Preparation and antibacterial activity of novel fluoroalkyl end-capped oligomers/silica nanocomposites-encapsulated low molecular biocides

Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer [R_F-(DOBAA) _n -R_F] reacted with tetraethoxysilane (TEOS) and silica nanoparticles in the presence of low-molecular weight biocides such as hibitane, hinokitiol, and hinokioil under alkaline conditions to afford R_F-(DOBAA) _n -R_F/silica nanocomposites-encapsulated these biocides in excellent to moderate isolated yields. Fluoroalkyl end-capped N,N-dimethylacrylamide oligomer [R_F-(DMAA) _n -R_F] and acrylic acid oligomer [R_F-(ACA) _n -R_F]/silica nanocomposites-encapsulated hibitane were obtained under similar conditions. Dynamic light scattering measurements showed that the size of these fluorinated nanocomposites-encapsulated biocides thus obtained is nanometer size-controlled. Additionally, these fluorinated nanocomposites were shown to have a good dispersibility and stability in methanol and water. Of particular interest, these fluorinated nanocomposites-encapsulated biocides were found to have a good antibacterial activity against Staphylococcus aureus, and these nanocomposites were applied to the surface modification of traditional organic polymers such as poly(methyl methacrylate).     

A stochastic realization algorithm via block LQ decomposition in Hilbert space

A stochastic realization problem of a stationary stochastic process is re-visited, and a new stochastically balanced realization algorithm is derived in a Hilbert space generated by second-order stationary processes. The present algorithm computes a stochastically balanced realization by means of the singular value decomposition of a weighted block Hankel matrix derived by a “block LQ decomposition”. Extension to a stochastic subspace identification method explains how the proposed abstract algorithm is implemented in system identification.     

Stabilization of bioethanol recovery with silicone rubber‐coated ethanol‐permselective silicalite membranes by controlling the pH of acidic feed solution

In order to produce highly concentrated bioethanol by pervaporation using an ethanol‐permselective silicalite membrane, techniques to suppress adsorption of succinic acid, which is a chief by‐product of ethanol fermentation and causes the deterioration in pervaporation performance, onto the silicalite crystals was investigated. The amount adsorbed increased as the pH of the aqueous succinic acid solution decreased. The pervaporation performance also decreased with decreasing pH when the ternary mixtures of ethanol/water/succinic acid were separated. Using silicalite membranes individually coated with two types of silicone rubber, pervaporation performance was significantly improved in the pH range of 5 to 7, when compared with that of non‐coated silicalite membranes in ternary mixtures of ethanol/water/succinic acid. Moreover, when using a silicalite membrane double‐coated with the two types of silicone rubber, pervaporation performance was stabilized at lower pH values. In the separation of bioethanol by pervaporation using the double‐coated silicalite membrane, removal of accumulated substances having an ultraviolet absorption maximum at approximately 260 nm from the fermentation broth proved to be vital for efficient pervaporation. Copyright © 2005 Society of Chemical Industry     

Pressure anomaly in the paramagnetic region of bcc solid3He

The isochoric pressure of bcc Solid³He in the vicinity of the triple point has been measured by changing the temperature stepwisely and waiting for thermal equilibrium. We observed anomalous pressure kinks of the temperature dependence in the paramagnetic region near the triple point. This anomaly appeared at 0.37 to 0.40 tesla, and disappeared below 0.36 tesla. Moreover, critical phenomena at the transition point from the paramagnetic phase (PP) to the high field phase was observed and the phase line curves toward the PP side.     

Characteristics of hydrogen-fueled gas turbine cycle with intercooler,hydrogen turbine and hydrogen heater

The performances of a hydrogen-fueled gas turbine cycle equipped with an intercooler, regenerator, hydrogen turbine and recuperative hydrogen heater are analyzed. The intercooler is very effective to prevent the condensation and freezing of water vapor in cooling the suction air. The operation of hydrogen turbine in low-temperature range can also be prevented by adopting hydrogen heater. Thermodynamic analysis has revealed that the thermal efficiency and the specific output are considerably improved compared to those of the simple gas turbine cycle.     

Synthesis and surface properties of novel fluoroalkyl end-capped amphiphilic fullerene cooligomers

New fluoroalkyl end-capped fullerene cooligomers were prepared by the reactions of fluoroalkanoyl peroxides with fullerene and comonomers such as acryloylmorpholine, N,N-dimethylacrylamide and acrylic acid. These fluorinated fullerene cooligomers were easily soluble in water and common organic solvents, and were able to reduce the surface tensions of both water and benzene, quite effectively. Additionally, these fullerene cooligomers were found to form a stable monomolecular film at the air-water interface, and the modified polystyrene surface treated with these cooligomers was shown to have a strong hydrophilicity with good oil repellency.     

Characterization of the cell leakage of a stacked trench capacitor(STT) cell

The cell leakage of a stacked trench capacitor (STT) cell has been investigated. The major leakage mechanisms of the STT are trench-to-trench leakage, trench junction leakage, and LOCOS isolation leakage. It is shown that compared to a conventional trench capacitor, the trench-to-trench leakage current is reduced and high punchthrough voltage is obtained. Therefore, the trench-to-trench spacing can be reduced 0.1 μm shorter than that of the trench capacitor. These reductions result from the STT structure itself. The surface leakage current, which is the dominant leakage current in the trench capacitor, does not flow in the STT. This paper also describes the effect of the sidewall damage caused by trench etching on the trench junction leakage. Reactive ion etching (RIE) produces deep levels just beneath the trench surface. But, the trench junction of the STT is not influenced by these deep levels because the trench surface is covered by a n^-diffused layer. This paper also investigates the relationship between the cell leakage and the retention time. At DRAM operation temperatures, LOCOS isolation leakage is dominant rather than trench junction leakage. Therefore, the deeper trench can increase the storage capacitance and improve the retention time     

Focusing characteristics of a wide-striped laser diode integratedwith a microlens

We developed a wide-striped laser diode integrated with a microlens that provides good focusing characteristics through a small focusing spot. We calculated and demonstrated that a 60-μm-wide core and a 1.9-μm-high ridge is the best structure for fundamental index-guiding mode oscillation of a wide-striped laser diode. We integrated a wide-striped laser diode with the developed microlens in the Fresnel diffraction held, and demonstrated that a device with a 60-μm-wide core has a minimum focusing spot width of 2.0 μm in the horizontal direction. Also, we estimated the wavefront in the Fresnel diffraction field from the working distance error of a lens designed for a collimated incident beam, and showed that the working distance error, focusing spot width, and sidelobe can be improved by this estimated wavefront     

An integrated laser blood flowmeter

We have constructed a very small and lightweight blood flowmeter using micromachining and surface mounting techniques for a wearable health monitoring system. The hybrid integrated structure of the optical system incorporates a InGaAsP-InP distributed feedback laser diode (DFB-LD) with a wavelength of 1310 nm, an edge-illuminated photodiode (PD) and a polyimide waveguide on silicon substrate (2 mm /spl times/ 3 mm). This integrated flowmeter can be positioned directly on the tissue and permits real-time monitoring of capillary microcirculation. In-vivo measurements of blood perfusion in a finger confirm the feasibility of the blood flowmeter.