.029  CHP
2922698.72  4404.297  4404.27712.0u−0.020  |Ti i—CHB
2922697.44  4404.546  4404.5485.2+ 0.002  CH?P
3022691.10  4405.776  4405.7326.4sd−0.044  Ti i—CH?B
3022689.73  4406.043  4406.0363.0u−0.007  CH?P
3122683.17  4407.317  A
3122681.62  4407.618  4407.65214.1sd*+ 0.034  V iM
3222674.32  4409.037  A
3222672.69  4409.354  4409.3592.9uN+ 0.005  M
3322664.71  4410.907  A
3322663.07*4411.226  4411.2275.4uN+ 0.001  CH—CH?M
3422654.44  4412.906  4412.8771.4u−0.029  M
3422653.18  4413.152  4413.1212.5−0.031  M
Open in a separate window*Blend.Satellite lines as follows:
DesignationJLaboratory
Wave numberWavelength

RQ 2d 1c323293.17*4291.897
RQ 2c 1d ; RQ 2d 1c2; 223261.34*4297.769
RQ 2c 1d ; RQ 2d 1c1; 123229.71*4303.621
QR 1 2c323179.75*4312.897
QR 1 2d223179.05*4313.027
QP 2 1d323177.73  4313.273
QP 2 1c323177.15  4313.381
QP 2 1d; QP 2 1c2; 223174.46*4313.881
RQ 1d 2c323092.75  4329.146
RQ 1c 2d323092.26  4329.238
RQ 1c 2d423065.80  4334.204
Open in a separate window

Table 6

CH in the Solar Spectrum A 2Δ—X 2Π (1,2)
Laboratory
P1cdP1dcP2cdP2dcQ1cQ1dQ2cQ2dR1cdR1dcR2cdR2dcIntensityWave number cm−1Wavelength A
1313121083.78  4741.660
1313221077.49  4743.076
1212421040.28*4751.463
1212121034.82  4752.697
11220998.22  4760.982
11320997.21*4761.219
11120993.57  4762.035
11120992.87  4762.194
10220956.62  4770.432
10220955.52  4770.682
10220952.79*4771.305
10220951.91  4771.505
9220916.02  4779.692
9220914.78*4779.975
9220912.79*4780.429
9220911.85  4780.644
8220876.26  4788.794
8220874.73  4789.145
8220873.82  4789.354
8220872.56  4789.644
7220837.84  4797.625
77329835.83  4798.089
7220834.15  4798.475
6220800.39  4806.263
6220798.97  4806.591
6220798.14  4806.784
17176320796.78  4807.097
1717120787.35  4809.279
1616220774.31  4812.296
1616520765.81*4814.267
5620764.24*4814.630
5720763.02*4814.913
5620761.64*4815.233
5220760.55  4815.486
15220752.52  4817.350
15120751.93  4817.486
1515220744.41  4819.232
14220731.59  4822.214
14220730.92  4822.370
4220729.75  4822.640
4220728.91  4822.837
4320726.33  4823.438
4320725.64  4823.597
1414320724.38  4823.891
13220711.85  4826.844
13220710.99  4827.009
1313220705.27  4828.342
3220696.75  4830.332
3220695.97  4830.513
12220692.96  4831.216
123420692.14  4831.408
3320691.71  4831.508
12220687.60  4832.467
12220686.99  4832.610
11520675.54*4835.285
11220674.45  4835.541
11220670.88  4836.376
11220670.20  4836.535
22220665.81  4837.562
4838.899
1022520659.09  4839.135
10320658.03  4839.384
10320655.35  4840.012
10320654.55  4840.200
9320644.23  4842.620
9320642.80  4842.954
9320641.02  4843.371
911520639.87  4843.641
8620630.61*4845.817
8320629.01  4846.191
220628.34  4846.350
8320627.96  4846.440
811520626.65  4846.746
7320618.58  4848.644
77420616.61  4849.108
7320614.78  4849.537
6320607.97  4851.141
6620606.45*4851.499
6620605.36*4851.755
6320604.23  4852.020
5320598.95  4853.265
5320597.80  4853.537
5320596.06  4853.945
5320595.01  4854.194
4320591.61  4854.995
4320590.65  4855.221
4320587.97  4855.854
4320587.27  4856.019
3220585.87  4856.348
3220584.67  4856.631
22620582.64*4857.110
3320581.17  4857.459
3320580.69  4857.572
22220575.52  4858.791
3220502.61  4876.070
3220501.28  4876.387
220500.65  4876.535
3120497.27  4877.340
   3720496.23*4877.589
4520480.80*4881.262
4620479.27*4881.627
620478.34*4881.849
4720476.93*4882.185
   4120475.50  4882.526
5220460.87  4886.017
5120459.59  4886.322
120458.64  4886.549
5720457.36*4886.856
   5620456.67*4887.021
6420442.89*4890.315
6220441.13  4890.735
6220439.97  4891.014
   6220438.76  4891.302
7220426.06  4894.343
77320424.13  4894.807
   7220422.38  4895.227
8220411.40  4897.859
8220409.71  4898.265
8220408.61  4898.528
   8220407.41  4898.816
9220398.60  4900.933
9220397.08  4901.296
9220395.39  4901.704
   9220394.16  4901.999
10220387.46  4903.610
10220386.24  4903.905
10220383.50  4904.563
   10220382.60  4904.779
11220377.89  4905.913
11220376.83  4906.169
11220373.31  4907.017
   11220372.53  4907.205
12220370.00  4907.814
12220368.99  4908.057
12220364.85  4909.055
   1213220364.14  4909.227
13220363.15  4909.463
14220359.49  4910.347
14220358.74  4910.529
13220357.79  4910.756
   13220357.56  4910.812
15220356.53  4911.062
15220356.01  4911.186
1717220355.21  4911.379
16220354.79  4911.481
16220354.36  4911.583
   1414320352.25  4912.094
   1515220348.75  4912.939
16, 171617120346.28  4913.535  
Open in a separate window*Blend.Satellite lines as follows :
DesignationJLaboratory
Wave numberWavelength

RQ 2d 1c320692.964831.216
RQ 2c 1d ; RQ 2d 1c2; 220660.104838.899
RQ 2c 1d ; RQ 2d 1c1; 120628.344846.350
PQ 1d 2c320501.284876.387
PQ 1c 2d320500.654876.535
PQ 1c 2d420478.344881.849
PQ 1c 2d520458.644886.549
Open in a separate window

