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排序方式: 共有77条查询结果,搜索用时 15 毫秒
1.
Koen Nickmans Gerardus M. Bögels Carlos Sánchez‐Somolinos Jeffrey N. Murphy Philippe Leclère Ilja K. Voets Albertus P. H. J. Schenning 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(33)
While self‐assembled molecular building blocks could lead to many next‐generation functional organic nanomaterials, control over the thin‐film morphologies to yield monolithic sub‐5 nm patterns with 3D orientational control at macroscopic length scales remains a grand challenge. A series of photoresponsive hybrid oligo(dimethylsiloxane) liquid crystals that form periodic cylindrical nanostructures with periodicities between 3.8 and 5.1 nm is studied. The liquid crystals can be aligned in‐plane by exposure to actinic linearly polarized light and out‐of‐plane by exposure to actinic unpolarized light. The photoalignment is most efficient when performed just under the clearing point of the liquid crystal, at which the cylindrical nanostructures are reoriented within minutes. These results allow the generation of highly ordered sub‐5 nm patterns in thin films at macroscopic length scales, with control over the orientation in a noncontact fashion. 相似文献
2.
Thomas Frissen Erkan Toguslu Pieter Van Ostaeyen Leen dHaenens 《Telematics and Informatics》2018,35(2):491-503
The current study set out to investigate to what extent ISIS is bolstering its jihadist ideology on a ‘cut-and-paste’ or ‘cherry-picked’ version of Islam in their renowned online propaganda magazine Dabiq. The main objective was to examine in a systematic and quantitative way to what extent ISIS utilizes the Koran in an atomistic, truncated and tailored manner to bolster its religious legitimacy. A total of 15 issues of Dabiq and 700 Koranic references were scrutinized. By means of a quantitative analysis we developed an innovative taxonomy of Koranic chapters and verses (i.e. surahs and ayat, respectively) on the basis of their appearance in Dabiq. Our large-scale data analysis provide consistent empirical evidence for severe decontextualization practices of the Koran in three ways: (1) a thin, Medinan-dominated religious layer, (2) ayah mutilation, and (3) clustered versus exclusive mentions. Limitations and implications for future research, policy makers and CVE initiatives are discussed. 相似文献
3.
Robert F. DeJaco Matheus Dorneles de Mello Huong Giang T. Nguyen Mi Young Jeon Roger D. van Zee Michael Tsapatsis Joern Ilja Siepmann 《American Institute of Chemical Engineers》2020,66(4):e16868
In this work, batch-adsorption experiments and molecular simulations are employed to probe the adsorption of binary mixtures containing ethanol or a linear alkane-1,n-diol solvated in water or ethanol onto silicalite-1. Since the batch-adsorption experiments require an additional relationship to determine the amount of solute (and solvent) adsorbed, as only the bulk liquid reservoir can be probed directly, molecular simulations are used to provide a relationship between solute and solvent adsorption for input to the experimental bulk measurements. The combination of bulk experimental measurements and simulated solute–solvent relationship yields solvent and solute loadings that are self-consistent with simulation alone, and allow for an assessment of the various assumptions made in the literature. At low solution concentrations, the solute loading calculated is independent of the assumption made. At high concentrations, a negligent choice of assumption can lead to systematic overestimation or underestimation of calculated solute loading. 相似文献
4.
Fabio Fais Reda Juskeviciene Veronica Francardo Stphanie Mateos Manuela Guyard Ccile Viollet Samuel Constant Massimo Borelli Ilja P. Hohenfeld 《International journal of molecular sciences》2022,23(7)
The nasal epithelium is a key portal for infection by respiratory viruses such as SARS-CoV-2 and represents an important target for prophylactic and therapeutic interventions. In the present study, we test the safety and efficacy of a newly developed nasal spray (AM-301, marketed as Bentrio) against infection by SARS-CoV-2 and its Delta variant on an in vitro 3D-model of the primary human nasal airway epithelium. Safety was assessed in assays for tight junction integrity, cytotoxicity and cilia beating frequency. Efficacy against SARS-CoV-2 infection was evaluated in pre-viral load and post-viral load application on airway epithelium. No toxic effects of AM-301 on the nasal epithelium were found. Prophylactic treatment with AM-301 significantly reduced viral titer vs. controls over 4 days, reaching a maximum reduction of 99% in case of infection from the wild-type SARS-CoV-2 variant and more than 83% in case of the Delta variant. When AM-301 administration was started 24 h after infection, viral titer was reduced by about 12-folds and 3-folds on Day 4. The results suggest that AM-301 is safe and significantly decelerates SARS-CoV-2 replication in cell culture inhibition assays of prophylaxis (pre-viral load application) and mitigation (post-viral load application). Its physical (non-pharmaceutical) mechanism of action, safety and efficacy warrant additional investigations both in vitro and in vivo for safety and efficacy against a broad spectrum of airborne viruses and allergens. 相似文献
5.
