Alternative fatty food simulants for migration testing of polymeric food contact materials.

The amounts of substances migrating from plastics into foodstuffs with high fat contents are in most cases higher than in foodstuffs with water contents. This increase in migration commonly is due to the higher solubility of the migrating organic compounds in fat compared to water. The increase in migration is not necessarily due to an increase in the substance's diffusion coefficient due to interactions between the fat and the plastic as is often assumed. Ethanol is a good simulant for fatty foods because it has little interaction with many plastics, e.g. polyolefins, migrants are readily soluble in it, and because it is easy to work with analytically. The utilizable limits of ethanol and ethanol/water mixtures as food simulants are developed from the physical background of diffusion. The use of ethanol and ethanol/water mixtures is supported by published experimental migration results.     

DIFFUSION LAG TIME FOR MULTIPLE AND PERIODIC LAMINATES

The permeability and lag time for a heterogeneous diffusion system, in which the diffusivity and partition coefficient for the diffusant are dependent on position, are formulated in terms of a linear asymptotic analysis. A repeated integration of the diffusion equation is used to obtain the time dependence of the total solute release into the receiver, Q(t). The asymptotic form of Q(t) is linear in time. The slope, and intercept of this linear asymptote with the time axis, respectively, give formulas for the steady-state permeability and lag time. These formulas are then applied to diffusion systems of multiple laminates, consisting of a series of different homogeneous slabs. Thus, for the first time, a concise treatment of diffusion in multiple laminates is obtained. The formulas are also applied to periodic laminates, consisting of a series of identical slabs, but with position-dependent diffusivity and partition coefficient. We found that the lag time can be well approximated by (nh))²/(6D_eff), where n and h are, respectively, the number and thickness of individual lamella, and D_eff is an effective diffusivity, for which a relation in terms of the local property distributions is obtained. This approximation becomes more accurate with increasing number of lamellae. At n = 5, the relative error is already within 4%. Finally a procedure is discussed for readily obtaining the lag time for periodic structures consisting of a serial repetition of a multi-laminate.     

Deciding the Word Problem for Ground and Strongly Shallow Identities w.r.t. Extensional Symbols

Journal of Automated Reasoning - The word problem for a finite set of ground identities is known to be decidable in polynomial time using congruence closure, and this is also the case if some of...     

The rust preventing mechanism of zinc dust paints

In atmospheric weathering the rust preventing mechanism of zinc dust paints is dominated by the sealing action of the zinc corrosion products on the paint surface. Under immersed conditions the time of cathodic protection of bare steel is dependent on the zinc content of the paints. An optimum zinc content has been found for all of the tested binders: polystyrene, vinyl copolymer and chlorinated rubber. Differences in the optimum zinc content arise mainly due to the different wetting of the pigment by the binders.