Table 11

CH in the Solar Spectrum C 2Σ+—X 2Π (1, 1)
LaboratorySun

PQRIntensityWave number cm−1Wavelength AWavelength ADisk int. Rowl. est.⊙—lab. ASolar identificationNotes
191   32050.51  3119.1713119.198[ 1Nd?]+0.027M
18(CH)   32045.67*3119.6423119.678[ 1]+0.036OH CH Cr iM
171   32038.34  3120.3553120.372[ 3 ]+0.017Cr iiM
161.532029.60  3121.2073121.160[ 4 ]−0.047V iiM
15(CH)   32019.19*3122.2223122.219[ 0 ]−0.003OH CHM
142   32006.57  3123.4533123.443[−1 ]−0.010OHM
13(CH)   31990.65*3125.0073124.998[ 4 ]−0.009Cr iiM
124.531974.16  3126.6193126.617[ 1 ]−0.002CH OH—OHB
113   31956.69  3128.3283128.289[ 1 ]−0.039Sc ii OH |M
10(OH)   31936.86  3130.2713130.267[ 3 ]−0.004|V ii—OHM
8(OH)   31895.65  3134.3153134.337[ 1 ]+0.022|OH Cr iiM
71.531873.48  3136.4953136.506[ 2 ]+0.011V iiM
61.331850.58  3138.7513138.786[ 0 ]+0.035A
51.531826.96  3141.0803141.106[−1 ]+0.026CH?P
22   31670.8    3156.57  3156.565[ 0 ]−0.01  —CHB
331670.2    3156.63  A
42   31669.0    3156.75  3156.727[ −1 ]−0.02  CHP
52   31667.2    3156.93  3156.916[ 0 ]−0.01  —CHB
66   31665.2   3157.13  3157.143[ 1 ]+0.01  |OH—Fe ipM
73   31663.0    3157.35  A
84   31660.1    3157.64  3157.634[−1 ]−0.01  CHP
94   31658.8    3157.77  3157.751[ 0 ]−0.02  CH OH?B
10(CH)   31652.9*  3158.36  3158.351[ 0 ]−0.01  Fe iip—M
116   31648.4    3158.80  3158.783[ 1 ]−0.02  Co i CHB
126   31643.3    3159.31  3159.349[ 0 ]+0.04  Fe iip?—V ii?M
136   31637.2    3159.92  3159.935[ 0N ]+0.02  CH—B
145   31630.3    3160.61  3160.612−10.00  Cr i CHB
15(CH)   31622.2*  3161.42  3161.423[ 0 ]0.00  M
166   31612.9    3162.35  3162.353[ 1 ]0.00  Fe i CHB
174   31602.1    3163.43  3163.423[ 2 ]−0.01  Nb ii—CHB
184   31589.5    3164.69  3164.685[ 1 ]−0.01  Mn ii—CHB
193   31575.1    3166.14  3166.130[ 0 ]−0.01  CHP
203   31558.4    3167.81  3167.790[ 1 ]−0.02  Fe i—CHB
21(CH)   31540.6    3169.60  3169.616[ 0 ]+0.02  OHM
62   31503.07  3173.3763173.408[ 1 ]+0.032Fe iM
72   31473.45  3176.3623176.351[ 1 ]−0.011Fe iM
82   31444.83  3179.253A
93   31417.00  3182.0703182.061[ 1 ]−0.009Fe i—CHB
10(CH)   31385.15  3185.2993185.327[ 2 ]+0.028Fe iiM
114   31355.47  3188.3143188.335[ 0 ]+0.021CHP
124   31325.15  3191.4003191.414[ 0 ]+0.014Fe ip CHB
134   31294.43  3194.5333194.524[−1 ]−0.009CHP
14(CH)   31263.55*3197.6893197.710[ 1N ]+0.021CHM
153   31231.66  3200.9543200.962[ 1 ]+0.008OHM
162.531199.10  3204.2953204.284[ 2Nd?]−0.011M
172   31165.79  3207.7203207.711[ 0 ]−0.009Fe iM
181.531131.80  3211.2223211.209[−1 ]−0.013CH?P
191   31096.37  3214.8813214.864[−2 ]−0.017CH?P
2031059.68  3218.6783218.684[−1 ]+0.006Cr iM
2131021.21  3222.670A
Open in a separate window*Blend.Under the general heading, “Laboratory,” the respective rotational quantum numbers of the P, Q, and R branches are entered as indicated by the respective headings. Lines of weak satellite branches are indicated by the symbol ‡, and a summary of the satellite lines is included in footnotes to the tables.These entries are followed by an intensity column. Intensities have been determined from measurements of the emission from the reaction zone of an acetylene-oxygen flame. A question mark (?) after the intensity number indicates a questionable intensity measurement caused by some overlapping from a strong neighboring line.(CH) indicates a weak line masked by a stronger CH line, whereas “M” indicates masking by some other emission in the laboratory source. In 9]. In ,3,3, and and44 the laboratory analysis is from Gerö [6]; in and66 it is from N. H. Kiess and Broida [7]; in ,8,8, ,99 from Gerö [6]; and in and1111 from Heimer [8]. Fagerhölm’s measurements [10] of the A 2Δ—X2 Π and B 2Σ—X 2Π bands do not fit the solar data so well as those of Gerö and have been used only as a check for errors. An asterisk in the wave number column is used to indicate a blend of two or more CH lines.

