Random poly(ε‐caprolactone‐L‐alanine) by direct melt copolymerization

A series of random polyesteramides (PEAs) with a range of molar composition from 90/10 to 50/50 were synthesized by direct melt polycondensation of ε‐caprolactone and l ‐alanine. Their structure was fully characterized by Fourier transform IR and NMR spectroscopy. The resulting copolymers are completely amorphous with the exception of PEA‐90/10 which possesses a semicrystalline structure. These PEAs present increasing glass transition temperatures at increasing l ‐alanine contents and exhibit fairly good thermal stability with 10% mass loss temperatures reaching 315 °C. © 2020 Society of Industrial Chemistry     

A comparative study of the electrochemical behaviour of Algerian zinc and a zinc from a commercial sacrificial anode

Zinc is used in the oil industry as a sacrificial anode for protecting steel storage tanks from corrosion. The behaviour of a sample of zinc from the Algerian metallurgy industry (zinc A) and a commercially available zinc (zinc B) was compared in an electrolyte from storage tank drainage water. The corrosion potential measurements for zinc A confirmed that this material could be used as a sacrificial anode. The polarization curves of the two materials (zinc A and zinc B) were different, zinc A being the least polarized. Thus, the same corrosion protection could be obtained with a lower surface ratio (S _Zn/S _Fe) for Zinc A. Cyclic voltammetry curves provided evidence of a surface layer formed by dissolution products. To provide protection over extended periods of time, the zinc anode must be oversized. The two types of zinc tested were comparable.The results of the impedance spectroscopy study confirmed the previous results. The corrosion layer formed on zinc A was not prejudicial to dissolution. Hence, the properties of this zinc were found to be satisfactory for its use as a sacrificial anode.     

高精度节能型电力稳压器

分析了现有交流稳压器的特点和不足,提出了新一代数控稳压器的理论和实际无均差系统的方法,给出了超高精度无均差稳压系统的实现方法.经全乐科技公司模拟试验,获得了很好的结果.市电220.4 V和220.5 V,试验样机采用3 V、9 V和27 V这3个变压器,已达到优于±1%的精度,符合大部分负载的实际需要,经用户单位试用半年,效果非常满意.     

The vehicle routing problem with restricted mixing of deliveries and pickups

The vehicle routing problem with deliveries and pickups is one of the main problems within reverse logistics. This paper focuses on an important assumption that divides the literature on the topic, namely the restriction that all deliveries must be completed before pickups can be made. A generalised model is presented, together with a mathematical formulation and its resolution. The latter is carried out by adopting a suitable implementation of the reactive tabu search metaheuristic. Results show that significant savings can be achieved by allowing a mixture of delivery and pickup loads on-board and yet not incurring delays and driver inconvenience.     

Lateral Magnetically Modulated Multilayers by Combining Ion Implantation and Lithography

The combination of lithography and ion implantation is demonstrated to be a suitable method to prepare lateral multilayers. A laterally, compositionally, and magnetically modulated microscale pattern consisting of alternating Co (1.6 µm wide) and Co‐CoO (2.4 µm wide) lines has been obtained by oxygen ion implantation into a lithographically masked Au‐sandwiched Co thin film. Magnetoresistance along the lines (i.e., current and applied magnetic field are parallel to the lines) reveals an effective positive giant magnetoresistance (GMR) behavior at room temperature. Conversely, anisotropic magnetoresistance and GMR contributions are distinguished at low temperature (i.e., 10 K) since the O‐implanted areas become exchange coupled. This planar GMR is principally ascribed to the spatial modulation of coercivity in a spring‐magnet‐type configuration, which results in 180° Néel extrinsic domain walls at the Co/Co‐CoO interfaces. The versatility, in terms of pattern size, morphology, and composition adjustment, of this method offers a unique route to fabricate planar systems for, among others, spintronic research and applications.     

Fabrication and Optical Properties of Periodic Ag Nano‐Pore and Nano‐Particle Arrays with Controlled Shape and Size over Macroscopic Length Scales

A facile and economical route to preparation of highly ordered sliver pore or particle arrays with controlled pore‐shape and size extended over cm² areas is described. The substrates are prepared at planar and curved surfaces via sphere‐imprinted polymer (PDMS) templating using polystyrene spheres with diameters of 820, 600, or 430 nm. Nano‐pore arrays are created by sputtering 80 nm of Ag directly onto the templates and nano‐particle arrays are prepared by electrode‐less deposition of Ag from Tollen's reagent. The shape of the nano‐pore or particles in the array conformed to that of the imprint of the sphere on the template. Stretching the flexible template enable creation of cuboid shaped nano‐voids and nano‐particles following Ag deposition. Diffuse reflectance from the spherical Ag nano‐cavity arrays showed absorbance maxima at wavelengths comparable similar to the diameter of the templating sphere, whereas reflectance from the cuboid arrays, showed little correlation with the sphere diameter. The cuboid nano‐particle arrays showed the most intense visible absorption which is red‐shifted compared to the spherical arrays. White light diffraction from the arrays, observed by rotating 1 cm² substrates relative to a fixed light source, reflected exactly the symmetry axes of the periodic nano‐features in the arrays demonstrating the remarkable macroscopic order of the periodic structures. Raman spectra of 1‐benzenethiol adsorbed at the arrays indicated SERS enhancements from the substrates are attributed mainly to surface nano‐roughness with only moderate contributions from the periodically corrugated structures. Despite excitation at the major resonance dip in the reflectance spectrum, a weak, localized rim dipole mode is found to elicit a small increase in the SERS enhancement factor for the 430 nm diameter spherical arrays. FDTD studies of nano‐void arrays provided insights into v arious factors affecting the SERS experiment and confirmed the array's plasmonic spectra are dominated by propagating plasmon modes under microscope excitation/collection angles.     

Artificial intelligence implementation in the APS process diagnostic

Thermal spray process is a technique of coating manufacturing implementing a wide variety of materials and processes. This technique is characterized by up to 150 processing parameters influencing the coating properties. The control of the coating quality is needed through the consideration of a robust methodology that takes into account the parameter interdependencies, the process variability and offers the ability to quantify the processing parameter-process response relationships. The aim of this work is to introduce a new approach based on artificial intelligence responding to these requirements. A detailed procedure is presented considering an artificial neural network (ANN) structure which encodes implicitly the physical phenomena governing the process. The implementation of such a structure was coupled to experimental results of an optic sensor controlling the powder particle fusion state before the coating formation. The optimization steps were discussed and the predicted results were compared to the experimental ones allowing the identification of the control factors.     

Provably safe navigation for mobile robots with limited field-of-views in dynamic environments

This paper addresses the problem of navigating in a provably safe manner a mobile robot with a limited field-of-view placed in a unknown dynamic environment. In such a situation, absolute motion safety (in the sense that no collision will ever take place whatever happens in the environment) is impossible to guarantee in general. It is therefore settled for a weaker level of motion safety dubbed passive motion safety: it guarantees that, if a collision takes place, the robot will be at rest.     

Abundant non-toxic materials for thin film solar cells: Alternative to conventional materials

Presented are the results of a comparative analysis to identify abundant, non-toxic binary materials with potential applicability for photovoltaics. Materials other than the conventional Si, CdTe, and Cu(In,Ga)Se₂ (CIGS) are examined. The screening is based on the materials’ bulk properties and a set of environmental, physical, and chemical criteria. The screening process is detailed and the properties and applicability of the screened materials are discussed.