Sufficient Utilization of Mn2+/Mn3+/Mn4+ Redox in NASICON Phosphate Cathodes towards High-Energy Na-Ions Batteries

Na superionic conductor of Na₃MnTi(PO₄)₃ only containing high earth-abundance elements is regarded as one of the most promising cathodes for the applicable Na-ion batteries due to its desirable cycling stability and high safety. However, the voltage hysteresis caused by Mn²⁺ ions resided in Na⁺ vacancies has led to significant capacity loss associated with Mn reaction centers between 2.5–4.2 V. Herein, the sodium excess strategy based on charge compensation is applied to suppress the undesirable voltage hysteresis, thereby achieving sufficient utilization of the Mn²⁺/Mn³⁺ and Mn³⁺/Mn⁴⁺ redox couples. These findings indicate that the sodium excess Na_3.5MnTi_0.5Ti_0.5(PO₄)₃ cathode with Ti⁴⁺ reduction has a lowest Mn²⁺ occupation on the Na⁺ vacancies in its initial composition, which can improve the kinetics properties, finally contributing to a suppressed voltage hysteresis. Based on these findings, it is further applied the sodium excess route on a Mn-richer phosphate cathode, which enables the suppressed voltage hysteresis and more reversible capacity. Consequently, this developed Na_3.6Mn_1.15Ti_0.85(PO₄)₃ cathode achieved a high energy density over 380 Wh kg⁻¹ (based on active substance mass of cathode) in full-cell configurations, which is not only superior to most of the phosphate cathodes, but also delivers more application potential than the typical oxides cathodes for Na-ion batteries.     

地面三维激光雷达在坝区地形测量中的应用

针对叶巴滩水电站相对高差大、地势陡峻、存在大量倒悬崖深"V"型峡谷等复杂地理特点,采用地面三维激光雷达技术进行坝区地形测量,生成1:1000、1:500比例尺的数字高程模型(DEM)和数字线划图(DLG),并应用于土石方量计算.应用表明,地面三维激光雷达技术安全、精准、高效,所获取的数据内容丰富,细节特征提取自动化程度...     

考虑发电集团利益主体协调的风电消纳调度策略

大规模风电并网的反调峰特性造成系统在负荷低谷时段弃风问题严重,在北方供暖期尤为突出。增强热电联产机组运行的灵活性,提高发电集团参与调峰的积极性,是解决这一问题的方法。提出了考虑发电集团主体协调的两阶段调度策略,将每个发电集团作为独立的利益主体,各自以集团发电煤耗量最小为目标进行调度。针对弃风问题,通过增加储热装置提高发电集团的调峰能力,引入调峰补偿实现发电集团内部自调节、集团间辅助协调的风电消纳策略,减少对其他发电集团出力计划的影响。通过多种调度模式算例对比,所提调度策略能够实现风电消纳功率最大化,保证集团利益,调动发电集团调峰积极性。     

基于模型预测控制的能源产消者端对端交易策略

新能源政策市场化无补贴发展背景下,为保障分布式光伏资源的消纳,须探索有效的市场机制,发挥用户调动灵活性资源的主动性。端对端(Peer-to-Peer, P2P)能源交易作为本地电力消费者和生产者间直接能源交易模式,有利于局部区域功率平衡。采用连续双向拍卖市场机制,提出基于模型预测控制的P2P市场交易策略。针对储能参与后的产消者电量投标决策问题,利用模型预测控制滚动优化储能的充放电功率,指导市场主体的电量投标。在此基础上,将具有学习能力的增强零信息策略作为报价方法,实现各主体的自主决策。辽西某区域电网算例结果表明：所提方法能够有效调动市场主体的积极性,指导其投标行为,进一步增加个体收益,提高配网接纳分布式光伏的能力。     

调控Al2O3晶型控制MgAl2O4:Mn4+荧光粉中Mn价态研究

Mn4+激活红光荧光粉是白光半导体发光二极管(wLEDs)领域当前研究热点之一.Mn4+离子2E→4A2跃迁在铝酸盐中的最短发光波长是在MgAl2O4中实现的651nm发光,由于其结构中含有形成四面体或八面体配位的两种阳离子格位(Mg2+/Al3+),易造成所掺杂锰元素存在多种价态(+2/+4/+3等).本研究通过改变...     

系统化全域推进海绵城市建设的长效管控机制研究

在系统化全域推进海绵城市建设的总体要求下,如何结合"放管服"改革和"行政审批制度"改革,实现海绵城市建设的长效管控,是当前需要研究的重点问题.以编制《海绵城市监管技术指南》为契机,在调研两批30个试点城市推进模式的基础上,对海绵城市建设全过程的管控机制进行系统研究,提出了海绵城市建设的管控体制、管控模式、管控目标和管控...     

Use of Cottonseed Meal for Producing Eicosapentaenoic Acid by Pythium irregulare

Cottonseed meal (CSM), a common agricultural by‐product, was used as a nutrient source for the production of eicosapentaenoic acid (EPA) by Pythium irregulare. CSM can support good cell growth performance, as can yeast extract (YE). In terms of the maximum EPA content and EPA yield, CSM is superior to YE. Low concentrations of CSM are beneficial to lipid synthesis, and high concentrations favor the EPA content. Utilizing response surface methodology (RSM) analysis, the optimum contents of glucose and CSM in the fermentation medium were determined to be 40.2 and 16.1 g/l, respectively. After 6 days of fermentation at 25 °C and optimal conditions, the EPA yield and productivity were 245.3 and 40.9 mg/l day, respectively. Particle size of CSM was found to affect the EPA production, and a finely ground CSM (100 mesh) was determined to be best for EPA production. The variation in the fatty acid content of total fatty acid (TFA) indicates that EPA was synthesized through the n‐6 route in P. irregulare and Δ12 desaturase was the key enzyme for EPA biosynthesis. Sodium carbonate was determined to be notably good at removing free gossypol attached to biomass. After fungal biomass from each flask had been harvested from Na₂CO₃‐supplemented medium, 1 % (w/v) Na₂CO₃ solution was used to wash the mycelia three times; free gossypol (FG) was not detected (detection limit 0.0018 %). This work provides a new approach using cottonseed meal to produce EPA through fungal fermentation.     

模具零件数控加工在线检测宏程序编程及应用

针对形状复杂的注塑模具零件加工工序多、配合精度要求高和模具制造过程中检测过程耗费时间及人力的问题,探索应用UG软件CMM模块对模具零件进行机床在线检测,规划模具零件检测几何要素和测头动作路径,编制并调用系统检测的宏程序,运用宏程序条件转移功能同步生成检测误差,从而拓展数控机床的功能,节省零件在其他检测设备上的装夹、找正和检测时间,提高模具零件加工精度和装配效率,以适应大量个性化产品对模具的需求.     

环境岩土工程课程教学研究与实践

环境岩土工程课程作为本科高年级选修课,涉及岩土、环境、卫生工程以及土壤学等多个领域,是一门新兴的综合性交叉学科。结合卓越工程师培养计划以及环境岩土工程课程特点,从理论教学、实验教学以及实践环节等方面对该课程教学内容及教学模式进行探索与改革,旨在引导学生主动学习,掌握环境岩土工程课程知识,提高学生运用专业知识分析问题、解决问题的工程实践能力和创新能力,将卓越工程师培养目标落到实处。