Table 3

CH in the Solar Spectrum A 2Δ—X 2Π (1, 1)
LaboratorySun

Q1cQ1dQ2cQ2dR1dcR1cdR2dcR2cdIntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙–lab. ASolar identificationNotes
29, 283?23886.86*4185.222A
29, 284?23883.64*4185.7874185.7794.5−0.008M
276?23880.52  4186.3344186.3369.3uN+ 0.002CN—Cr iM
3027M  23879.45*4186.521A
264  23872.78  4187.6914187.7207.2+ 0.029M
264  23871.58  4187.9014187.81220.8u−0.089Fe iM
255  23861.81  4189.6164189.56516.7u−0.051Fe iM
255  23860.75  4189.8024189.8163.8s+ 0.014V iM
24232313  23848.12*4192.0214192.01612.4u−0.005CN?—CHB
246?23847.29  4192.1674192.2043.6+ 0.037CHP
23(CH)23831.96*4194.8644194.84815.5u−0.016CHM
238?23831.30  4194.9804194.99611.2sd?+ 0.016CH Cr I—CNB
222211  23828.76*4195.4274195.4153.6−0.012Cr ii—CHB
2210  23813.78  4198.0664198.06823.1uN+ 0.002Fe iM
2210  23813.08  4198.1894198.24232.9u+ 0.053Fe iM
212115  23807.69*4199.1404199.10543.6u−0.035Fe iM
2114  23793.81  4201.5894201.5777.4w−0.012—CHB
2112  23793.07  4201.7204201.71517.1w−0.005|Ni i Fe iM
202018  23785.01  4203.1444203.1299.5sd−0.015—CHB
2016  23772.11  4205.4264205.3909.8wN−0.036Mn ii—CHB
2014  23771.49  4205.5354205.54421.2s+ 0.009Fe i (CH)M
191916  23760.89*4207.4114207.40814.0wN−0.003CHP
1919  23748.98  4209.5214209.5006.4u−0.021CHP
1918  23748.45  4209.6154209.6027.1u−0.013CHP
181833  23735.48*4211.9164211.89515.4u−0.021|Zr ii—CHB
18} 26   {23724.5623724.27  4213.8544213.8394.7u−0.015CHP
184213.9064213.90910.7+ 0.003CHP
171739  23709.04  4216.6134316.59911.6uN−0.014CHP
1717} 36   {23699.0723698.85  4218.387 4218.426} 4218.39212.6uN {+0.0050.034} CH—CHB
161643  23681.72*4221.4774221.46912.8−0.008CHP
161645  23672.66*4223.0934223.09115.6−0.002CHP
15} 45   {23653.7723653.58  4226.4654226.43152.5u−0.034Fe iM
154226.499A
151554  23645.54*4227.9364227.94415.6s+ 0.008CHP
1442  23625.14  4231.5874231.6099.7uN+ 0.022CH—Zr iiB
1440  23624.66  4231.6734231.6889.7uN+ 0.015CH–Fe iB
141463  23617.71*4232.9194232.92715.1u+ 0.008|CH—V i?B
1340  23595.95  4236.8224236.80612.0u−0.016CH V iiB
1340  23595.30  4236.9394236.9587.8u+ 0.019CHP
131362  23589.28*4238.0204238.02926.2s+ 0.009Fe iM
1246  23566.19  4242.1724242.16212.0−0.010Tm ii—CH|B
1246?23565.38*4242.3184242.2835.2wN*−0.035−CHB
1245?23560.54  4243.1894243.20314.8+ 0.014CH—B
1245?23560.12  4243.265A
1141  23536.30  4247.5614247.56018.1wN−0.001CH—B
1145  23535.34  4247.7344247.72611.5−0.008CHP
1148  23531.47  4248.4324248.41415.3s−0.018|Fe I p—CHB
1148  23530.89  4248.5374248.5349.4w−0.003CHP
1041  23506.18  4253.0034253.0048.9+ 0.001CHP
1045  23505.04  4253.2094253.2109.4s+ 0.001|CHP
1046  23502.12  4253.7384253.7359.2−0.003CHP
1050  23501.31  4253.8854253.91216.4sd+ 0.027CH—Fe iB
942  23475.98  4258.4754258.4889.4u+ 0.013CH—Ti iB
956  23474.60*4258.7254258.73112.9w+ 0.006CH—B
944  23472.61  4259.0864259.0989.4uN+ 0.012CHP
948  23471.55  4259.2784259.30514.3sd?+ 0.027V i Fe i (CH)M
840  23445.69  4263.9764263.9809.6w+ 0.004CHP
844  23444.06  4264.2734264.2812.3U+ 0.008CHP
842  23442.96  4264.4734264.46813.4s−0.005CHP
846  23441.63  4264.7154264.74120.2U+ 0.026Fe i (CH)M
744  23415.51  4269.4724269.4789.1w+ 0.006CH—La iiB
7782  23413.48*4269.8424269.84917.8U+ 0.007CH—Fe i pB
746  23411.70  4270.1674270.17015.0sd+ 0.003|Ti i CHB
642  23385.46  4274.9584274.95920.1uN+ 0.001CHP
680  23383.88*4275.2474275.25815.0+ 0.011CHP
6104  23383.17*4275.3774275.38624.3+ 0.009CHP
650  23381.73  4275.6404275.66110.5ud*+ 0.021CH La iiB
550  23355.75*4280.3964280.40314.2w+ 0.007Cr i CHB
560  23354.59  4280.6094280.6327.2+ 0.023Fe i p CHB
560  23352.70*4280.9564280.96411.4+ 0.008CHP
550  23351.87  4281.1084281.10018.0s−0.008|Mn i—CHB
430  23326.34  4285.7944285.81513.8s+ 0.021Co i—Fe i (CH)M
440  23325.56  4285.9374285.9381.8+ 0.001CHP
4(CH)23322.56*4286.4884286.47726.6uN−0.011Fe i—CHM
4M  23322.08  4286.5764286.58711.2uN+ 0.011CHP
3(CH)23297.42*4291.1134291.12126.1U+ 0.008CHM
3(CH)23296.85*4291.2194291.22014.2u+ 0.001CH Ti iM
(CH)23293.17*4291.8974291.8392.6sd−0.058V iM
3M  23292.69  4291.9854291.9796.5w−0.006Cr i—CHB
3(CH)23292.36*4292.0464292.05512.3+ 0.009CHM
2256  23269.80*4296.2074296.2178.1+ 0.010CHP
(CH)23263.96*4297.2864297.29120.9+ 0.005CHM
22120  23262.70*4297.5184297.53017.4wd?+ 0.012CH—B
1919(CH)23253.34*4299.2484299.24949.3sN+ 0.001|Fe i Ti I (CH)M
11} 80   {23252.00*23249.13*4299.4964299.48318.1u−0.013CH Fe i pB
18184300.0264300.05338.6w+ 0.027Ti iiM
17M  23245.09  4300.7744300.74411.8uN−0.030M
17M  23244.61  4300.8634300.82723.0u−0.036Fe iM
1919(CH)23243.12*4301.1384301.10341.6s−0.035Ti i (V ii)M
16} 88   {23239.8923239.69  4301.736} 4301.74915.1 {+0.0130.024} CH—CHB
164301.773
181850?23239.22*4301.8604301.92734.4u+ 0.067Ti iiM
1717M  23235.12*4302.6194302.53938.4S−0.080Ca iM
15M  23234.75  4302.6884302.65  19.5−0.04  M
15(CH)23234.38*4302.7564302.75424.2−0.002CHM
1168  23232.47*4303.1104303.0899.3w?N−0.021CHP
161688  23230.85*4303.4104303.42616.7+ 0.016CHP
14M  23229.30*4303.6974303.72313.2w+ 0.026CH—B
14(CH)23228.59*4303.8294303.83528.6u+ 0.006CHM
1515M  23226.26*4304.2614304.25614.6w−0.005CHP
13M  23223.84  4304.7094304.7219.0+ 0.012CHP
13M  23223.09  4304.8484304.85213.0uN+ 0.004CH—Fe iB
141488  23221.71*4305.1044305.11019.0+ 0.006CH Fe iB
1248  23218.55  4305.6904305.71315.6u+ 0.023Sc iiM
12M  23217.78  4305.8334305.8475.8+ 0.014CHP
1313(CH)23217.08*4305.9624305.91836.2S−0.044Ti i (CH)M
11M  23213.41  4306.6434306.59912.5uN−0.044Fe iM
12M  23212.73  4306.769A
1211(CH)23212.33*4306.8444306.85529.2+ 0.011CHM
10M  23208.67  4307.523} 4307.56428.8 {+0.0410.014} CH?—CHB
11(CH)23208.37*4307.578M
1110M  23207.52*4307.7364307.74840.2s+0.012Ca iM
10M  23204.74  4308.2524308.28912.8+0.037A
9M  23204.18*4308.3564308.38114.2+ 0.025CHP
Open in a separate window
LaboratorySun

