Pressurised chamber design for conducting rolling contact experiments with liquid refrigerant lubrication

A novel pressurised chamber was designed to construct a special purpose test rig to achieve saturated liquid state of refrigerants for lubricated rolling contact fatigue experiments. Traditional bench testing using refrigerants as the lubricant is difficult due to the gaseous phase at standard atmospheric conditions. Pressurising the concentrated contact test chamber is therefore necessary to evaluate at a liquid state and therefore simulate practical applications. The gas/liquid phase transitions have a significant influence on the lubricant properties and hence wear mechanisms. It is necessary to modify the wear test conditions for the Hydrocarbon (HC) and Hydrofluorocarbon refrigerants to obtain realistic simulation of refrigerator compressor tests. The chamber design and test rig are described in this paper. A preliminary experimental study of the influence of the HC (R600a) on rolling wear of the silicon nitride (Si₃N₄)/steel elements using the pressurised chamber is presented. Rolling fatigue test methods are adopted to measure the wear performance of silicon nitride/steel bearing materials. In this case the rolling wear mechanisms of Si₃N₄ were measured using R600a refrigerant lubrication.     

Future perspectives on sustainable tribology

This paper highlights the future perspectives of sustainable tribology by examining the economic, environmental and social impact of three tribological case studies. One case study examines the sustainability and durability of micro-CHP systems looking the tribological phenomena generated within a scroll expander system. The scroll is the main part of a specific micro-CHP system and experiences wear and cavitation damage. The tribological optimization of the scroll expander improves the sustainability of the micro-CHP unit while it has a serious economic and environmental impact to the consumers and to the society in general. Another case study is focused on friction and wear performance of lifeboat launch slipways. The causes of high friction and wear during the RNLI's lifeboat launches along an inclined slipway are investigated with a view to reducing the environmental impact due to slipway panel wear and lubricant release into the marine environment. The project encompasses the sustainable design of slipway panels using design modifications based on tribological investigations to double their lifespan, while environmental and economic impact was significantly reduced by the use of biodegradable greases and water as lubricants. The final case study involves an investigation of recycled plastic materials to replace polyurethane used on skateboard wheels, scooters and similar applications. Polyurethane (PU) is difficult to recycle. With the dwindling resources and environmental problems facing the world today, recycling for both waste reduction and resource preservation has become an increasingly important aspect of sustainability. The tribological results showed that recycled polycarbonate plastic can effectively act as a substitute to polyurethane wheels. Moreover, sustainability considerations showing the environmental benefits of the use of recycled plastics over PU include reducing the CO₂ footprint by 50% and the energy consumed by 60%, among other benefits. These case studies emphasise the importance of sustainable tribology in our epoch showing that increased sustainability performance can be achieved through tribology to a significant extent in many cases, providing stability to our world and more viable long term growth to our societies.     

Operational Analysis of a Quantum Dot Optically Gated Field-Effect Transistor as a Single-Photon Detector

We report on the operation of a novel single-photon detector, where a layer of self-assembled quantum dots (QDs) is used as an optically addressable floating gate in a GaAs/Al_0.2Ga_0.8As delta-doped field-effect transistor. Photogenerated holes charge the QDs, and subsequently, change the amount of current flowing through the channel by screening the internal gate field. The photoconductive gain associated with this process makes the structure extremely sensitive to light of the appropriate wavelength. We investigate the charge storage and resulting persistent photoconductivity by performing time-resolved measurements of the channel current and of the photoluminescence emitted from the QDs under laser illumination. In addition, we characterize the response of the detector, and investigate sources of photogenerated signals by using the Poisson statistics of laser light. The device exhibits time-gated, single-shot, single-photon sensitivity at a temperature of 4 K. It also exhibits a linear response, and detects photons absorbed in its dedicated absorption layer with an internal quantum efficiency (IQE) of up to (68 plusmn18)%. Given the noise of the detection system, the device is shown to operate with an IQE of (53 plusmn 11)% and dark counts of 0.003 counts per shot for a particular discriminator level.     