Recent research indicates that ostracism is painful even in the face of mitigating circumstances. However, in all previous experiments, there have been no costs to inclusion or benefits for ostracism. If being included meant losing money and being ostracized meant retaining money, would individuals still be distressed when ostracized? In 2 studies, the authors attempted to "load the dice" against inclusion in favor of ostracism. Participants played a variant of Cyberball called ?berball (pronounced Euroball), in which ostracism and inclusion were crossed with whether the participants earned or lost money for each ball toss they received. In 2 experiments, the authors found that even when being ostracized meant retaining more money than the other players, it was painful. In Study 2, the authors also introduced conditions in which participants were overincluded. In these conditions, participants were sensitive to financial incentives. However, even then participants felt worse when given no positive attention than when given punitive attention. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
6.
Juraj Doupovec Ilja Thurzo Drahoslav Barančok Victoria P. Shilo 《Materials Research Bulletin》1977,12(2):119-125
When cooling a melt the cooling rate in different layers varies due to differences in heat transfer. These changes in cooling rate were determined experimentally for the As2S3 melt in a quartz ampoule with diameter of 17 mm. The cooling rate at air quenching varies from 1.36 K/s in the bulk middle to 2.11 K/s in the border layers, and from 3.54 to 38.80 K/s for water quenching, respectively. Further, the corresponding changes in the density, microhardness, glass-transition temperature and electrical conductivity in dependence on the choice of the measured sample from various parts of the bulk were found. The anomalous behaviour of these parameters in dependence on the cooling rate corresponds to the polymeric structure of the glass. 相似文献
7.
Valincius G Ignatjev I Niaura G Kazemekaite M Talaikyte Z Razumas V Svendsen A 《Analytical chemistry》2005,77(8):2632-2636
A novel electrochemical technique for the general assay of lipase activity is described. The method utilizes a solid-supported lipase substrate, which is formed by dripping and drying a small amount of an ethanol solution of 9-(5'-ferrocenylpentanoyloxy)nonyl disulfide (FPONDS) onto gold modified by a hexanethiol self-assembled monolayer. The redox ferrocene group of FPONDS generates the electrochemical signal, the intensity of which is proportional to the number of FPONDS molecules at the interface. Electrochemical and surface-enhanced infrared absorption spectroscopic data, as well as control experiments with an engineered, deactivated mutant enzyme, demonstrate that the wild-type lipase from Thermomyces lanuginosus is capable of cleaving the ester bonds of FPONDS molecules via an enzymatic hydrolysis mechanism, which includes the adsorption of the lipase onto the substrate surface. The hydrolysis liberates the ferrocene groups from the interface triggering a decay of the electrochemical redox signal. The rate of the electrochemical signal decrease is proportional to the lipase activity/concentration. These data suggest a general method for the direct measure of enzymatic activity of lipases. 相似文献
8.
J. Ilja Siepmann 《Tribology Letters》1995,1(2-3):191-199
Configurational-bias Monte Carlo calculations have been used to study the mechanical relaxation of a monolayer of CH3(CH2)15S admolecules on a gold substrate when subjected to indentation by a force-microscope tip. Compression leads to substantial but reversible changes in molecular tilt angle and chain conformations. The same Monte Carlo technique has been used to probe the structural properties of liquid hexadecane films in contact with a flat metal substrate. 相似文献
9.
Ilja Vladimirov Sebastian Müller Roelf‐Peter Baumann Thomas Geßner Zahra Molla Souren Grigorian Anna Khler Heinz Bssler Ullrich Pietsch Ralf Thomas Weitz 《Advanced functional materials》2019,29(12)
The fundamental nature of charge transport in highly ordered organic semiconductors is under constant debate. At cryogenic temperatures, effects within the semiconductor such as traps or the interaction of charge carriers with the insulating substrate (dipolar disorder or Fröhlich polarons) are known to limit carrier motion. In comparison, at elevated temperatures, where charge carrier mobility often also decreases as function of temperature, phonon scattering or dynamic disorder are frequently discussed mechanisms, but the exact microscopic cause that limits carrier motion is debated. Here, the mobility in the temperature range between 200 and 420 K as function of carrier density is explored in highly ordered perylene‐diimide from 3 to 9 nm thin films. It is observed that above room temperature increasing the gate electric field or decreasing the semiconducting film thickness leads to a suppression of the charge carrier mobility. Via X‐ray diffraction measurements at various temperatures and electric fields, changes of the thin film structure are excluded as cause for the observed mobility decrease. The experimental findings point toward scattering sites or traps at the semiconductor–dielectric interface, or in the dielectric as limiting factor for carrier mobility, whose role is usually neglected at elevated temperatures. 相似文献
10.
In this work we consider the learning setting where, in addition to the training set, the learner receives a collection of auxiliary hypotheses originating from other tasks. We focus on a broad class of ERM-based linear algorithms that can be instantiated with any non-negative smooth loss function and any strongly convex regularizer. We establish generalization and excess risk bounds, showing that, if the algorithm is fed with a good combination of source hypotheses, generalization happens at the fast rate \(\mathcal {O}(1/m)\) instead of the usual \(\mathcal {O}(1/\sqrt{m})\). On the other hand, if the source hypotheses combination is a misfit for the target task, we recover the usual learning rate. As a byproduct of our study, we also prove a new bound on the Rademacher complexity of the smooth loss class under weaker assumptions compared to previous works. 相似文献