P1dcP1cdP2dcP2cdQ1cQ1dQ2cQ2dIntensityWave number cm−1Wavelength AWave length ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
10M  23203.77*4308.4324308.44111.1+ 0.009CHP
9M  23202.76  4308.6204308.59525.1−0.025CH—CHB
9M  23200.84  4308.9764309.04031.6u+ 0.064Fe iM
8(CH)23200.17*4309.1004309.13013.2+ 0.030CHM
9M  23199.74  4309.1814309.20513.2+ 0.024CHP
8M  23198.31  4309.4464309.45821.6w+ 0.012CH Fe i pB
8M  23197.31*4309.6324309.63421.8u+ 0.002‖Y ii CHB
7M  23196.30  4309.8204309.8349.5sN+ 0.014CH V iB
8M  23195.88  4309.8984309.90016.5uN+ 0.002CHP
77M  23194.19*4310.2124310.22518.3+ 0.013CHP
6  (CH)23192.87*4310.4574310.46729.2+ 0.010CHM
7M  23192.41  4310.5434310.5599.3+ 0.016CHP
6(CH)23191.64*4310.6864310.70422.7s+ 0.018CH—M
65M  23190.56*4310.8864310.89710.0+ 0.011CHP
65(CH)23189.12*4311.1544311.16717.9+ 0.013CHM
4M  23188.26  4311.3144311.3225.6+ 0.008CHP
54(CH)23187.27*4311.4984311.50939.6+ 0.011CHM
53, 23, 2(CH)23186.06*4311.7234311.71819.0−0.005CHM
M  23185.33*4311.8594311.8884.4u+ 0.029M
4(CH)23184.15*4312.0784312.08623.0+ 0.008CHM
4(CH)23183.74*4312.1554312.15014.8−0.005CHM
3M  23181.72*4312.5314312.5044.6u−0.027Cr i?—CHB
3(CH)23181.39*4312.5924312.56420.9−0.028Mn i—CHM
(CH)23179.75*4312.8974312.87535.5w?−0.022|Ti ii—CHM
22(CH)23179.05*4313.0274313.03519.5wN+ 0.008|CH Fe i pM
3} 24   {23104.0023103.46*4327.0384327.11018.2w+ 0.072Fe iM
34327.1394327.1572.0u?+ 0.018CHP
8  23102.23  4327.3704327.3171.4−0.053A
8  23101.32  4327.540A
36  23098.25  4328.115A
36  23097.89  4328.1834328.2032.0+ 0.020CH?P
420  23077.53  4332.0014332.0061.2o+ 0.005CH—B
414  23076.75  4332.148} 4332.1691.0 {+0.0210.037CHP
23076.44  4332.206A
23075.60  4332.364A
48  23073.37  4332.7834332.8314.8s+ 0.048V iA
412  23072.71  4332.9064332.9188.3u+ 0.012CH—B
520  23052.10  4336.7804336.7912.3u+ 0.011CHP
514  23050.92  4337.0024337.05530.4U+ 0.053Fe iM
M  23050.18  4337.142A
520  23048.79  4337.4034337.4114.8u+ 0.008CHP
520  23047.87  4337.5764337.56623.3s−0.010Cr iM
620  23027.55  4341.4044341.37119.6w?−0.033Ti iiM
20?23026.97  4341.5134341.5514.8uN+ 0.038Fe i pA
620  23025.95  4341.7054341.7105.8w+ 0.005CHP
G20  23024.93  4341.8984341.9244.8u?+ 0.026CHP
620  23023.50  4342.1684342.1806.4U+ 0.012Gd ii CHB
718  23003.77  4345.8924345.8955.8u+ 0.003CHP
7743  23001.62*4346.2984346.29512.0U−0.003CHP
722  22999.68  4346.6654346.6733.7u+ 0.008CHP
821  22980.73  4350.2494350.2496.4u0.000CHP
822  22978.93  4350.5894359.5858.3u−0.004Fe i—CHB
821  22978.01  4350.7644350.7603.9−0.004CHP
826  22976.47  4351.0554351.05620.0s+ 0.001Cr iM
920  22958.39  4354.4824354.5148.3uNN*+ 0.032Mg iM
918  22956.88  4354.7684354.7625.7−0.006CH Fe i?B
928  22955.02  4355.1214355.09323.0s−0.028Ca i (CH)M
924  22953.82  4355.3494355.3518.0u+ 0.002CHP
1020  22936.77  4358.5864358.51221.8u−0.074Fe iM
1036  22935.49  4358.8304358.82015.6uN−0.010—CHP
1030?22932.73  4359.3544359.3416.6−0.013CHB
10110  22931.91*4359.5104459.49313.8−0.017CHP
1128  22915.87*4362.5624362.53312.1w?−0.029—CHB
1132  22914.81*4362.7644362.74610.3u−0.018CHP
1140?22911.09  4363.4734363.4675.5u−0.006CHP
1130?22910.33  4363.6174363.6026.2w−0.015Mo ii—CHB
12M  22895.53  4366.4384366.4135.5uN−0.025—CHB
12(CH)22895.08*4366.5244366.50014.4−0.024CHM
12M  22889.92*4367.5084367.4755.7u−0.033CHP
12(CH)22889.32*4367.6224367.59432.7u−0.028|Fe i—CHM
1328  22876.01  4370.1644370.1546.2−0.010CHP
1332  22875.25  4370.3094370.2925.9−0.017CHP
13} 50? {22869.4622869.24  4371.415} 4371.42611.9wd? {+0.0110.031} CH—CH
134371.457B
1438  22857.00  4373.7994373.7917.8u−0.008CHP
1434?22856.50  4373.8944373.8887.80.006CH Fe i pB
141448  22849.59*4375.2174375.20212.6−0.015CHP
15(CH)22838.96*4377.2534377.23419.9−0.019CHM
15M  22838.10  4377.4184377.3748.4u−0.044Fe i—CHB
151548  22830.26*4378.9214378.91310.0−0.008CHP
16(CH)22820.85*4380.7274380.72421.0−0.003CH—M
16M  22820.27*4380.8384380.8529.6wN+ 0.014CH—B
161640  22811.40*4382.5424382.5218.2−0.021CHP
17} 32   {22803.2222803.00  4384.114} 4384.1208.4 {+0.0060.036CH—CHB
174384.156
171731  22792.92*4386.0954386.0639.8−0.032—CHB
1818M  22786.09*4387.4104387.39810.5u−0.012—CHB
181830?22775.14*4389.5194389.5044.6−0.015CHP
1919M  22769.35*4390.6354390.6307.5u−0.005CHP
1918?22757.45  4392.9314392.9244.8u−0.007CHP
1918?22756.89  4393.0394393.0256.1s?−0.014CH F ipB
202015?22752.83*4393.8234393.8086.4u−0.015CH V iB
2028?22739.85*4396.3314396.3098.2−0.022CHP
2020?22739.39  4396.4204396.4304.1u+ 0.010CHP
2121(CH)22736.52*4396.9754396.96110.2−0.014CHM
2122722.42  4399.704} 4399.77826.4w? {+0.0740.061} Ti ii (Cr i)M
2122721.72  4399.839
222222719.74*4400.2234400.1859.3−0.038Ni i CH?M
22(CH)22704.86*4403.1064403.0774.5uN−0.029CHM
22(CH)22704.16  4403.2424403.18714.5u−0.055A
232322703.21*4403.4264403.37410.7s−0.052‖Cr i Zr iiA
2322687.27  4406.5214406.5044.5u−0.017CHP
24232422686.36*4406.6964406.65218.2S−0.044V iM
24252522669.17*4410.0394410.0145.7−0.025—CH?B
2422668.37  4410.1954410.1675.7−0.028—CH?B
2522650.69  4413.6374413.5998.8w−0.038|Fe i CH?B
2522649.72  4413.8264413.8536.6u+ 0.027Cr iM
2622631.45  4417.3904417.4123.4s+ 0.022Co iM
2622630.37  4417.6004417.5742.5u−0.026CHP
2722611.22  4421.3424421.3344.8u−0.008Co i—CHB
2722610.08  4421.5654421.5737.9S+ 0.008V iM
2822589.60  4425.573A
2822588.33  4425.8224425.7695.0uN−0.053Fe i p—Fe i pA
2922566.49  4430.105A
2922565.28  4430.3434430.3686.1s+ 0.025Ti iM
3022541.17  4435.081A
3022539.67  4435.3764435.3285.9u−0.048Ni i?A
3122513.21  4440.5894440.6304.3+ 0.041Fe iA
3122512.03  4440.8234440.82710.4u+ 0.004M
3222482.25  4446.705A
Open in a separate window*Blend.Satellite lines as follows:
DesignationJLaboratory
Wave numberWavelength

RQ 2c 1cd ; RQ 2d 1c3; 323293.17*4291.897
BQ2d 1c223263.96*4297.286
BQ 2d 1c123234.38*4302.756
QP2 1d ; QR1 2d ; QR1 2c4; 2; 2, 323185.33*4311.859
QP2 1c423184.15*4312.078
QP2 1d323181.72*4312.531
QP2 1d; QP2 1c2; 223179.75*4312.897
PQ 1c 2d323102.23  4327.370
PQ 1d 2c323101.32  4327.540
PQ 1c 2d423076.44  4332.206
PQ 1d 2c423075.60  4332.364
PQ 1d 2c523050.18  4337.142
PQ 1c 2d623026.97  4341.513
Open in a separate window

