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1.
The solution behaviour of a new mesogenic side group polyacrylate in tetrahydrofuran and toluene has been investigated by static and dynamic light scattering. In the dilute regime the polymer behaves as typical polydisperse linear chains in good solvent and the dynamics is dominated by a single fast mode. Cluster formation was detected starting at a concentration around 50 g l−1. It seems to be independent of the solvent as well as of polymer molecular weight. In the semidilute regime, the behaviour of the reduced osmotic modulus leads to the conclusion that repulsion between the chains is stronger than in linear macromolecules. The appearance of larger clusters was revealed above a characteristic concentration and is slightly dependent on the polyacrylate molecular weight. The dynamics was generally characterised by a fast mode related to the cooperative diffusion and by a slow mode associated with large clusters. The existence of a network of multiconnected clusters is envisaged with increasing solution concentration. 相似文献
2.
Geetanjali Yadav Leonard A. Fabiano Lindsay Soh Julie Zimmerman Ramkrishna Sen Warren D. Seider 《American Institute of Chemical Engineers》2021,67(1):e16992
Algae-to-biodiesel processes are hindered by high costs and low energy return on investment.1,2. Herein, three foci in research improve algae-to-biodiesel processes by: (1) reducing high installation and energy costs in the CO2 sequestration, cultivation, and harvesting stages; (2) improving oil extraction and biodiesel generation; and (3) increasing utilization of the proteins in lipid-extracted biomass (e.g., for animal feed), as well as the omega-3 fatty acids for nutraceuticals and food supplements. A process is introduced that uses carbon dioxide to aid in all three of these foci. CO2 is used first in the form of microbubbles to lyse algae cell walls, releasing triglyceride oils. CO2 also aids with transesterification of these triglycerides using methanol. At low temperatures (353.15–368.15 K) and intermediate pressures (5–10 MMPa), carbon dioxide causes methanol to dissolve partially in the triglyceride phase and triglyceride to dissolve partially in the methanol phase, increasing the transesterification reaction rate. Due to the nondestructive nature of these processes, other metabolites can also be harvested providing improvements in both mass and economic efficiency with an overall sharp reduction in the modeled price of biodiesel. 相似文献
3.
Requirements engineering (RE) research often ignores or presumes a uniform nature of the context in which the system operates.
This assumption is no longer valid in emerging computing paradigms, such as ambient, pervasive and ubiquitous computing, where
it is essential to monitor and adapt to an inherently varying context. Besides influencing the software, context may influence
stakeholders’ goals and their choices to meet them. In this paper, we propose a goal-oriented RE modeling and reasoning framework
for systems operating in varying contexts. We introduce contextual goal models to relate goals and contexts; context analysis to refine contexts and identify ways to verify them; reasoning techniques to derive requirements reflecting the context and
users priorities at runtime; and finally, design time reasoning techniques to derive requirements for a system to be developed
at minimum cost and valid in all considered contexts. We illustrate and evaluate our approach through a case study about a
museum-guide mobile information system. 相似文献
4.
César MarconAuthor VitaeNey CalazansAuthor Vitae Edson MorenoAuthor VitaeFernando MoraesAuthor Vitae Fabiano HesselAuthor VitaeAltamiro SusinAuthor Vitae 《Journal of Parallel and Distributed Computing》2011,71(5):714-728
This paper describes CAFES, an extensible, open-source framework supporting several tasks related to high-level modeling and design of applications employing complex intrachip communication infrastructures. CAFES comprises several built-in models, including application, communication architecture, energy consumption and timing models. It also includes a set of generic and specific algorithms and additional supporting tools, which jointly with the cited models allow the designer to describe and evaluate applications requirements and constraints on specified communication architectures. Several examples of the use of CAFES underline the usefulness of the framework. Some of these are approached in this paper: (i) a realistic application captured at high-level that has its computation time estimated after mapping at the clock cycle level; (ii) a multi-application system that is automatically mapped to a large intrachip network with related tasks occupying contiguous areas in the chip layout; (iii) a set of mapping algorithms explored to define trade-offs between run time and energy savings for small to large intrachip communication architectures. 相似文献
5.
Thomas K. Hirsch Alexandre Da S. Rocha Fabiano D. Ramos Telmo R. Strohaecker 《Metallurgical and Materials Transactions A》2004,35(11):3523-3530
Plasma nitriding of tool materials is common practice to improve the wear resistance and lifetime of tools. Machining-induced
compressive residual stresses in shallow layers of some tenths of microns are observed accompanied by other characteristic
properties of machined surfaces in these high-strength materials. After plasma nitriding of M2 high-speed steel, previously
induced compressive residual stresses remain stable and the depth of diffusion layers decreases with increasing compressive
residual stresses. This article reports investigations of plasma nitrided samples with different levels of residual stresses
induced prior to the nitriding process. For comparison, experiments with bending load stresses during plasma nitriding have
also been carried out. The plasma nitriding treatment was performed at constant temperature of 500 °C with a gas mixture of
5 vol pct N2 in hydrogen. Nitriding time was varied from 30 to 120 minutes. All samples were characterized before and after plasma nitriding
concerning microstructure, roughness, microhardness, chemical composition, and residual stress states. Experimental results
are compared with analytical calculations on (residual) stress effects in diffusion and show a clear effect of residual and
load stresses in the diffusion of nitrogen in a high-strength M2 tool steel. 相似文献
6.
