Characterization of titania thin films grown by dip-coating technique

A dip-coating technique was employed to prepare anatase phase of titania thin films. Fluorine doped tin oxide substrates were used to prepare titania thin films. The samples were annealed at 550 °C for 18 h. X-ray diffraction results revealed the amorphous and anatase phases of TiO₂ for as-synthesized and annealed samples, respectively. The crystallite size of anatase TiO₂ thin films was almost 25 nm for annealed samples. UV–visible confirmed the energy band gap 3.86 and 3.64 eV for as-prepared and calcinated titania thin films. The reduction in the energy band gap could be due to the change in crystallization and agglomeration of small grains after calcination. The morphology of the prepared films was investigated by field emission scanning electron microscopy which demonstrated the agglomeration of spherical particles of TiO₂ with average particle size of about 30 nm. The molecular properties (chemical bonding) of the samples were investigated by means of Fourier Transform Infrared (FTIR) spectroscopy. FTIR analysis exhibited the formation of titania, functional group OH, hydroxyl stretching vibrations of the C–OH groups, bending vibration mode of H–O–H, alkyl C–H stretch, stretching band of Ti–OH, CN asymmetric band stretching, and C=O saturated aldehyde.     

Solving a bi-criteria permutation flow-shop problem using shuffled frog-leaping algorithm

Flow shop problems as a typical manufacturing challenge have gained wide attention in academic fields. In this paper, we consider a bi-criteria permutation flow shop scheduling problem, where the weighted mean completion time and the weighted mean tardiness are to be minimized simultaneously. Due to the complexity of the problem, it is very difficult to obtain optimum solution for this kind of problems by means of traditional approaches. Therefore, a new multi-objective shuffled frog-leaping algorithm (MOSFLA) is introduced for the first time to search locally Pareto-optimal frontier for the given problem. To prove the efficiency of the proposed algorithm, various test problems are solved and the reliability of the proposed algorithm, based on some comparison metrics, is compared with three distinguished multi-objective genetic algorithms, i.e. PS-NC GA, NSGA-II, and SPEA-II. The computational results show that the proposed MOSFLA performs better than the above genetic algorithms, especially for the large-sized problems.     

Energy use efficiency and economical analysis of almond production: a case study in Chaharmahal-Va-Bakhtiari province,Iran

The aim of this study was to analyse input–output energy and economical assessment of almond production in three age groups of orchards (group I 6–10, group II 11–15 and group III 16–20 years old) in Chahrmahal-Va-Bakhtiari province, Iran. Data for almond production were collected by administering questionnaire in face-to-face interviews from the orchards selected based on random sampling method during a 3-year period. The results showed that 57,027.13, 60,341.14 and 61,640.43 MJ ha^?1 energy was consumed by group I, group II and group III, respectively. The most energy input was consumed by electricity, followed by chemical fertilizer. Energy indices were calculated, and the results revealed that energy efficiency was 0.62, 1.12 and 0.81 in the triple groups of orchards, respectively. Economical assessment showed that total production cost of almond in group I, II and III was $4547.54, $5799.26 and $5687.05 ha^?1, respectively. In all orchard groups, the shares of variable and fixed production costs found to be same nearly. Net return for almond production was $14,516.22, $30,735.19 and $21,395.57ha^?1, respectively. According to the research results, it was concluded that although almond production in the study region was not an efficient process in terms of energy consumption, it was a profitable agricultural operation.     

