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排序方式: 共有266条查询结果,搜索用时 15 毫秒
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Chunliu Xu Weibo Hua Qinghua Zhang Yuan Liu Rongbin Dang Ruijuan Xiao Jin Wang Zhao Chen Feixiang Ding Xiaodong Guo Chao Yang Liangrong Yang Junmei Zhao Yong-Sheng Hu 《Advanced functional materials》2023,33(33):2302810
Na superionic conductor of Na3MnTi(PO4)3 only containing high earth-abundance elements is regarded as one of the most promising cathodes for the applicable Na-ion batteries due to its desirable cycling stability and high safety. However, the voltage hysteresis caused by Mn2+ ions resided in Na+ vacancies has led to significant capacity loss associated with Mn reaction centers between 2.5–4.2 V. Herein, the sodium excess strategy based on charge compensation is applied to suppress the undesirable voltage hysteresis, thereby achieving sufficient utilization of the Mn2+/Mn3+ and Mn3+/Mn4+ redox couples. These findings indicate that the sodium excess Na3.5MnTi0.5Ti0.5(PO4)3 cathode with Ti4+ reduction has a lowest Mn2+ occupation on the Na+ vacancies in its initial composition, which can improve the kinetics properties, finally contributing to a suppressed voltage hysteresis. Based on these findings, it is further applied the sodium excess route on a Mn-richer phosphate cathode, which enables the suppressed voltage hysteresis and more reversible capacity. Consequently, this developed Na3.6Mn1.15Ti0.85(PO4)3 cathode achieved a high energy density over 380 Wh kg−1 (based on active substance mass of cathode) in full-cell configurations, which is not only superior to most of the phosphate cathodes, but also delivers more application potential than the typical oxides cathodes for Na-ion batteries. 相似文献
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大规模风电并网的反调峰特性造成系统在负荷低谷时段弃风问题严重,在北方供暖期尤为突出。增强热电联产机组运行的灵活性,提高发电集团参与调峰的积极性,是解决这一问题的方法。提出了考虑发电集团主体协调的两阶段调度策略,将每个发电集团作为独立的利益主体,各自以集团发电煤耗量最小为目标进行调度。针对弃风问题,通过增加储热装置提高发电集团的调峰能力,引入调峰补偿实现发电集团内部自调节、集团间辅助协调的风电消纳策略,减少对其他发电集团出力计划的影响。通过多种调度模式算例对比,所提调度策略能够实现风电消纳功率最大化,保证集团利益,调动发电集团调峰积极性。 相似文献
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新能源政策市场化无补贴发展背景下,为保障分布式光伏资源的消纳,须探索有效的市场机制,发挥用户调动灵活性资源的主动性。端对端(Peer-to-Peer, P2P)能源交易作为本地电力消费者和生产者间直接能源交易模式,有利于局部区域功率平衡。采用连续双向拍卖市场机制,提出基于模型预测控制的P2P市场交易策略。针对储能参与后的产消者电量投标决策问题,利用模型预测控制滚动优化储能的充放电功率,指导市场主体的电量投标。在此基础上,将具有学习能力的增强零信息策略作为报价方法,实现各主体的自主决策。辽西某区域电网算例结果表明:所提方法能够有效调动市场主体的积极性,指导其投标行为,进一步增加个体收益,提高配网接纳分布式光伏的能力。 相似文献
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Feixiang Liu Ganggang Cao Zhengbing Guan Xiangru Liao Yujie Cai 《Journal of the American Oil Chemists' Society》2015,92(1):55-63
Cottonseed meal (CSM), a common agricultural by‐product, was used as a nutrient source for the production of eicosapentaenoic acid (EPA) by Pythium irregulare. CSM can support good cell growth performance, as can yeast extract (YE). In terms of the maximum EPA content and EPA yield, CSM is superior to YE. Low concentrations of CSM are beneficial to lipid synthesis, and high concentrations favor the EPA content. Utilizing response surface methodology (RSM) analysis, the optimum contents of glucose and CSM in the fermentation medium were determined to be 40.2 and 16.1 g/l, respectively. After 6 days of fermentation at 25 °C and optimal conditions, the EPA yield and productivity were 245.3 and 40.9 mg/l day, respectively. Particle size of CSM was found to affect the EPA production, and a finely ground CSM (100 mesh) was determined to be best for EPA production. The variation in the fatty acid content of total fatty acid (TFA) indicates that EPA was synthesized through the n‐6 route in P. irregulare and Δ12 desaturase was the key enzyme for EPA biosynthesis. Sodium carbonate was determined to be notably good at removing free gossypol attached to biomass. After fungal biomass from each flask had been harvested from Na2CO3‐supplemented medium, 1 % (w/v) Na2CO3 solution was used to wash the mycelia three times; free gossypol (FG) was not detected (detection limit 0.0018 %). This work provides a new approach using cottonseed meal to produce EPA through fungal fermentation. 相似文献
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