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1.
2.
Marcia Cristina Kaezer Fran a Rosane Aguiar da Silva San Gil Jean-Guillaume Eon 《Catalysis Today》2003,78(1-4):105-115
γ-Al2O3 supported vanadium oxides were modified by tungsten and molybdenum oxides in order to improve dispersion and selectivity towards olefins in propane oxidative dehydrogenation (ODH). Both vanadium–tungsten and vanadium–molybdenum catalysts were obtained by adsorption of mixed isopolyanions (VW5O195−, V2W4O194−, VMo5O195− and V2Mo4O194−) from aqueous solutions. The isopolyanion solutions were characterized by UV-Vis and 51V NMR spectroscopy. Vanadium, vanadium–tungsten and vanadium–molybdenum precursors and catalysts were also characterized by UV-Vis (diffuse reflectance) and solid state 51V NMR spectroscopy. An improved selectivity to propene in the presence of tungsten and molybdenum in VOx/γ-Al2O3 was observed and attributed to dilution of vanadium by tungsten or molybdenum oxides on the γ-Al2O3 surface. 相似文献
3.
I. Belda X. Llorà E. Giralt 《Soft Computing - A Fusion of Foundations, Methodologies and Applications》2006,10(4):295-304
One of the goals of computational chemistry is the automated de novo design of bioactive molecules. Despite significant progress
in computational approaches to ligand design and efficient evaluation of binding energy, novel procedures for ligand design
are required. Evolutionary computation provides a new approach to this design issue. This paper presents an automated methodology
for computer-aided peptide design based on evolutionary algorithms. It provides an automatic tool for peptide de novo design,
based on protein surface patches defined by user. Regarding the restrictive constrains of this problem a special emphasis has been made on the design of the
evolutionary algorithms implemented. 相似文献
4.
In this paper we describe, from a theoretical point of view, critical configurations for the projective reconstruction of
a set of points, for a single view, i.e. for calibration of a camera, in the case of projections from ℙk to ℙ2 for k ≥ 4. We give first a general result describing these critical loci in ℙk, which, if irreducible, are algebraic varieties of dimension k−2 and degree 3. If k=4 they can be either a smooth ruled surface or a cone and if k = 5 they can be a smooth three dimensional variety, ruled in planes, or a cone. If k≥ 6, the variety is always a cone, the
vertex of which has dimension at least k − 6. The reducible cases are studied in Appendix A.
These results are then applied to determine explicitly the critical loci for the projections from ℙk which arise from the dynamic scenes in ℙ3 considered in [13].
Marina Bertolini is currently Associate Professor of Geometry at the Department of Mathematics at the Università degli Studi di Milano, Italy.
Her main field of research is Complex Projective Algebraic Geometry, with particular interest for the classification of projective
varieties and for the geometry of Grassmann varieties. On these topics M. Bertolini has published more than twenty reviewed
papers on national and international journals. She has been for some years now interested also in applications of Algebraic
Geometry to Computer Vision problems.
Cristina Turrini is Associate Professor of Geometry at the Department of Mathematics of Università degli Studi di Milano, Italy. Her main
research interest is Complex Projective Algebraic Geometry: subvarieties of Grassmannians, special varieties, automorphisms,
classification. In the last two years she has started to work on applications of Algebraic Geometry to problems of Computer
Vision. She is author or co-author of about thirty reviewed papers. She is also involved in popularization of Mathematics,
and on this subject she is co-editor of some books. 相似文献
5.
O Bernard B Chachuat A Hélias B Le Dantec B Sialve J-P Steyer L Lardon P Neveu S Lambert J Gallop M Dixon P Ratini A Quintabà S Frattesi J M Lema E Roca G Ruiz J Rodriguez A Franco P Vanrolleghem U Zaher D J W De Pauw K De Neve K Lievens D Dochaine O Schoefs H Fibrianto R Farina V Alcaraz Gonzalez V Gonzalez Alvarez P Lemaire J A Martinez F Esandi O Duclaud J F Lavigne 《Water science and technology》2005,52(1-2):457-464
The TELEMAC project brings new methodologies from the Information and Science Technologies field to the world of water treatment. TELEMAC offers an advanced remote management system which adapts to most of the anaerobic wastewater treatment plants that do not benefit from a local expert in wastewater treatment. The TELEMAC system takes advantage of new sensors to better monitor the process dynamics and to run automatic controllers that stabilise the treatment plant, meet the depollution requirements and provide a biogas quality suitable for cogeneration. If the automatic system detects a failure which cannot be solved automatically or locally by a technician, then an expert from the TELEMAC Control Centre is contacted via the internet and manages the problem. 相似文献
6.