Table 4

CH in the Solar Spectrum A 2Δ—X 2Π (2, 2)
LaboratorySun

Q1cQ1dQ2cQ2dR1dcR1cdR2dcR2cdIntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
2020723587.31*4238.3744238.3959.7ud?+ 0.021CH La iiB
23, 22623584.39*4238.8994238.9449.7sN+ 0.045Cr iM
22423583.67  4239.0284239.0443.8+ 0.016Fe i p CHB
23323583.23  4239.1084239.1452.4+ 0.037A
21} 5 {23581.1823580.534239.4764239.4852.1u+ 0.009CHP
214239.5924239.5992.6u+ 0.007CHP
24223579.75  4239.7334239.73319.8u0.000Mn i—Fe iM
24223578.80  4239.9044239.95316.5u+ 0.049Fe iM
1919823577.18*4240.1954240.1994.7w?+ 0.004CHP
20623574.93  4240.6004240.6102.2+ 0.010CHP
20623574.29  4240.7154240.70214.1u−0.013Cr iM
25223570.94  4241.3184241.3281.2u+ 0.010CH—-B
25223569.86  4241.5124241.5212.8sd+ 0.009CHB
19(CH)23565.38*4242.3184242.2835.2wN*−0.035—CHM
181918(CH)23564.69*4242.4434242.45520.0+ 0.012CHM
18} 9 {23554.2223553.814244.3284244.3403.1u+ 0.012CHP
184244.4034244.4033.3u0.000CH—Fe iB
17171223550.06*4245.0784245.0826.6wN+ 0.004CH—B
17} 6 {23540.6523540.324246.776} 4246.83740.3w? {+0.061+0.002} Sc iiM
174246.835
16161123533.52*4248.0624248.0557.3w?N−0.007CHP
16(CH)23524.74*4249.6484249.63723.0ud−0.01l—CHM
16M23524.50  4249.691—CHA
15151323515.35*4251.3454251.3318.2s−0.014B
15151823507.64*4252.7394252.75611.8u+ 0.017CHP
14M23496.01  4254.8444254.8463.3u+ 0.002CHP
14(CH)23495.17*4254.9964254.97927.0ud−0.017Fe i—CHM
14142423488.93*4256.1274256.1365.20+ 0.009CH—B
13M23475.27  4258.6034258.61919.2u+ 0.016Fe iM
13(CH)23474.60*4258.7254258.73112.9w+ 0.006CH—M
13132223468.90*4259.7594259.7648.2w?+ 0.005CH—B
121523453.31  4262.5914262.5854.7w−0.006CHP
121523452.66  4262.7094262.7107.3+ 0.001CHP
12} 20 {23447.9823447.584263.560} 4263.608 {+0.0480.024} CH—CHB
124263.6328.7ud?
11(CH)23430.54*4266.7334266.74210.3+ 0.009CHM
1116?23429.67  4266.8914266.96819.0u+ 0.077Fe iM
11M23425.88  4267.5824267.5884.9s+ 0.006CHP
11(CH)23424.91*4267.7594267.74913.1uN−0.010CHM
101023406.90  4271.0424271.0576.1+ 0.015CH—Cr iB
101023405.76  4271.2504271.16452.2u−0.086Fe iM
101023402.96  4271.7614271.774177.0s+ 0.013Fe iM
101023402.13  4271.9134271.94918.2uN+ 0.036Fe i p CHB
98?23382.42  4275.5144275.5132.6−0.001CHP
98?23380.90  4275.791A
98?23379.27  4276.0904276.1034.7+ 0.013CH—B
923378.17  4276.2914276.2744.4−0.017—CHB
88(CH)23357.76*4280.0284280.03715.0wd?+ 0.009CHM
8(CH)23355.75*4280.3964280.40314.2w+ 0.007Cr i CHM
M23355.21  4280.4954280.4942.8s*−0.001Gd iiM
8(CH)23353.65  4280.7814280.78813.7+ 0.007Sm ii CHM
710?23332.39  4284.6834284.68611.7u+ 0.003Ni iM
77M23330.41*4285.0464285.00817.5s−0.038CH Ti i|M
7(CH)23328.63*4285.3734285.3717.9−0.002CHM
61423306.74  4289.3984289.37230.5s−0.026Ca iM
61423305.26  4289.670} 4289.72953.6S {+0.0590.086} Cr iM
61423304.47  4289.815
61423303.01  4290.0844290.0574.9u−0.027CHP
51423280.93  4294.1534294.14250.5s−0.011Fe i Ti iiM
51423279.84  4294.3544294.3706.3u+ 0.016CHP
51623278.19  4294.6594294.6237.2ud−0.036W i—CHB
51623277.23  4294.8364294.8591.6+ 0.023CHP
4M23254.96  4298.9494298.99427.2s+ 0.045Ca iM
4(CH)23253.88*4299.1484299.13824.2u?−0.010CHM
4M23251.70  4299.5514299.48318.1u−0.068CH Fe i pM
4M23250.98  4299.6844299.64519.1s−0.039‖Ti i Fe iM
3(CH)23229.30*4303.6974303.72313.2W+ 0.026CH—M
3(CH)23228.59*4303.8294303.83528.6u+ 0.006CHM
33(CH)23224.53*4304.5814304.57125.1w−0.010Fe i CHM
2(CH)23204.18*4308.3564308.38114.2+ 0.025CHM
(CH)23203.77*4308.4324308.44111.1+ 0.009CHM
22(CH)23197.31*4309.6324309.63421.8u+ 0.002‖Y ii CHM
11(CH)23189.12*4311.1544311.16717.9+ 0.013CHM
112823169.49*4314.8074314.80716.2s0.000Ti iM
11, 10,
9, 8
} 100{23125.56*4323.0044323.01315.5+ 0.009CHP
Open in a separate window
LaboratorySun