Endometriosis in monozygotic twins

OBJECTIVE: To describe the occurrence of endometriosis in monozygotic twins. DESIGN: Postal questionnaire plus confirmation of disease status. SETTING: Twins were recruited via the American Endometriosis Association and the National Endometriosis Society of Great Britain and via British gynecologists. RESULT(S): Fourteen twin pairs were concordant for endometriosis, and two were discordant. Nine pairs of twins had moderate-severe endometriosis. CONCLUSION(S): These findings contribute to the growing body of literature that suggests endometriosis has a genetic basis.     

Design and Characterisation of Titanium Nitride Subarrays of Kinetic Inductance Detectors for Passive Terahertz Imaging

We report on the investigation of titanium nitride (TiN) thin films deposited via atomic layer deposition (ALD) for microwave kinetic inductance detectors (MKID). Using our in-house ALD process, we have grown a sequence of TiN thin films (thickness 15, 30, 60 nm). The films have been characterised in terms of superconducting transition temperature \(T_\mathrm{c}\), sheet resistance \(R_\mathrm{s}\) and microstructure. We have fabricated test resonator structures and characterised them at a temperature of 300 mK. At 350 GHz, we report an optical noise equivalent power \(\hbox {NEP}_\mathrm{opt} \approx 2.3\times 10^{-15}~\hbox {W}/\sqrt{\hbox {Hz}}\), which is promising for passive terahertz imaging applications.     

Use of Sacrificial Piles as Pier Scour Countermeasures

Laboratory studies on the use of sacrificial piles as a pier scour countermeasure are reported. Sacrificial piles, which previous studies have shown to result in significant scour depth reductions under clear-water conditions, were found to be rather less effective under live-bed conditions due to the passage of bed forms. Sacrificial piles are not recommended unless the flow remains aligned and the flow intensity is relatively small.     

Tribological analysis of hydrocarbon refrigerants applied to the hermetic compressor

This paper describes the tribological impacts of hydrocarbon refrigerants deployed in the domestic refrigerator hermetic compressor. In-use durability is examined from a tribological viewpoint. Experimental tribological information is presented from physical test procedures involving sliding tests to establish wear mechanisms and friction coefficients within critical components. Hydrocarbon refrigerant R600a is compared with hydroflourocarbon R134a using aluminium on steel samples within a novel pressurised micro-friction test rig. The refrigerant R600a is tested for its influence upon the tribological performance of mineral oil (MO) and poly-ol-ester (POE) lubricant, whilst an R134a/POE charge combination is used as a benchmark. Although wear rates were significantly greater for samples utilising POE lubricants than for MO, the friction coefficients were much lower.     

Early stage cavitation erosion within ceramics—An experimental investigation

Six ceramic material types were considered within an experimental investigation to identify the erosion damage mechanisms resulting from cavitation exposure. These materials were a Y-TZP-type zirconia, different commercially available silicon nitrides, a high-purity alumina and a hardened high-nitrogen stainless steel as reference. An ultrasonic transducer was utilised to produce cavitation conditions and the configuration was “static specimen method” using a 5-mm diameter probe, 20-kHz and 50-μm amplitude. The exposure times were periods from 15 s to 3 h.Experimental methods employed to characterise wear mechanisms were light microscopy, scanning light interferometry and scanning electron microscopy.It was found that the zirconia and silicon nitrides demonstrated evidence of local pseudo-plastic deformation or depression prior to more pronounced erosion damage by fracture. Zirconia showed evidence of delayed surface changes when the sample is at rest stored in air, possibly by spontaneous phase transformation after the completion of the erosion tests. Alumina showed evidence of brittle surface fracture and negligible or no pseudo-plastic deformation. All wear mechanisms are discussed, and the materials are ranked in terms of cavitation resistance performance.     

FAP− Anion Ionic Liquids Used in the Lubrication of a Steel–Steel Contact

This study compares the tribological behavior of two ionic liquids ([BMP][FAP] and [(NEMM)MOE][FAP]) used as oil additive for the lubrication of a steel–steel contact. Friction and wear experiments were performed using a HFRR test machine. Friction coefficient and electrical contact resistance were measured during the tests, and the wear surface was analyzed by confocal microscopy and XPS. The tribological results showed that both ionic liquids used as additive decrease friction and wear but the [BMP][FAP] had a better performance than the [(NEMM)MOE][FAP] due to its higher reactivity with the steel.