Enhancing electrochromic properties of polypyrrole by silsesquioxane nanocages

A new monomer, octa(thiophenephenyl)silsesquioxane (OThiophenePS) was synthesized via click chemistry. The chemical structure of OThiophenePS was characterized by nuclear magnetic resonance (¹H NMR) and Fourier transform infrared (FT-IR) spectroscopies. Electrochemical polymerization of pyrrole with OThiophenePS was performed resulting in polypyrrole-attached, polyhedral oligomeric silsesquioxane (OPS–PPy). The spectroelectrochemical studies show that the electrochromic properties of (OPS–PPy) are superior to those of polypyrrole (PPy). This great improvement can be attributed to the more accessible doping sites and the facile ion movement during the redox switching brought by the loose packing of the PPy chains.     

A new deep intuitionistic fuzzy time series forecasting method based on long short-term memory

The Journal of Supercomputing - In recent years, deep artificial neural networks can have better forecasting performance than many other artificial neural networks. The long short-term memory...     

Maximization of total surface area of Pt-SnO<Subscript>2</Subscript>/Al<Subscript>2</Subscript>O<Subscript>3</Subscript> catalyst by the Taguchi method

The maximization of the total surface area of Pt-SnO₂/Al₂O₃ catalyst was studied by using the Taguchi method of experimental design. The catalysts were prepared by sol-gel method. The effects of HNO₃, H₂O and aluminum nitrate concentrations and the stirring rate on the total surface area were studied at three levels of each. L₉ orthogonal array leading nine experiments was used in the experimental design. The parameter levels that give maximum total surface area were determined and experimentally verified. In the range of conditions studied it was found that, medium levels of HNO₃ and H₂O concentration and lower levels of aluminum nitrate concentration and stirring rate maximize the total surface area.     

Improved phase performance for rotman lens

Rotman lenses are used to obtain multiple beams from a single array. Although the beams produced by the feed antennas at focal points have no path length errors, the beams produced by feed antennas at off focal points may have large path length errors. These path length errors cause deterioration in the multiple beams. In this article, two novel methods are introduced to obtain feed curves which reduce the path length errors of off focal feed points significantly, compared with the commonly used circular and elliptical feed curves. The first method obtains feed curve points based on having zero path length error at three chosen points of the radiating array for each beam direction. The second method uses the particle swarm optimization method for obtaining optimum feed points for each beam direction. The results show that there is a very significant drop in the level of the maximum path length errors (in the order of about 1:4). © 2012 Wiley Periodicals, Inc. Int J RF and Microwave CAE 23: 634–638, 2013.     

A multiperiod set covering location model for dynamic redeployment of ambulances

Emergency medical service (EMS) providers continually seek ways to improve system performance particularly the response time to incidents. The demand for ambulances fluctuate throughout the week, depending on the day of week, and even the time of day, therefore EMS operators can improve system performance by dynamic relocation/redeployment of ambulances in response to fluctuating demand patters. The objective of the model is to determine the minimum number of ambulances and their locations for each time cluster in which significant changes in demand pattern occur while meeting coverage requirement with a predetermined reliability. The model is further enhanced by calculating ambulance specific busy probabilities and validated by a comprehensive simulation model. Computational results on experimental data sets and data from an EMS agency are provided.     

Using fuzzy inference system for architectural space analysis

Though architectural space is the main source and the only indispensable component of any architectural construction, in many cases its boundaries are uncertain, leading intuitive spatial design. Creating a mathematical model of architectural space with concrete results will offer many possibilities for design process in analysing spatial organization, independently from in architect's experience and intuitions. This paper presents a fuzzy inference system based spatial analysis model for spatial analysis for architectural design which brings many advantages to design process. The aim of this article is to investigate the potential of a fuzzy system with a Mamdami inference engine, considering different numbers of membership functions. Two venues have been selected and the fuzzy inference system based spatial analysis model is applied. For better judgement, outcomes of the model have been compared to depthmap analysis model. The results of the model indicate that fuzzy inference system based spatial analysis model performs very well, even with the limited and imprecise data. Such prototype can evolve into a tool for identifying spatial formations for improvements during the architectural design process.     

Visualization of fibrous and thread-like data

Thread-like structures are becoming more common in modern volumetric data sets as our ability to image vascular and neural tissue at higher resolutions improves. The thread-like structures of neurons and micro-vessels pose a unique problem in visualization since they tend to be densely packed in small volumes of tissue. This makes it difficult for an observer to interpret useful patterns from the data or trace individual fibers. In this paper we describe several methods for dealing with large amounts of thread-like data, such as data sets collected using Knife-Edge Scanning Microscopy (KESM) and Serial Block-Face Scanning Electron Microscopy (SBF-SEM). These methods allow us to collect volumetric data from embedded samples of whole-brain tissue. The neuronal and microvascular data that we acquire consists of thin, branching structures extending over very large regions. Traditional visualization schemes are not sufficient to make sense of the large, dense, complex structures encountered. In this paper, we address three methods to allow a user to explore a fiber network effectively. We describe interactive techniques for rendering large sets of neurons using self-orienting surfaces implemented on the GPU. We also present techniques for rendering fiber networks in a way that provides useful information about flow and orientation. Third, a global illumination framework is used to create high-quality visualizations that emphasize the underlying fiber structure. Implementation details, performance, and advantages and disadvantages of each approach are discussed.     

A gantry-based tri-modality system for bioluminescence tomography

A gantry-based tri-modality system that combines bioluminescence (BLT), diffuse optical (DOT), and x-ray computed tomography (XCT) into the same setting is presented here. The purpose of this system is to perform bioluminescence tomography using a multi-modality imaging approach. As parts of this hybrid system, XCT and DOT provide anatomical information and background optical property maps. This structural and functional a priori information is used to guide and restrain bioluminescence reconstruction algorithm and ultimately improve the BLT results. The performance of the combined system is evaluated using multi-modality phantoms. In particular, a cylindrical heterogeneous multi-modality phantom that contains regions with higher optical absorption and x-ray attenuation is constructed. We showed that a 1.5 mm diameter bioluminescence inclusion can be localized accurately with the functional a priori information while its source strength can be recovered more accurately using both structural and the functional a priori information.     

Sink placement on a 3D terrain for border surveillance in wireless sensor networks

With their distributed nature and redundant operation capability, wireless sensor networks are very suitable for border surveillance scenarios that track intruders trying to breach to a safe side. In such scenarios, keeping the operation going on for as long as possible is the most important aspect of the network. We propose that by placing sink at a carefully selected coordinate will results in a longer living network. We also place restrictions on the candidate locations so that the sensing quality of the network is above a useful predetermined value and the sink is placed in a relatively safe location to avoid destruction. In order to find the suitable coordinates we propose a modified lifetime metric which takes quality and safety measures into account. We also propose a genetic algorithm which uses a discrete event simulator-in-the-loop over a three dimensional terrain to find locations for the sink that fits the given quality and safety restrictions. Using a three dimensional underlying terrain makes the proposed approach more realistic. The results obtained for various sensor network scenarios indicate that the proposed algorithm can find locations that increase the lifetime by also considering the sensing quality and safety.