P1dcP1cdP2dcP2cdQ1cQ1dQ2cQ2dIntensityWave Number ber cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
212, 7, 2}{23125.26*4323.0594323.0636.5+ 0.004CHP
12, 11, 10
13, 9
13, 6, 5
4
} 150 {23124.49*23124.26*4323.204 4323.247} 4323.22623.6 {+0.0220.021} CH—CHB
814, 39023123.67*4323.3574323.36711.1u+0.010CH Fe i pB
14, 7 {9,8,76,5,43}} 120 {23122.98*23122.25*4323.4874323.51224.7u+ 0.025CH—B
6104323.6224323.61118.7uN−0.011CHP
9, 8, 7, 651115} 155 {23121.14*23120.47*23119.78*4323.8304323.85126.6+ 0.021CHP
10, 515, 44323.9554323.97313.2+ 0.018CHP
11, 4124324.0844324.0879.9+ 0.003CHP
12, 336023119.23*4324.1884324.1769.2−0.012CHP
13161316} 60 {23118.20*23118.04*4324.381} 4324.41217.8 {+0.031+0.002} CH CHB
224324.410
14143123115.79*4324.8314324.8199.9w−0.012—CHB
17172523114.36*4325.0994325.14116.6s+ 0.042Ti iM
15152823113.03*4325.3484325.35615.5u+ 0.008CHP
161816184323109.38*4326.0314326.05213.2uN+ 0.021CHP
172023104.87  4326.875} 4326.9178.6w {+0.0420.020} CH—CHB
171823104.54  4326.937
19192023103.46*4327.1394327.1572.0u?+ 0.018CHP
18} 14 {23099.1323098.734327.9514327.91716.2u−0.034Fe iM
184328.0254328.0356.2+ 0.010CHP
20201523095.65*4328.6024328.6108.1u+ 0.008CHP
19} 20 {23092.0723091.554329.2744329.2896.9u+ 0.015CHP
194329.3714329.3916.0u+ 0.020CHP
21211223086.07*4330.3994330.4085.3uN*+ 0.009CHP
20423083.08  4330.9604330.9569.7u−0.004Fe iM
201023082.71  4331.0294331.0533.5w+ 0.024CH—B
22221023074.38*4332.5934332.5836.7uN−0.010Cr i—CHB
21} 10 {23071.8923071.364333.0614333.0512.8u−0.010CH Fe i pB
214333.1604333.2063.2u+ 0.046Ni i? CH?B
23231223060.07*4335.2824335.2747.6u−0.008CHP
33?23046.10  4337.9094337.92524.0w+ 0.016Ti iiM
3M23045.62  4338.000A
24248?23042.30*4338.6254338.6273.2+ 0.002CHP
33423040.32*4338.9984339.0102.3u+ 0.012CHP
25623020.97  4342.645A
25223020.54  4342.726A
44?23019.34  4342.9524342.9901.7u?+ 0.038CH?P
4(CH)23018.16*4343.1754343.21615.0ud*+ 0.041Cr i Fe i pM
4(CH)23015.42*4343.6924343.70518.6u+ 0.013Fe iM
4M23014.66  4343.8354343.8540.8+ 0.019CH—Fe i pB
264?22996.59  4347.2494347.2429.9s−0.007Fe iM
264?22995.86  4347.3864347.3700.8−0.016—CHB
5M22993.38  4347.8554347.84115.4w?−0.014Fe iM
5M22992.02  4348.1134348.1042.5−0.009CHP
5M22990.15  4348.4664348.4922.3u+ 0.026CHP
5422989.26  4348.6354348.6361.7u+0.001CHP
6422967.77  4352.7044352.74332.6s+ 0.039Fe iM
6} 2 {22965.7822965.274353.0814353.0532.5−0.028CHP
64353.1774353.1726.9o?−0.005—CHB
6322963.88  4353.4414353.4352.3uN— 0.006CHP
7422942.48  4357.5024357.5148.7+0.012Cr i Fe i pFe i pM
77722940.47*4357.8834357.8695.5u−0.014CHP
7322938.68  4358.2244358.1708.7s−0.054Nd iiM
822917.66  4362.2214362.2165.5u−0.005CHP
822915.87*4362.5624362.53312.1w?−0.029—CHM
822914.81*4362.7644362.74610.3u−0.018CHM
822913.71  4362.9744362.9533.9u−0.021Cr i Cr iiM
922892.74  4366.970A
922891.49  4367.2084367.1952.5−0.013Ni i—CHB
922889.92*4367.5084367.4755.7u−0.033CHP
922888.68*4367.7454367.7233.2−0.022CHM
1022868.46  4371.6064371.5822.7−0.024CHP
1022867.24  4371.8404371.7944.1u−0.046M
1022864.72  4372.3224372.3356.2sd*+ 0.013CH—B
1022863.79  4372.5004372.4933.0−0.007CHP
1122844.21  4376.2474376.2165.2−0.031CHP
1122843.32  4376.4184376.4055.7−0.013CHP
1122839.67  4377.1174377.0872.7−0.030CHP
1122838.96*4377.2534377.23419.9−0.019CHM
1222820.27*4380.8384380.8529.6wN+ 0.014CH—M
1222819.45  4380.9964380.9902.7ut−0.006CHP
1222814.66  4381.9154381.8853.0u−0.030CHP
1222814.24  4381.9964381.9892.5u−0.007CH—Fe iB
13622796.15  4385.473A
13622795.43  4385.6124385.6112.5−0.001CHP
13131222789.68*4386.7184386.6945.2uN−0.024CHP
14422772.02  4390.1204390.1142.7−0.006CHP
14422771.50  4390.2214390.2223.6w+ 0.001CHP
141420?22764.84*4391.5054391.4888.6−0.017CHP
1522747.67  4394.820} 4394.85211.6s {+0.0320.027} Ti iM
1522747.36*4394.879
151522739.85*4396.3314396.3098.2−0.022CHM
1622723.53  4399.4884399.4823.6s−0.006CH?P
1622723.29  4399.535A
161622714.65*4401.209A
171722698.72*4404.2974404.27712.0u−0.020|Ti i—CHM
171722689.14*4406.1574406.1575.7u0.000CH V iB
181822673.67*4409.1634409.12811.6u−0.035Fe iM
1822663.07*4411.226} 4411.2275.4uN {+0.0010.038CH—CH?B
1822662.87  4411.265
191922648.10*4414.1424414.1244.3u−0.018—CH?B
1922636.64  4416.3774416.3602.9−0.017—CH?B
1922636.20  4416.4624416.4758.2Sd?+ 0.013‖V i—Ti i?M
202022621.65*4419.3034419.2733.6−0.030Fe i pM
2022609.31  4421.7154421.7637.7s+0.048Ti iM
2022608.76  4421.823A
212122594.30*4424.653A
2122580.76  4427.3054427.31734.6S+ 0.012Fe iM
2122580.24  4427.407A
222222565.75*4430.250A
2222551.22  4433.105A
2222550.46  4433.2544433.23022.3u−0.024Fe iM
2322520.17  4439.217A
2322519.35  4439.3794439.3584.3−0.021M
2422487.19  4445.728A
2422486.45  4445.8744445.8491.1u−0.025Zr ii?A
2522452.10  4452.677A
2522451.15  4452.865A
2622414.34  4460.178A
2622413.37  4460.3714460.3616.3−0.010Mn iM
2722373.38  4468.343A
2722372.25  4468.569A
Open in a separate window