Mariana S. Silveira Cláudia P. M. L. Fontes Alexandre A. Guilherme Fabiano A. N. Fernandes Sueli Rodrigues 《Food and Bioprocess Technology》2012,5(3):947-953
The aim of the present work was to investigate the use of cashew apple juice as a low cost substrate for Lactobacillus casei B-442 cultivation and lactic acid production. Ammonium sulfate was employed as the only exogenous nitrogen source. The effect
of cashew apple juice reducing sugars and ammonium sulfate concentration and the fermentation pH and temperature on biomass
formation, lactic acid production, and productivity were evaluated. The highest productivity (2.36 g/L.h) was obtained applying
50 g/L of reducing sugar from the cashew apple juice supplemented with 6 g/L of ammonium sulfate. The process yield was about
95% when fermentation was carried out at 37 °C with pH controlled at pH 6.5 using NaOH (120 g/L). 相似文献
7.
Ana Beatriz Aguiar Sanford Leidivan Sousa da Cunha Caio Bezerra Machado Flvia Melo Cunha de Pinho Pessoa Abigail Nayara dos Santos Silva Rodrigo Monteiro Ribeiro Fabiano Cordeiro Moreira Manoel Odorico de Moraes Filho Maria Elisabete Amaral de Moraes Lucas Eduardo Botelho de Souza Andr Salim Khayat Caroline Aquino Moreira-Nunes 《International journal of molecular sciences》2022,23(15)
The circadian clock (CC) is a daily system that regulates the oscillations of physiological processes and can respond to the external environment in order to maintain internal homeostasis. For the functioning of the CC, the clock genes (CG) act in different metabolic pathways through the clock-controlled genes (CCG), providing cellular regulation. The CC’s interruption can result in the development of different diseases, such as neurodegenerative and metabolic disorders, as well as cancer. Leukemias correspond to a group of malignancies of the blood and bone marrow that occur when alterations in normal cellular regulatory processes cause the uncontrolled proliferation of hematopoietic stem cells. This review aimed to associate a deregulated CC with the manifestation of leukemia, looking for possible pathways involving CG and their possible role as leukemic biomarkers. 相似文献
8.
Magnetic polystyrene–palygorskite nanocomposite obtained by heterogeneous phase polymerization to apply in the treatment of oily waters 下载免费PDF全文
Antonieta Middea Luciana Spinelli Fernando Gomes de Souza Junior Reiner Neumann Thais Fernandes Fabiano Richard Leite Faulstich Otavio Gomes 《应用聚合物科学杂志》2018,135(15)
Water contaminated by oil poses challenges to the management of water resources. Magnetic nanoparticles has been issue of different potential applications including remotion oil from water. Magnetic polystyrene–palygorskite nanocomposites were prepared by a heterogeneous phase polymerization for the removal of organic contaminants from water. The organo‐Fe3O4‐palygorskite nanoparticles were coated with polystyrene, forming water repellent and oil absorbing surfaces to promote the removal of oil from the surfaces of nanocomposites by applying an external magnetic field. X‐ray fluorescence, X‐ray diffraction, scanning electron microscopy, zeta potential and size distribution measurement, surface area determination by BET, density measurement by He pycnometry, carbon grade determination, thermogravimetric analysis, Fourier‐transform infrared spectroscopy, Raman spectroscopy, and evaluation of hydrophobicity by contact angle were used to characterize the nanoparticles. The magnetic nanocomposite obtained showed excellent hydrophobicity, around 78° contact angle. In addition, oil removal capability tests were also performed, according to which the preliminary results indicated removal of approximately 98% of oil in synthetic oily water samples. The oil–water separation using this magnetic nanocomposite provides a promising alternative strategy for water treatment. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46162. 相似文献
9.
B. Fabiano A. P. Reverberi A. Del Borghi V. G. Dovi 《Theoretical Foundations of Chemical Engineering》2012,46(6):673-680
Biodiesel is an alternative non-petroleum based fuel, consisting of alkyl esters obtained either by esterification of free fatty acids with low molecular weight alcohols, or by transesterification of triglycerides. The realization of a biodiesel unit can pose several safety issues and inherent safety application opportunities as the production involves the transport, use and storage of hazardous materials, either flammable or toxic. In the experimental phase, we studied, at laboratory scale, different alkali catalysts and the relevant reaction parameters, considering inherent safety opportunities. An accurate kinetic model of the transesterification process was developed and validated, allowing to provide possible minimization and simplification plant options. 相似文献
10.
The implementation of the orbital minimization method (OMM) for solving the self-consistent Kohn–Sham (KS) problem for electronic structure calculations in a basis of non-orthogonal numerical atomic orbitals of finite-range is reported. We explore the possibilities for using the OMM as an exact cubic-scaling solver for the KS problem, and compare its performance with that of explicit diagonalization in realistic systems. We analyze the efficiency of the method depending on the choice of line search algorithm and on two free parameters, the scale of the kinetic energy preconditioning and the eigenspectrum shift. The results of several timing tests are then discussed, showing that the OMM can achieve a noticeable speedup with respect to diagonalization even for minimal basis sets for which the number of occupied eigenstates represents a significant fraction of the total basis size (>15%). We investigate the hard and soft parallel scaling of the method on multiple cores, finding a performance equal to or better than diagonalization depending on the details of the OMM implementation. Finally, we discuss the possibility of making use of the natural sparsity of the operator matrices for this type of basis, leading to a method that scales linearly with basis size. 相似文献