The characterization of new synthesized chiral polymeric membranes, based in polysulfone polymer is here reported. Polysulfone was derivatized to chiral polysulfone, by bonding covalently the chiral carrier, N-dodecyl-4(R)-hydroxy-l-proline, to the polymer matrix. Two different chiral polysulfones, referred to as CPSA and CPSB, have been synthesized and used in the preparation of chiral polymeric membranes. However, as a consequence of the limited CPSB solubility, only CPSA resulted adequate to obtain useful membranes. Therefore, various chiral polysulfone membranes containing different amounts of CPSA in unmodified polysulfone (PS) were prepared and properly characterized by scanning electron microscopy (SEM) and by enantioselective transport experiments of racemic propranolol. Dialysis transport experiments allowed us to determine the influence of the carrier content in the membrane on the transport rate and on enantiomer separation. Membranes containing a CPSA/PS ratio of 1:3 showed an alpha value of 1.1 at 96 h of performance. Modelling of the propranolol transport rate is also performed. 相似文献
7.
M Isabel Sánchez de Rojas Julián Rivera Moisés Frías Félix Marín 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(3):209-217
Copper slag is a by‐product generated during smelting to extract copper metal from the ore. The copper slag obtained may exhibit pozzolanic activity and may therefore be used in the manufacture of addition‐containing cements. In this paper the effect of the incorporation of the copper slag in cement is measured. Blends of copper slag with Portland cement generally possess properties equivalent to Portland cement containing fly ash, but very different to the silica fume incorporation. Copper slag and fly ash reduce the heat of hydration more effectively than silica fume in mortars. The replacement of 30% cement by copper slag reduces the flexural and compressive strength in a similar way to fly ash; however, after 28 days, the reduction is less than the percentage of substitution. Hydrated calcium aluminate phases were analysed using scanning electron microscopy (SEM) and X‐ray diffraction (XRD) techniques. The pozzolanic activity of copper slag is similar to that of fly ash and higher than silica fume. In the presence of low water/cement ratios, certain pozzolanic materials produce a very compact cement paste that limits the space available for hydration products, a determining factor in the formation of hydrated calcium aluminates. SEM was found to be a useful analytical technique when aluminates are formed and can be clearly detected by XRD. Copyright © 2008 Society of Chemical Industry 相似文献
8.
GM Gazzaniga G Angelini G Pastorino E Santoro M Lucchini ML Dal Prà 《Canadian Metallurgical Quarterly》1993,78(3):271-275
Four hundred forty-six patients with Tourette Syndrome (TS) and/or their parents completed a 52-item self-report survey about vocal and motor tics, and the frequency of associated co-morbid conditions of aggression, obsessions and compulsions, attentional problems, sleep disturbance, mood disturbance, anxiety, and self-mutilative behaviours which have been frequently reported in the literature on TS. Respondents also responded to an open-ended question regarding the most disabling aspects of TS. Results were analyzed within two age groups; under 18 years of age (N = 245) and 18 years of age or older (N = 177). Tics and associated conditions were the most frequently reported disabling aspect by both age groups. Subjects under age 18, however, reported significantly more frequent problems with hyperactivity, temper control, aggressive behaviours and sleepwalking than adults with TS. 相似文献
9.
EH Eddes AM Masclee HG Gooszen M Fr?lich CB Lamers 《Canadian Metallurgical Quarterly》1997,174(4):387-392
Two mobilizable cloning vectors, designated pABW1 and pAWB2, were constructed basing on the E. coli vector pBGS18 and oriT originating from RK2. In pABW2 the kanamycin resistance gene was replaced by a novel tetracycline resistance cassette derived from Tn1721. Both vectors, specific for E. coli, allow to perform the cloning steps in E. coli and then to efficiently transfer the constructs by conjugation to the host of choice. A vector which cannot propagate in the given host can be applied for identification of the host specific plasmid replicator regions. With the use of pABW2 we defined the minimal replicator region of pTAV202-a mini-derivative of the large pTAV1 plasmid of P. versutus. We also proved that RepC' encoded on this fragment is the principal initiator replication protein and that oriV is located along its coding sequence. 相似文献
10.
Batch process industries are characterized by complex precedence relationships between operations, which renders the estimation
of an acceptable workload very difficult. A detailed schedule based model can be used for this purpose, but for large problems
this may require a prohibitive large amount of computation time. We propose a regression based model to estimate the makespan
of a set of jobs. We extend earlier work based on deterministic processing times by considering Erlang-distributed processing
times in our model. This regression-based model is used to support customer order acceptance. Three order acceptance policies
are compared by means of simulation experiments: a scheduling policy, a workload policy and a regression policy. The results
indicate that the performance of the regression policy can compete with the performance of the scheduling policy in situations
with high variety in the job mix and high uncertainty in the processing times.
Correspondence to: C.V. Ivanescu 相似文献