Effect of complexation of oxidised corn starch with mineral elements on physicochemical properties

The objective of this study was to determine the effect of complexation of oxidised starch with mineral elements on its physicochemical properties. Corn starch was oxidised with sodium hypochlorite and, afterwards, modified with ions of potassium, magnesium and iron. Thus, native and modified starches were analysed for: contents of mineral elements, colour parameters (L*a*b*), water binding capacity and solubility in water at temperature of 60 and 80 °C. Thermodynamic characteristics of gelatinisation by DSC, molecular weight distribution by GPC, intrinsic viscosity and pasting properties by RVA were studied. The efficiency of incorporation of metal ions into oxidised corn starch was about 30%, 20% and 20% for potassium, magnesium and iron ions, respectively. The complexation with potassium ions caused the greatest changes in the molecular weight distribution and the intrinsic viscosity of starches and viscosity of starch pastes. Only modification of starch with iron ions affected the colour parameters of the starch. Incorporation of metal ions into starch resulted also in changes in its water binding capacity and solubility in water.     

Chaotic pulse position modulation to improve the efficiency of sonar sensors

Ultrasonic devices are widely used in robotics as exteroceptive sensors for ranging measurements. Robotic applications often involve a large number of sonars operating concurrently, giving rise to the phenomenon of crosstalk. In this work, the problem of improving performance of ultrasonic devices in the presence of crosstalk and noise is addressed. In order for each device to discriminate its own echo, chaos is exploited to create unique firing sequences. In particular, the firing scheme described in this work is inspired to a modulation scheme used in chaotic communications, called chaotic pulse position modulation (CPPM). The evaluation of the time of flight is performed by a detection filter. The experimental setup consists of a Polaroid 600 electrostatic transducer driven by a continuous CPPM modulator. Experimental results confirm the suitability of the approach.     

A Food-Grade Method for Enhancing the Levels of Low Molecular Weight Proanthocyanidins with Potentially High Intestinal Bioavailability

Proanthocyanidins (PACs) are a group of bioactive molecules found in a variety of plants and foods. Their bioavailability depends on their molecular size, with monomers and dimers being more bioavailable than those that have a higher polymerization degree. This study aimed to develop a method to convert high-molecular-weight PACs to low-molecular-weight ones in a grape seed extract (GSE) from Vitis vinifera L. Therefore, GSE was subjected to alkaline treatment (ATGSE), and its difference in chemical composition, compared to GSE, was evaluated using a molecular networking (MN) approach based on results obtained from HPLC-ESI HRMS/MS characterization analysis. The network analysis mainly noted the PAC cluster with about 142 PAC compounds identified. In particular, the obtained results showed a higher content of monomeric and dimeric PACs in ATGSE compared to GSE, with 58% and 49% monomers and 31% and 24% dimers, respectively. Conversely, trimeric (9%), polymeric (4%), and galloylated PACs (14%) were more abundant in GSE than in ATGSE (6%, 1%, and 4%, respectively). Moreover, in vitro antioxidant and anti-inflammatory activities were investigated, showing the high beneficial potential of both extracts. In conclusion, ATGSE could represent an innovative natural matrix rich in bioavailable and bioaccessible PACs for nutraceutical applications with potential beneficial properties.     

Synthesis of Mammalian Gonadoliberin Analogs with the N-terminal glutamine or glutamine or glutamic acid

Synthesis of two mammalian gonadoliberin analogs, [Gln¹]GnRH and [Glu¹]GnRH, in solution by the peptide segment coupling of the [(2 + 4) + 4] type has been described.     

Age-dependent MRI-detected lesions at early stages of transient global ischemia in rat brain

Although ischemic stroke has higher incidence and severity in aged than in young humans, the age factor is generally neglected in ischemia animal models. This study was aimed at comparing age-dependent effects at early stages of transient global cerebral ischemia (TGCI) in rats. TGCI was induced in two groups of rats (3–6 and 20–24 months old, respectively) by exposure to 15% oxygen and 15 min occlusion of the two common carotid arteries. Brains were analysed in vivo by MRI–apparent diffusion coefficient (ADC) and T₂ maps–at 1–3 h post-TGCI and in vitro by histochemical examination of triphenyltetrazolium chloride (TTC)-stained slices. At 1–3 h post-TGCI, a higher incidence of lesions was found in aged than in young rats especially in the hippocampus and cortex (occipital plus parietal) but not in the thalamus. The lesioned regions showed lower ADC values in aged than in younger rats. The most substantial ADC decreases were associated with enhanced spin-spin relaxation and lower TTC staining. The different responses of the two age groups support the use of aged animals for investigations on different ischemia models. Our model of brain ischemia appears appropriate for further studies including drug effects.     

Induction Motor Identification by a Microcomputer-Based Structure

The paper deals with the parameter estimation of an induction motor performed through a microcomputer-based data acquisition system and recursive identification algorithms (RLS and RGLS) implemented by means of a general purpose computer. The microcomputer-based data acquisition system is essentially made by connecting the Z80 CPU with its peripherals and auxiliary memories through a bus standard. The motor is represented by a classical fifth-order model linearized around a usual working point; an approximate third-order model, obtained via balanced realization, is in good correlation with the original one according to the identification aims and to the measurement set efficiency. An original CAD procedure is utilized to determine the electrical parameters.     

Design and control of an IPMC wormlike robot.

This paper presents an innovative wormlike robot controlled by cellular neural networks (CNNs) and made of an ionic polymer-metal composite (IPMC) self-actuated skeleton. The IPMC actuators, from which it is made of, are new materials that behave similarly to biological muscles. The idea that inspired the work is the possibility of using IPMCs to design autonomous moving structures. CNNs have already demonstrated their powerfulness as new structures for bio-inspired locomotion generation and control. The control scheme for the proposed IPMC moving structure is based on CNNs. The wormlike robot is totally made of IPMCs, and each actuator has to carry its own weight. All the actuators are connected together without using any other additional part, thereby constituting the robot structure itself. Worm locomotion is performed by bending the actuators sequentially from "tail" to "head," imitating the traveling wave observed in real-world undulatory locomotion. The activation signals are generated by a CNN. In the authors' opinion, the proposed strategy represents a promising solution in the field of autonomous and light structures that are capable of reconfiguring and moving in line with spatial-temporal dynamics generated by CNNs.     

On the way to plastic computation

The development of post silicon technologies based on organic materials consolidates the possibility to realize new devices and applications with unusual properties: flexibility, lightweight, disposability. Both materials and processes play a fundamental role in this new electronic framework and have been improved continuously in the last decades. In this contribution, a new perspective will be drawn by considering a complete technology platform that lead printed organic electronics technology from the basic device and materials to a manufacturing process flow, design tools and market applications development. The final goal of the proposed approach is the manufacturing of organic circuits with sub-micron feature size at low fabrication costs with high flexibility and application versatility by using additive manufacturing processes. The identification of suitable material features and process steps and the implementation of dedicated CAD tools in a complete workflow are here reported. Moreover, the feasibility of the adopted technology is demonstrated by the design of both digital and analog circuits. Multilayered structure devices, like Organic Thin Film Transistor (OTFT), are used to design complex architectures like arithmetic logic units and nonlinear oscillators.     

Generators of the ideal of an algebraic space curve

In this paper we show that the ideal of any algebraic curve in affine 3-space whose Jacobian matrix has rank at least 1 at every singular point of the curve can be generated by three polynomials and we give constructive procedures to compute such generators.