A comparative study on structural,morphological and photocatalytic properties of anodically grown ZnO nanowires under varying parameters

Journal of Materials Science: Materials in Electronics - In this study, zinc oxide (ZnO) nanowires (NWs) were successfully produced on Zn plates through electrochemical anodization in potassium...     

Pharmacodynamic Comparison of a Nasal Formulation of Verapamil and Intravenous and Oral Dosage Forms

The nasal route has been shown to be effective for the administration of numerous drugs in order to improve drug bioavailability. A nasal gel of verapamil hydrochloride was formulated and evaluated pharmacodynamically in humans, using electrocardiographic results, with comparison to oral and IV routes. Seven volunteers were involved in the study and the pharmacodynamic parameters were evaluated statistically. Experimental nasal gel showed similar pharmacodynamic results with the intravenous route, which is a hint to the reduction in verapamilinduced first-pass metabolism. However, oral route of administration showed a tendency of less efficacy. No reasonable effect of verapamil could be obtained with the placebo group.     

The effect of fibre orientation of the dry sliding wear of borsic-reinforced 2014 aluminium alloy

The effect of fibre orientation on the dry sliding wear of continuous B(SiC) fibre reinforced aluminium alloy composites was investigated using a pin-on-disc wear testing machine. The metal-matrix composites (MMC) samples were tested in the normal (N), parallel (P) and antiparallel (AP) orientations sliding against a steel counter disc at a fixed speed of 1 m s^–1 under loads of from 12 to 60 N.The results showed that for the matrix alloy and MMCs, the average wear increased linearly with load. Wear of the MMCs was insensitive to fibre content but for composites with fibre contents at or above the minimum of 16 vol% used for this work, the wear rate was about 18% of that of the unreinforced matrix. Fibre orientation had a minor effect on wear rate; the N orientation gave the lowest wear rate with the AP orientation slightly higher and the P orientation significantly higher.The average coefficients of friction of the MMCs in N and AP orientations decreased linearly with increased wear rate and non-linearly with increased load, but the P orientation was insensitive to either variable.It was concluded from these results and a metallographic examination that the mechanism of wear of MMCs was essentially oxidative wear of the matrix. The hard fibres modified this to slightly different degrees depending on their orientation relative to the wear surface and sliding direction.     

Thermodynamic analysis of solar photovoltaic cell systems

The thermodynamic characteristics of solar photovoltaic (PV) cells are investigated from a perspective based on exergy. A new efficiency is developed that is useful in studying PV performance and possible improvements. Exergy analysis is applied to a PV system and its components, and exergy flows, losses and efficiencies are evaluated. Energy efficiency is seen to vary between 7% and 12% during the day. In contrast, exergy efficiencies, which incorporate the second law of thermodynamics and account for solar irradiation exergy values, are lower for electricity generation using the considered PV system, ranging from 2% to 8%. Values of “fill factors” are determined for the system and observed to be similar to values of exergy efficiency.     

Oxidation behavior of single-crystal Al2O3-fiber-reinforced Ni3Al-based composites

A series of single-crystal Al₂O₃-fiber-reinforced Ni3Al-based intermetallic matrix composites were fabricated by pressure casting. The matrices employed were binary Ni₃Al, Ni₃Al-0.5 at. pct Cr, and Ni₃Al-0.34 at. pct Zr. The development of microstructure upon oxidation in air at either 1100 °C or 1200 °C was investigated by optical, scanning, and transmission electron microscopy. In air-oxidized binary Ni₃Al, some of the fibers were fully or partially covered with a layer of oxide. A weak fiber/matrix bond in this system, which led to fiber debonding during composite processing, is believed to be responsible for the ingress of O into the composite and oxidation of the matrix in the debonded regions at the fiber/matrix interface. Addition of Cr to Ni₃Al resulted in an almost threefold increase in fiber/matrix bond strength. No oxidation of the interface was observed. A thick layer of oxide was formed around all the fibers when the composite was thermally cycled prior to isothermal annealing. Addition of Zr to Ni₃Al resulted in the formation of a layer of ZrO₂ on the surface of the fibers during composite processing. The ZrO₂ layer provided a fast path for the diffusion of O, which led to the formation of a rootlike oxide structure around the fibers. The rootlike structure consisted of a network of Al₂O₃-covered ZrO₂.     

The IFR/DFR property of the forward recurrence-time distribution

When a failure or replacement process is modeled as a renewal process, the residual life of the unit in use at a given time is generally referred to as the forward recurrence time (RT). Distributional properties of this random variable are critically important in many applications. This paper investigates the extent to which the failure-rate function monotonicity of a life distribution is inherited by the forward RT distribution at time s of its renewal process. For DFR life distributions, the forward RT distribution is also DFR for every s⩾0. However, the corresponding property does not necessarily hold for IFR life distributions. The forward RT distribution is IFR in the limit as s→0 and as s→∞. For IFR Weibull life distributions, we demonstrate numerically that the forward RT distribution is IFR for small s. As s is increased, it alternates between being IFR and non-IFR in an interesting cyclical pattern, and remains IFR beyond a large enough s     

Forecasting based on sectoral energy consumption of GHGs in Turkey and mitigation policies

Recently, global warming and its effects have become one of the most important themes in the world. Under the Kyoto Protocol, the EU has agreed to an 8% reduction in its greenhouse gas (GHG) emissions by 2008–2012. The GHG emissions (total GHG, CO₂, CO, SO₂, NO₂, E (emissions of non-methane volatile organic compounds)) covered by the Protocol are weighted by their global warming potentials (GWPs) and aggregated to give total emissions in CO₂ equivalents. The main subject in this study is to obtain equations by the artificial neural network (ANN) approach to predict the GHGs of Turkey using sectoral energy consumption. The equations obtained are used to determine the future level of the GHG and to take measures to control the share of sectors in total emission. According to ANN results, the maximum mean absolute percentage error (MAPE) was found as 0.147151, 0.066716, 0.181901, 0.105146, 0.124684, and 0.158157 for GHG, SO₂, NO₂, CO, E, and CO₂, respectively, for the training data with Levenberg–Marquardt (LM) algorithm by 8 neurons. R² values are obtained very close to 1. Also, this study proposes mitigation policies for GHGs.     

Film morphology and reaction rate for the CVD of tungsten by the WF6—SiH4 reaction

Journal of Electronic Materials - Low pressure chemical vapor deposition (LPCVD) of tungsten (W) by SiH4 reduction of WF6 on Si(100) surfaces was studied in a single-wafer, cold-wall reactor over a...