Infrared thin layer drying of saffron (Crocus sativus L.) stigmas: Mass transfer parameters and quality assessment

Saffron is the most precious and expensive agricultural product. A dehydration treatment is necessary to convert Crocus sativus L. stigmas into saffron spice. To the best of our knowledge, no information on mass transfer parameters of saffron stigmas is available in the literature. This study aimed at investigating the moisture transfer parameters and quality attributes of saffron stigmas under infrared treatment at different temperatures(60,70, …, 110 °C). It was observed that the dehydration process of the samples occurred in a short accelerating rate period at the start followed by a falling rate period. The effective moisture diffusivity and convective mass transfer coefficient were determined by using the Dincer and Dost model. The diffusivity values varied from1.1103 × 10~(-10)m~2·s~(-1)to 4.1397 × 10~(-10)m~2·s~(-1) and mass transfer coefficient varied in the range of 2.6433 × 10~(-7)–8.7203 × 10~(-7)m·s~(-1). The activation energy was obtained to be 27.86 k J·mol~(-1). The quality assessment results showed that the total crocin content increased, when the temperature increased up to90 °C but, in higher temperatures, the amount of crocin decreased slightly. The total safranal content of the samples decreased slightly when drying temperature increased from 60 °C to 70 °C and then continuously increased up to 110 °C. Also, the amount of picrocrocin increased from 83.1 to 93.3 as the drying temperature increased from 60 °C to 100 °C.     

Nonlinear free vibration of temperature-dependent sandwich beams with carbon nanotube-reinforced face sheets

In this research, large amplitude free vibrations of a sandwich beam with stiff core and carbonnanotube (CNT)-reinforced face sheets are analysed. The distribution of CNTs across the thickness of the facesheets may be uniform or functionally graded. The equivalent single- layer theory of Timoshenko is used toconstruct the Hamiltonian of the beam under the von Kármán type of geometrical nonlinearity assumptions.A uniform temperature field through the beam is also included in the formulation. The Ritz method withpolynomial basis functions is used to discrete the equations of motion and establish the matrix representation ofthe governing equations. A nonlinear eigenvalue problem is obtained and solved using a standard continuationprocedure. After validating the developed solution method and formulation, parametric studies are conductedto examine the influences of thermal environment, core thickness-to-face sheet thickness ratio, boundaryconditions, amplitude of vibrations, CNTs volume fraction and their distribution pattern. It is concludedthat an increase in the volume fraction of CNTs results in higher fundamental frequency and decreases thenonlinear-to-linear frequency ratio.     

Study on Wear Model and Adhesive Wear Mechanism of Brass under Boundary Lubrication

Protection of Metals and Physical Chemistry of Surfaces - The tribological tests of brass and steel are carried out on an in-situ tribometer. The Stribeck curve illustrates that the roughness and...     

Influence of the underneath cavity on buoyant‐forced cooling of the integrated photovoltaic panels in building roof: a thermography study

Airflow around building‐integrated photovoltaics (BIPV) has a significant impact on their hygrothermal behavior and degradation. The potential of reducing the temperature of BIPV using an underneath cavity is experimentally and numerically investigated in literature. Most of the models are oversimplified in terms of modeling the impact of 3D flow over/underneath of PV modules, which can result in a non‐uniform surface temperature and consequently a non‐homogenous thermal degradation. Moreover, the simultaneous presence of radiation and convection related to upstream wind, in addition to the combined impact of back‐ventilation and surface convection, is barely addressed in literature. However, these simplifications can result in the unrealistic loading climate conditions. This paper aims to present a unique experimental setup to provide more realistic climate conditions for investigating the ventilation potential of the underneath. The setup consists of a solar simulator and a building prototype with installed PV, placed inside an atmospheric wind tunnel to control upstream wind velocity. Thermography is performed using an infrared camera to monitor the surface temperature of the BIPV. The potential of an underneath cavity with various cavity heights and PV arrangement is further investigated in this paper. The outcome would be eventually useful in the development of practical guidelines for BIPV installation. Copyright © 2013 John Wiley & Sons, Ltd.     

Mixed matrix membranes on the basis of Matrimid and palladium-zeolitic imidazolate framework for hydrogen separation

Iranian Polymer Journal - Gas separation membranes with enhanced performance were developed by the introduction of nanosized palladium particles. In this study, gas separation performance of...