Table 7

CH in the Solar Spectrum B 2Σ—X 2Π (0, 0)
LaboratorySun

P1P2Q1Q2R1R2IntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
72525823.373871.3633871.392226   +0.029CN (CH)M
62725822.183871.5423871.56324.5+0.021CH CN—Ni iB
73425821.353871.6663871.65115.7−0.015La ii CHB
83325820.643871.7733871.75841.8−0.015Fe i (CH)M
63025819.843871.8933871.90314.4+0.010CHP
B
83025818.733872.0593872.06225.8+0.003CN CHB
52025817.233872.2843872.27320.9−0.011|CN—CHB
52725814.513872.6923872.73231.8+0.040|CN V i? CH?B
92625813.613872.8273872.83421.9+0.007CHP
92725811.973873.0733873.09030   +0.017CH—B
41625808.783873.5523873.57520.9+0.023CN CH?B
42125805.463874.0503874.06047.6+0.010Fe i (CH)M
102425802.183874.5433874.52423.4−0.019—CHB
102625800.653874.7733874.77622.4+0.003CH CNB
31325797.093875.3083875.29024.5−0.018Ti i—CNM
31725792.773875.9563875.94819.3−0.008CN—CHB
112425785.973876.9783876.97826.90.000CN—CN (CH)M
112525784.563877.1913877.19819.1+0.007CHP
2825782.803877.4553877.45119.1−0.004CN CHB
21225776.443878.4123878.41233.20.000CH CN—CNB
1425774.083878.7683878.74761.9−0.021Fe i|V ii CNM
122225764.703880.1803880.19025.7+0.010CHP
122325763.373880.3803880.39422   +0.014CN (CH)M
1825756.063881.4823881.4903.2+0.008CHP
132025737.873884.2253884.22210.8−0.003CHP
P
132025736.603884.4163884.4409.5+0.024CHP
11025723.403886.4103886.42831.6+0.018CH—B
22025706.873888.9093888.93820.8+0.029CHP
114 }27 {25705.5225705.083889.1133889.10539.4−0.008CHP
3889.1803889.23114.7+0.051CH—B
P
141825703.823889.3703889.35822.1−0.012CH Fe iB
23125700.663889.8483889.84822.10.000CHP
1525698.253890.2133890.19616.4−0.017V i—Mg i?M
32925695.993890.5553890.56816.7+0.013‖CH—Nd iiB
33925691.813891.1883891.19820.4+0.010CHP
43825682.603892.5843892.59116.4+0.007CHP
120?25680.353892.9253892.89826.2−0.027|Fe i V i (CH)M
44725679.403893.0693893.07430.3+0.005CHP
515 }49 {25666.1625665.633895.0773895.08821.2+0.011CH—Ce iiB
3895.1573895.16712.6+0.010CHP
1520?25664.453895.3373895.33419.3u−0.003CH—B
55425663.663895.4573895.44842.3u−0.009Fe i p—CH|B
21325656.613896.5273896.5345.9+0.007Zr i? CH?B
21825650.293897.4873897.45828.4u−0.029Fe i (CH)M
65125646.443898.0723898.09418.7s*+0.022CHP
65825644.343898.3913898.39422.4u+0.003CHP
75525623.253901.6003901.59820   u−0.002CHP
76525621.543901.8603901.86621.4u+0.006CHP
325?25620.873901.9623901.97713.3u+0.015CH—Cr iB
16625618.963902.2533902.26221.5s+0.009V i (CH)M
16725617.863902.4213902.43014.9u+0.009Gd ii—CHB
32325616.583902.6163902.63215.9+0.016CHP
85925596.573905.6673905.67946.1+0.012|CH Fe i pB
86425595.023905.9043905.90525.9u+0.001CHP
42325582.803907.7703907.77412.8u+0.004Cr i CHB
42725579.533908.2683908.27413.8+0.006CHP
95925566.073910.3273910.33424.3+0.007CHP
96425564.663910.5423910.53430.4−0.008CHP
17M25563.943910.6533910.66716u+0.014M
17125562.813910.8253910.84926.1u+0.024Fe iM
52825542.013914.0103914.01316.6+0.003CHP
53225539.323914.4223914.42626.1u+0.004CHP
105925531.633915.6013915.61223   +0.011CHP
106325530.363915.7963915.81132s?+0.015CH—Cr iB
6183025498.303920.7203920.72927.8u+0.009CH—B
63325496.003921.0733921.04942.1s−0.024Cr i (CH)M
115725492.923921.5473921.55627.8w+0.009CHP
115925491.853921.7123921.71626.8u+0.004CHP
73225451.423927.9413927.933159   S−0.008Fe i (CH)M
7128625449.63*3928.2183928.21749.4u−0.001CHP
126325448.803928.3463928.34532.8−0.001CHP
8138025401.73*3935.6253935.64531   uN+0.020CHP
1365?25401.033935.7343935.73180.00CHP
83825399.723935.9373935.97959.4s+0.042Co i (CH)M
1465?25348.773943.8483943.82039.6uN−0.028CHP
9147825348.16*3943.9433943.9188.9−0.025Ce ii—CH|B
93725346.653944.1783944.17933.1uN+0.001|CH—B
103425291.713952.7463952.7566.3+0.010CHP
10157925290.26*3952.9733952.98228   s*+0.009CHP
1550?25289.463953.0983953.08412.5o?−0.014CHP
113325231.543962.1723962.18421.4u+0.012CH—B
1135.525230.123962.3953962.3988.8+0.003CHP
16} 36 {25225.4625224.933963.1273963.11544.9u−0.012Fe i (CH)M
163963.2113963.23328.5u+0.022CHP
123125167.583972.2423972.26715.8w?+0.025CHP
123225166.263972.4503972.4413.3uN−0.01Co i CHB
17} 18 {25153.8925153.483974.4043974.39627.3u−0.008Fe i (CH)M
173974.4693974.49725.9u+0.028CH—B
1327.525099.633982.9963983.00815.3+0.012CH—B
133025098.413983.1903983.19916.5u+0.009CH—B
18} 4 {25074.4625074.173986.994}3986.99413.7uN {0.0000.046CH—B
183987.040M
142525027.293994.5093994.51417.6u+ 0.005CH—Co i|B
142625026.133994.6933994.68316.5u−0.010Ti i Nd ii CHB
1924986.234001.0744001.1106.0+ 0.036A
152024950.244006.8454006.82510.5uN−0.020—CHB
152124949.164007.0184006.99714.5u−0.021CHP
1617.524868.314020.0464020.0298.5u?−0.017—CHB
161824867.274020.2144020.19310.7u−0.021—CHB
171324780.764034.2494034.23212.9u−0.017—CHB
171324779.744034.4154034.3869.9−0.029CHP
186.524686.904049.5874049.56510.1u−0.022CHP
185.524685.914049.7504049.73111.6u−0.019CHP
1924585.824066.2374066.2206.4u−0.017—CHB
1924584.864066.3964066.37318.7s−0.023Co iM
2024476.394084.417A
Open in a separate window*Blend.Satellite line as follows:
DesignationJLaboratory
Wave numberWavelength
PQ 12125698.253890.213
Open in a separate window

Table 8

CH in the Solar Spectrum B 2Σ—X 2Π (1, 0)
LaboratorySun

P1P2Q1Q2R1R2IntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λ⊙—lab. ASolar identificationNotes
30.927561.60  3627.2023627.1695   −0.033B
2, 11.027559.78  3627.4423627.4563.2+0.014CHP
4} 1.9 {27558.3127557.743627.635  3627.62311.3−0.012Mg i? CHB
33627.710  3627.7150.7+0.005V ii Ti iiM
41.527554.95  3628.0783628.09821.8+0.020Fe iM
20.927553.45  3628.2753628.2796.8+0.004CHP
51.427548.01  3628.9923629.0064.4+0.014CHP
51.827545.17  3629.3663629.3524.4−0.014CHP
10.727542.25  3629.7513629.73714   −0.014Mn iM
61.227530.49  3631.3013631.26545.4−0.036A
61.527528.25  3631.5963631.58631.2−0.010M
11.027515.40  3633.2923633.3086.6+0.016CHP
71.127505.35  3634.6203634.6185   −0.002CHP
71.027503.40  3634.8783634.8655.1−0.013CHP
11.527497.52  3635.6553635.6524.7−0.003Ti i p? CHB
122.127492.88*3636.2693636.23816.5−0.031Fe iM
22.327486.64  3637.0943637.05810.7−0.036Fe iM
11.127475.26  3638.6013638.6052   +0.004CHP
32.427472.90  3638.9133638.9054.4−0.008CHP
8M27472.28  3638.9963639.0309.1+0.034V iM
8M27470.15  3639.2773639.28514.3+0.008M
32.927468.73  3639.4663639.45018.7−0.016Co iM
2M27448.48  3642.1513642.14722.8−0.004—CHB
42.927447.38  3642.2973642.2815.9−0.016CHP
43.627444.25  3642.7123642.68231.8−0.030Ti iM
21.527442.25  3642.9783642.9715.4−0.007CHP
90.1?27429.39  3644.6863644.69515.8+0.009Cr iiM
90.1?27428.09  3644.859A
53.227415.56  3646.5253646.5046.6−0.021CHP
53.927413.08  3646.8553646.8379.9−0.018—CHB
31.327406.76  3647.6963647.66959.6−0.027Co iM
31.827402.50  3648.2633648.22814   −0.035Fe i p—CHB
63.627377.09  3651.6493651.65428   +0.005Ni i Cr iiM
64.027375.02  3651.9253651.92125.6−0.004—CHB
41.827359.76  3653.9623653.97920.2+0.017Fe iM
42.127356.49  3654.3983654.3865.1−0.012CHP
73.527331.61  3657.7253657.71121.2−0.014Ni i Fe i|M
73.627329.83  3657.963A
52.127306.82  3661.0463661.03810.4−0.008CHP
52.327304.15  3661.4043661.37222.6−0.032Sm ii Fe i—V iiM
82.227278.56  3664.8393664.82813−0.011CHP
82.327277.08  3665.0383665.02813.9−0.010—CHB
62.227247.74  3668.9843668.96923   −0.015Ti iM
62.627245.47  3669.2903669.24435   −0.046Ni iM
91.027217.46  3673.0663673.08732.7+0.021Fe iM
91.027216.18  3673.2393673.22617.2−0.013—CHB
72.427182.16  3677.8363677.85538.5+0.019Cr iiM
72.627180.21  3678.1003678.10012.90.000CHP
82.227109.90  3687.6403687.66041.7+0.020Fe iM
82.527108.14  3687.8783687.8667.6−0.012CHP
91.227030.43  3698.4823698.4777.3−0.005—CHB
91.227028.86  3698.6973698.6946.8−0.003CHP
100.526942.95  3710.490A
100.526941.64  3710.6703710.63810.8−0.032
Open in a separate window*Blend.Satellite line as follows:
DesignationJLaboratory
Wave No.Wavelength
PQ 1 2127492.883636.269
Open in a separate window

