Anwendungen für Mehrphasen-CFD am Fahrzeugexterieur

Forschung im Ingenieurwesen - In der Automobilindustrie werden einphasige Strömungssimulationen seit vielen Jahren zur Aerodynamik- und Aeroakustikentwicklung eingesetzt. Sie gewähren...     

The use of palladium nanoparticles supported with MCM-41 and basic (Al)MCM-41 mesoporous sieves in microwave-assisted Heck reaction

A series of supported catalysts has been obtained by grafting of chemically generated palladium nanoparticles onto basic, Cs⁺ ion-exchanged molecular sieves (Al)MCM-41 and onto the non-basic, parent material MCM-41. Catalytic activity of the catalysts has been investigated in the Heck reaction between bromobenzene and butyl acrylate under microwave irradiation. The activity of the bifunctional catalysts (Pd@Cs⁺-(Al)MCM-41) and the activity of Pd@MCM-41 combined with sodium acetate as an external base were considerably higher under microwave irradiation than activities observed for the same catalytic systems under the conventional heating. The Pd@MCM-41/NaOAc system showed higher conversions than the bifunctional catalysts presumably due to a different nature and accessible amount of the base. On the other hand, microwave irradiation seems to increase the rate of aggregation of the metallic particles and thus also catalyst deactivation as compared with the usual heating.     

Investigation of the selective catalytic reduction of NO by NH3 on Fe-ZSM5 monolith catalysts

Photocatalytic nitric oxide (NO) decomposition and reduction reactions, using carbon monoxide (CO) as a reducing gas, have been investigated over Degussa P25 titanium dioxide photocatalysts, using a continuous flow reactor. The effects of thermal pretreatment temperature and reaction gas composition on the activity and selectivity of the decomposition and reduction reactions have been evaluated. Prepared materials were characterised by X-ray diffraction (XRD), N₂ physisorption, transmission electron microscopy (TEM) and differential scanning calorimetry (DSC) and findings from these techniques were used to explain the observed photocatalytic properties. XRD and TEM results indicated that for the pretreatment temperatures used (70, 120, 200, 450 and 600 °C) there was no appreciable change in the phase composition and the original composition of ca. 77 vol.% anatase and 23 vol.% rutile was maintained even after treatment at 600 °C. It was found that the photocatalytic activity for both the decomposition and reduction reactions decreased with increasing pretreatment temperature. This was attributed to the removal of surface hydroxyl species that act as active sites for reaction. For the decomposition reactions the only products observed were nitrogen and nitrous oxide and the selectivity for nitrogen formation remained constant (ca. 23%) regardless of the pretreatment temperature. The presence of CO in the reaction gas had a dramatic effect on the selectivity of the reactions with nitrogen selectivities as high as 65% being observed. It was found that as the CO/NO ratio increased the selectivity for nitrogen formation increased.     

Einfluß einer Auslagerung unter Schutzgas bei 800 bis 1000 °C auf die mechanischen Eigenschaften des Werkstofftyps X 10 NiCrAlTi 32 20

Effects of Aging in Inert Gas at 800 to 1000 °C on the Mechanical Properties of X 10 NiCrAlTi32 20 Type Alloys Specimens of three casts of a X 10 NiCrAlTi32 20 type alloy with different carbon contents (0,04, 0,08 and 0,33 wt%) were annealed at 800, 900 and 1000°C between 6 and 900 h. Tensile- and notched bar impact-tests were performed at room temperature to characterize the changes of mechanical properties due to the heat treatments. The structural changes were recorded by optical metallography, scanning electron microscopy and transmission electron microscopy. The formation of fine dispersed M₂₃C₆-precipitates leads to hardening effects, which are lost by coarsening with longer annealing time or higher temperatures, where an embrittlement occurs. Only the low carbon version exhibits a dominant precipitation of Ti(C, N), especially at 1000°C, which maintains its ductility.     

Modelling the dynamics of landscape transformations and population growth in the highlands of Ethiopia using remote-sensing data

This study models landscape transformations and settlement dynamics in a highland area of Ethiopia over a 56 year period (1957–2013). The analyses were performed using aerial photographs, satellite images, and field data. The remotely sensed images were geometrically and radiometrically corrected. Visual interpretation of aerial photographs and supervised classification of multispectral satellite images using the maximum likelihood algorithm were chosen for land-cover mapping. The population size was estimated by counting the houses on the aerial photographs and on the high-resolution images, and by direct census. The overall trend showed an increase of cropland and a decrease of other types of land cover. Landscape transformation rates recently slowed down due to ownership and policy restrictions. The average cropland holding size per family has decreased from 2.6 to 1.1 ha due to the exponential growth of the population. The relationship between settlement and cropland expansion is statistically significant. Models of logistic growth were fitted to the cropland area, and models of exponential and logistic growth to the population development to estimate the carrying capacity. The concomitant increase of population and the decrease of cropland per head resulted in a shortage of food and energy, highlighting the importance of policy decisions on land management.     

Purification of phospholipids by preparative high pressure liquid chromatography

A method is described for the purification of a number of phospholipids by preparative high performance liquid chromatography (HPLC). Purification of digalactosyl-diglyceride from spinach and egg phosphatidylcholine, 1,2-dioleoyl-sn-glycero-3-phosphocholine and 1,2-dioleoyl-sn-glycero-3-phosphoethanolamine from its reaction mixture have been resolved. The lipid separation is performed on a polygosil column and the individual compounds are monitored directly by refractive index detection. Chloroform/methanol mixtures are used as eluent systems, providing a wide polarity range to separate the classes of lipids. The developed equipment can be used for columns between 10 and 50 cm long and 4 and 50 mm inner diameter. The flow rate could be varied between 1 and 100 ml/min and applied pressures between 10 and 450 bars.     

Dependence of the activity of phospholipase C beta on surface pressure and surface composition in phospholipid monolayers and its implications for their regulation

We have examined the influence of surface pressure and phospholipid composition on hydrolysis of phosphatidylinositol (4,5)-bisphosphate (PIP2) by phospholipase C beta 1 (PLC beta 1) and PLC beta 2 in mixed composition phospholipid monolayers. Increasing the monolayer surface pressure from 15 to 36 mN/m reduced the rate at which PIP2 was hydrolyzed by PLC beta 1 and PLC beta 2 by 4-6-fold, although PLC beta 1 was more active than PLC beta 2, even at high surface pressure. Reduced enzyme activity was accompanied by an increase in reaction induction times, suggesting that increasing surface pressure reduced the penetration rate of the enzymes into the monolayer. Quantitation of interfacial enzyme concentration using 35S-labeled PLC beta 1 confirmed that less enzyme was associated with the monolayer at higher pressures. The relationship between PLC activity and substrate concentration was examined at a single surface pressure of 30 mN/m. This relationship was not hyperbolic, and increases in the mole percentage (mol %) of PIP2 in the monolayer resulted in an upwardly-curving increase in PLC activity. Thus, PLC beta 1 activity increased 7-fold and PLC beta 2 activity increased 4-fold when the mol % of PIP2 in the monolayer increased from 17.9% to 29%, increasing further thereafter. Paradoxically, increasing the mol % of PIP2 from 0 to 60% was accompanied by a 3-fold decrease in interfacial enzyme concentrations. Taken together, these data show that the catalytic activity of PLC beta involves some element of penetration of lipid interfaces, and suggest that the organization of the substrate facilitates PLC activity, giving credence to the substrate theory of interfacial activation of phospholipases. We present a hypothesis suggesting that PIP2 molecules coalesce into enriched lateral domains which favor PLC beta activity.