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1.
2.
Epoxidation of natural rubber with peroxyacids in homogeneous solution (CHCl3, benzene) and in latex occurs without main chain fission or isomerization of the cis configuration. There are two possible modes of addition of oxygen to the double bond, which gives rise to diastereoisomers in dyad structures, as shown by the occurrence of splitting of 13C NMR resonances in 100% epoxidized rubber. In partially epoxidized rubber the 13C NMR resonances of the methylene carbon atoms have been fully assigned using pulse sequences and lanthanide shift reagents, in terms of triad sequences. Resonances in the olefinic region of the spectrum require assignment in terms of pentad sequences whereas those from the oxirane region are much more closely spaced and are assigned using triads. Intensity measurements on the methylene carbon NMR resonances show that the epoxidation reaction is a random process in both homogeneous solution and in latex particles. 相似文献
3.
The distribution of ergosterol in different parts of shiitake mushrooms was studied in order to optimize the conversion of ergosterol to vitamin D2 during drying. The effect of moisture on the conversion of ergosterol to vitamin D2 was also investigated by adjusting the moisture content of fresh mushrooms to different levels in a large vacuum desiccator and subjecting them to UV irradiation at 290-320 nm wavelength, for 2 h. The moisture, ergosterol and vitamin D2 contents were determined using standard procedures. It was found that the ergosterol content on a dry matter basis of fresh shiitake mushroom was highest in the gills (10.6 ± 0.99 mg/g DM), followed by the cap or pileus (5.34 ± 0.64 mg/g DM) and was least in the stalk or stipe (2.97 ± 0.56). The moisture content had a marked influence on the conversion of ergosterol to vitamin D2, the best conversion taking place at a moisture content of about 70% on a wet basis. 相似文献
4.
PA Cabrera S Parietti G Haran U Benavidez S Lloyd G Perera S Valledor MA Gemmell T Botto 《Canadian Metallurgical Quarterly》1996,26(1):79-83
Forced thinking is an incompletely understood and rarely described epileptic aura. We studied three patients with forced thinking from left frontal lesions, two neoplastic and one vascular. All three experienced repetitive, intrusive thoughts at the onset of seizures. Their forced thinking was associated with the desire to vocalize, orobuccal movements, and speech arrest. The episodes occurred with other ictal manifestations and responded to antiseizure therapy. These patients suggest that epileptic forced thinking is a heterogeneous phenomenon; forced thinking from left frontal lesions is a manifestation of expressive language and is distinct from experiential thoughts arising from temporal limbic foci. 相似文献
5.
M. C. S. Perera 《应用聚合物科学杂志》1987,34(7):2591-2600
Epoxidation has been applied to modify the surface of natural rubber laces. When very thin laces of fractionated bleached rubber are used, about 6% of the double bonds could be modified. Using 1H nuclear magnetic resonance (NMR) and infrared (IR) analysis the best condition for the reaction was worked out. Both 13C NMR and differential scanning calorimetry (DSC) results indicate that the 6% epoxide groups are placed in a predominantly block manner. Modification in yellow fraction rubber however gives lower epoxy contents. Increase in glass transition tempreature by epoxidation results in more damping and better abrasion resistance. The resultant polymer acts very similar to a 90/10 natural rubber/50% epoxidized natural rubber (NR/ENR-50) blend. 相似文献
6.
S. Perera 《时间序列分析杂志》2004,25(5):723-732
Abstract. Maximum quasi-likelihood estimation is investigated for the NEAR(2) model, an autoregressive time series model with marginal exponential distributions. In certain regions of the parameter space, simulations indicate that maximum quasi-likelihood estimators perform better than two-stage conditional least squares estimators in terms of the per cent of estimates falling in the parameter space. The problem of out-of-range estimates is shown to be caused by the lack of information in the data rather than the characteristics of the method of estimation. 相似文献
7.
Nitrogen-containing aluminium titanate 总被引:1,自引:0,他引:1
In the Ti-Al-O-N system a phase isostructural to aluminium titanate but with expanded unit cell dimensions was observed. It was stable between 1400 and 1700 °C and has unit cell dimensions of a=0.3719 nm, b=0.9703 nm and c=0.9869 nm with a composition of Ti
1.00
4+
Al
0.54
3+
Ti
1.46
3+
N
0.28
3–
O
4.58
2–
0.14 Several samples were prepared by reaction sintering mixtures of TiN, Al2O3 and AlN powders at 1400 to 1470 °C for 4 h in a nitrogen atmosphere to maximize this phase. One specific advantage of the nitrogen-containing aluminium titanate over aluminium titanate is that the former is unchanged at 1150 °C in a nitrogen atmosphere whereas the latter decomposes. In the Al2O3-TiO2 oxide system Al2TiO5 solid solution extends to approximately Al0.75Ti2.25O5 at 1470 °C under the mildly reducing conditions of a graphite furnace. The unit cell volume increases linearly with the increasing replacement of Al3+ by Ti3+. 相似文献
8.
Davide Ciceri Lachlan R. Mason Dalton J. E. Harvie Jilska M. Perera Geoffrey W. Stevens 《Microfluidics and nanofluidics》2013,14(1-2):213-224
The use of a microfluidic device in determining the extraction kinetics of CoII ions by di-(2-ethylhexyl) phosphoric acid (DEHPA) was demonstrated. Experimental data obtained using a Y-Y-shaped microchannel were modelled using a finite volume method. The contributions of diffusion and reaction transport resistances to the overall rate of mass transfer were obtained. A diffusion-controlled transfer assumption could not account for the experimental data, confirming that transport occurs under a mixed reaction–diffusion resistance regime. The reaction rate constant was determined to be $(2.4 \pm 0.6) \times 10^{-10}$ m/s, in good agreement with corresponding Lewis cell measurements from the literature. 相似文献
9.
Dharani Perera R. T. Jim Eales Kathy Blashki 《Universal Access in the Information Society》2009,8(2):77-88
For people with upper limb disabilities visual art is an important activity that allows for expression of individuality and
independence. They show remarkable endurance, patience and determination to adapt their remaining capabilities to create visual
art. There are significant advantages of digital technologies in assisting artists with upper limb disabilities. Paralinguistic
voice recognition technologies have proven to be a particularly promising mode of interaction. Despite these benefits, technological
support for people with upper limb disabilities to create visual art is scarce. This paper reports on a number of case studies
of several artists with upper limb disabilities. These case studies illustrate the struggles they face to be creative and
also show the significant advantages of digital technologies in assisting such artists. An investigation into people’s ability
to use the volume of their voice to control cursor movement to create drawings on the screen is also reported. With motivation,
training and practise, use of volume to control drawing tasks shows great promise. It is believed that paralinguistic voice
has wider implications beyond assisting artists with upper limb disabilities, such as: an alternative mode of interaction
for disabled people to perform tasks other than creating visual art, alternative mode of interaction for hands busy environments
and as a voice training system for people with speech impairments. 相似文献
10.
When buildings are subjected to earthquakes, it is imperative to dissipate some of the input energy through pre-determined and well designed mechanisms. This study investigates the influence of mechanical control on structural systems through the application of strategically located component elements with reliable damping and stiffness properties that can modulate the response. The effects of installing such damping elements at two particular locations have been investigated. These positions are between the shear walls near the coupling beams and within cut out sections of the wall elements in multi-storey structures. Finite element time history analysis is used in the study and results indicate that the proposed procedure is able to achieve reasonable improvements in seismic response. 相似文献