Table 9

CH in the Solar Spectrum B 2Σ— X 2Π (1, 1)
LaboratorySun

P1P2Q1Q2R1R2IntensityWave number cm−1Wavelength AWavelength ADisk int. Δλ/λSpot⊙—lab. ASolar identificationNotes
41   24835.75  4025.3164025.3083.5−0.008CHP
32   24835.22  4025.4024025.42911.9u+0.027|Ni i Cr iM
42   24832.45  4025.8514025.82315.9u−0.028M
353.524830.76*4026.1254026.16810.7sd+0.043Cr iM
20.524829.60  4026.3134026.3101.7−0.003CHP
512.524828.06*4026.5624026.54210.4s−0.020Ti iM
21   24823.62  4027.2834027.2512.4s−0.032Zr i—CHB
60.524819.66  4027.9264027.9437.0u+0.017CH—B
60.524817.25  4028.3174028.34622.3u+0.029Ti iiM
10.524810.17  4029.4664029.4432.5u−0.023CHP
70.524801.91  4030.8084030.76353.1S−0.045Mn iM
70.524799.95  4031.1274031.1164.2u−0.011Cr iM
10.524783.46  4033.8094033.7902.4u−0.019CHP
1224765.72  4036.6994036.6701.5−0.029CHP
2224762.79  4037.1774037.12110.9u−0.056M
10.524761.26  4037.4264037.4381.2+0.012CHP
23.524756.88  4038.1404038.1243.2s−0.016M
33.524746.14  4039.8934039.8642.2s−0.029M
11.524743.41  4040.3394040.3104.0s—.0.029Ti i—CHB
34   24742.16  4040.5434040.5146.9u−0.029—CHB
44.524724.98  4043.3504043.3465.9uN−0.004CHP
44.524721.89  4043.8564043.90622.0u+0.050Fe iM
20.524718.50  4044.4104044.3801.7−0.030CHP
21   24712.51  4045.3914045.39025.0u−0.001Co iM
54   24698.42  4047.6994047.6735.4s−0.026Y i—CHB
55   24696.01  4048.0934048.0725.9u−0.021—CHB
31   24680.01  4050.7184050.68014.1u−0.038Fe iM
32   24675.90  4051.392A
64   24666.30  4052.9694052.9407.9u−0.029Ti i—CHB
65   24664.35  4053.2904053.27115.0u−0.019Fe iM
42   24637.26  4057.7474057.7333.2−0.014CHP
43   24634.33  4058.2294058.22124.9s−0.008Co i Fe iM
73.524628.23  4059.2344059.2225.7u−0.012CHP
74   24626.54  4059.5134059.5025.7u−0.011CHP
54   24589.48  4065.6324065.5873.7u−0.045Ti i CHB
53.524587.06  4066.0324066.0043.0u−0.028Fe i p—CHB
82   24583.70  4066.5884066.59019.7u+0.002Fe iM
83   24582.18  4066.8394066.8207.6u−0.019CHP
62.524536.85  4074.3524074.3324.4sN−0.020Ti i W iM
63   24534.69  4074.7114074.68414.0u−0.027Fe i pM
91.524532.00  4075.1584075.10315.2u−0.055M
90.524530.85  4075.3494075.3167.6uN−0.033—CHB
73   24478.67  4084.0364083.9994.9u−0.037CH?P
73.524476.75  4084.3574084.3276.4u−0.030CHP
82.524414.86  4094.7104094.6985.9u−0.012CHP
82.524413.13  4095.0004094.93825.4s−0.062Ca iM
91   24344.81  4106.4934106.43219.5u−0.061Fe iM
91   24343.31  4106.7464106.7303.8u−0.016CHP
100.324268.04  4119.4834119.5267.1s+0.043Fe ii pM
100.324266.88  4119.6804119.6715.6sd?−0.009Fe i p—CHB
Open in a separate window*Blend.Satellite line as follows:
DesignationJLaboratory
Wave No.Wavelength
PQ 1 2124761.264037.426
Open in a separate windowUnder the general heading, “Sun,” the solar wavelengths are from the new solar ledger now in course of preparation. These wavelengths differ slightly from those published in 1928, because a running correction has since been made to reduce them to the 1928 International Solar Standards [11]. In addition, some new measurements have been averaged in for a number of lines. This work is in progress for the region short of 4000 A. Consequently, some solar wavelengths quoted in the present paper may differ slightly from those in the final solar ledger. The changes are so slight that they will not likely affect the CH identifications.The second solar column contains the reduced equivalent widths of the solar lines furnished by Minnaert and his colleagues at the Utrecht Observatory. The equivalent widths have been measured in milliangstroms (mA) from the Utrecht Solar Atlas [12]. The tabular entries have been reduced from the measured values by dividing by X, and by allowing for the effect of blending when there is more than one contributor effective in producing the solar line. Details of the method are described by Minnaert in his 1951 paper [13]. These measured intensities replace the Rowland eye estimates for all solar lines except those in and11.11. In this spectral region the measured intensities have not yet been completed, and in their place the Rowland estimates are entered in brackets, —3 being substituted for Rowland’s 0000, 2 for 000, etc., as was done in 1928 [1].In the solar column headed, “Spot,” the intensity behavior of the solar atomic lines in the spot spectrum is described as follows:
ddoubleSgreatly
Ndiffusestrengthened
NNvery diffuseuunchanged
oobliteratedwweakened
sstrengthenedWgreatly weakened
These letters have been substituted for the estimated spot intensities published in more detail in 1933 [14]. Although the spot behavior was studied especially for atomic lines, in many cases it was noted in the 1933 paper when a line was a blend of an atomic and a molecular line in the spot spectrum as judged by the observed Zeeman effect, and the molecular contributor has turned out to be CH. An asterisk in this column indicates that the spot behavior refers to two adjacent solar lines; i.e., two disk lines are blended in the spot spectrum.Following the spot column there is one headed “⊙–lab.” This is the difference, expressed in A, between the solar and laboratory wavelengths, another criterion used in making the identification of the solar line. Residuals greater than ±0.030 A are tolerated only if the solar line is very faint or blended, and in either case the CH identification is subject to question.The next column gives the final adopted solar identification. Here the symbol |, preceding or following the chemical symbol, indicates that the line so marked is a stronger contributor to the solar line than other contributors. The symbol ‖ denotes a predominant contributor. Parentheses are used in this column for lines masked in the solar spectrum. Only the more important masked CH lines are thus noted in the tables. For those CH lines marked (CH) or (M) in the laboratory intensity column, if the solar identification refers to the CH line responsible for the masking, M is entered in the last column (see below).In the last column four letters are used to indicate the judgment of the authors regarding the assigned identifications of the solar lines. They are as follows: The present paper is one of a series planned to include the data on individual molecules present in the sun. A general survey of the molecular program was presented by the authors in Liège in 1956 [15]. It is hoped that the format adopted in the present tables may serve as a guide to those interested in preparing papers on molecular spectra in a style useful for astrophysical purposes.The authors are most grateful to Mrs. Isabel D. Murray for her very accurate and painstaking work in helping to prepare the tables.  相似文献   
9.
Closing address to the 5th IFAC congress     
Victor Broida 《Automatica》1973,9(1):3-5
  相似文献   
1
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