Study of the High‐Pressure Vapour‐Liquid Equilibria for Strongly Non‐ideal Binary and Ternary Mixtures

High‐pressure vapour‐liquid equilibria for binary and ternary high polar and asymmetric systems are calculated using the Peng‐Robinson‐Stryjek‐Vera equation of state coupled with the Twu‐Coon (TWMR), the Orbey‐Sandler (OSMR) and the Wong‐Sandler (WSMR) mixing rules. Modified UNIFAC model is used for determining the activity coefficient and excess Gibbs free energy. The calculated results are compared with the experimental data and good agreement is observed. The average absolute deviation percents (AAD%)s indicated that the WSMR has less AAD% than other mixing rules in most of cases.     

Application of artificial intelligence to improve quality of service in computer networks

Resource sharing between book-ahead (BA) and instantaneous request (IR) reservation often results in high preemption rates for ongoing IR calls in computer networks. High IR call preemption rates cause interruptions to service continuity, which is considered detrimental in a QoS-enabled network. A number of call admission control models have been proposed in the literature to reduce preemption rates for ongoing IR calls. Many of these models use a tuning parameter to achieve certain level of preemption rate. This paper presents an artificial neural network (ANN) model to dynamically control the preemption rate of ongoing calls in a QoS-enabled network. The model maps network traffic parameters and desired operating preemption rate by network operator providing the best for the network under consideration into appropriate tuning parameter. Once trained, this model can be used to automatically estimate the tuning parameter value necessary to achieve the desired operating preemption rates. Simulation results show that the preemption rate attained by the model closely matches with the target rate.     

Rapid Synthesis of Cobalt Metal Organic Framework

Metal-organic framework (MOF) has been shown to potential applications due to the high porous hybrid structure. Cobalt MOF was synthesized rapidly by ultrasound energy with about 3,000 m²/g surface area by BET method. Furthermore, this component is crystalline with significant thermal stability, on account of X-ray diffraction and thermal analysis, respectively. Based on high roughness, crystallinity, and unreported type of FTIR spectrum, a new structure of Co-MOF structure was proposed.     

Utilisation of iron ore mine tailings for the production of geopolymer bricks

This study presents a methodology for making bricks, in a cost-effective and environmentally friendly manner, using the tailings produced from iron ore mines in Western Australia (WA). The study was based on the geopolymerisation process, which is known to conserve energy by reducing the emission of greenhouse gases. The reduction is accomplished by avoiding the processes of high temperature kiln firing, traditionally utilised when making bricks from sandy soils with high clay content. In this study, the sodium silicate was added to the mine tailings in powder form, as an activator for the formulation of the geopolymer bricks. The effects of the initial setting time, curing temperature, curing time and activator content on the unconfined compressive strength (UCS), water absorption and other durability properties of the bricks were investigated. X-ray diffraction analysis was performed to investigate the phase composition of the geopolymer bricks. The bricks achieved an UCS as high as 50.53 MPa for the optimum values of the parameters. Technically, the geopolymer bricks that were produced met both the American Society of Testing and Materials and the Australian Standards (AS) requirements for bricks. A cost analysis of the geopolymer bricks is also presented, and this shows that the cost of geopolymer bricks is lower than that of the commercial, fired clay bricks.     

Compatibilization mechanisms of nanoclays with different surface modifiers in UCST blends: Opposing effects on phase miscibility

The effects of organically modified and pristine nanoclays on the kinetics of thermodynamic equilibrium state attainment for semicrystalline binary blends of polyethylene (PE)/ethylene-vinyl acetate copolymer (EVA) have been investigated. Due to the non-equilibrium compatibilization mechanism, intercalated organoclay results in a slower rate of phase miscibility change at lower annealing temperatures, thereby worsening the PE/EVA compatibility state. In contrast to poorly dispersed pristine nanoclay, the homogeneous state is obtained at higher or equal rates by adding organoclay at higher annealing temperatures because of the dominant role of nanofiller equilibrium compatibilization mechanism. Phase diagrams of these UCST blends determined by a dynamic method shifts to higher temperatures by the incorporation of nanofillers and the unexpected reduction in miscibility window area is much more noticeable for nanocomposites having highly restricted molecular movements. This can verify that dynamic methods lose their efficiency for measuring the equilibrium phase diagram of polymer blends containing nanoparticles.     

Association Equation of State for Hydrogen-Bonded Substances

An association equation of state (AEOS) has been proposed for hydrogen-bonded compounds. To obtain this AEOS, the compressibility factor was assumed to consist of two parts: the physical part due to physical interactions of molecules; and the chemical part due to molecular association by hydrogen bonding of molecules. The physical part of the compressibility factor was represented by the MMM EOS for non-polar compounds proposed by Mohsen-Nia et al., Fluid Phase Equilib. 206 , 27-39 (2003), and the chemical part of the compressibility factor was deduced by proposing a molecular association model of infinite series.     

Efficient optimization of network protection design with <Emphasis Type="Italic">p</Emphasis>-cycles

The purpose of this paper is to consider network survivability designs that utilize the p-cycle, and to propose a novel ILP formulation for capacity design based on network fundamental cycles, as well as the available straddling links. Concepts of visible and hidden straddling links—which are essential components of the model presented herein—are also introduced. The proposed model caters for the case of joint optimization of a p-cycle network that can be solved without enumerating p-cycle candidates. In addition, the complexity of the proposed model is much less than any conventional model dealing with large size networks and suitable for the design of networks having multiple quality of protection (MQoP) service classes using mixed protection techniques.     

Measurement and correlation of the individual ionic activity coefficients of aqueous electrolyte solutions of KF,NaF and KBr

Ion selective electrodes were used to measure the activity coefficients of individual ions at 298.2 K in aqueous solutions of KF, KBr and NaF up to 3, 2 and 1 molal, respectively. The mean ionic activity coefficients of the electrolytes obtained from the values of individual ions show good agreement with values reported in the literature. The experimental results confirm that the activity coefficients are different for the anion and the cation in an aqueous solution of a single electrolyte. It is also confirmed that the deviation from ideality for each ion depends on its counterion. The Khoshkbarchi—Vera equation was used to correlate the experimental data.