Expanding the Dynamic Modeling of Water-Food-Energy Nexus to Include Environmental,Economic, and Social Aspects Based on Life Cycle Assessment Thinking

The concept of the water-food-energy nexus has been widely studied in the past decade. In this paper we expand on this concept to include environmental, economic, and social aspects as well as life cycle assessment based thinking. We proposed a set of Environmental Footprint Assessment, Life Cycle Assessment, and Socio-Economic Assessment indicators and calculated them using a developed System Dynamic Model for Water-Land-Food-Energy-Environment-Economic-Social Nexus (SD-WLF3ESN). The developed model was applied to predict the WLF3ESN of the corn crop in the Western Lake Erie Basin (WLEB)-USA for the period 2016-2030. The prediction was based on scenarios for population, land, yield, crop use, and crop production costs and returns at the county level of WLEB. A matrix for WLF3ESN of the corn crop in WLEB was developed. This matrix can help in developing policies and strategies for managing the nexus in the basin.

     

Effect of different application techniques on microshear bond strength of self-etch adhesives to dentin

Objectives: To investigate the effect of different self-etch adhesive systems application techniques: active or passive in a single or double layer on adhesive–dentin microshear bond strength.

Methods: Occlusal surfaces of 48 extracted human molars were ground to expose flat superficial dentin surfaces. Specimens were randomly divided into two main groups according to the tested self-etch adhesive system either: One-step self-etch (Adper^TM easy-one) or two-step self-etch (Adper^TM SE Plus). Each adhesive system was applied on the prepared dentin surfaces followed one of these techniques: (1) Passive application of a single layer, (2) Active application of single layer, (3) Passive application of double adhesive layer (with light curing in between), and (4) Active application of double adhesive layers. Resin composite was packed inside micro-tubes fixed on the bonded dentin surfaces and light cured for 40 s. All specimens were stored in artificial saliva either for 24 h or 3 months before testing. Microshear bond strength test was employed using a universal testing machine at a crosshead speed of 0.5 mm/min.

Results: Adper^TM SE Plus showed higher significant microshear bond strength in compared with Adper^TM easy-one. For both adhesive systems active application showed higher significant microshear bond strength to dentin than passive application. Double application of adhesive systems showed lower microshear bond strength than single application.

Conclusion: Active application of self-etch adhesives could improve the dentin microshear bond strength. Double application with curing in between the layers did not improve the bond strength to the tested adhesive.     

Thermocatalytic decomposition of methane using activated carbon: Studying the influence of process parameters using factorial design

The thermocatalytic decomposition of methane over activated carbon (AC) is proposed as a potential alternative for the production of hydrogen. The experiments were divided into two parts; the first part was conducted using thermogravimetric analyzer (TGA) while the second part was conducted in a bench-scale unit. For the first part, the research objective is to study the main and interaction effects of decomposition temperature (800-950 °C) and methane partial pressure (0.03-0.63 atm) on the initial specific rate of carbon formation by using statistical method. The experiments were carried out as a general full factorial design consisting of 20 experiments. Quadratic model was developed for initial specific rate of carbon formation in term of temperature and methane partial pressure using response surface methodology. The model’s results show that not only the effects of the main parameters are important, but also the interaction effects between them are significant. For the second part, the main effects of decomposition temperature (775-850 °C) and AC weight (20-120 g) on the initial rate of methane decomposition by using the analysis of variance (ANOVA) were investigated. The results showed that AC weight has higher mean effects than decomposition temperature on the initial rate of methane decomposition.     

Current Operational Amplifier (COA): CMOS Realization and Active Compensation

A methodology for analysis and synthesis of lowpass sigma-delta () converters is presented in this paper. This method permits the synthesis of modulators employing continuous-time filters from discrete-time topologies. The analysis method is based on the discretization of a continuous-time model and using a discrete simulator, which is more efficient than an analog simulator. In our analysis approach, the influence of the sample and hold block and non-idealities of the feedback DAC can be systematically modeled by discrete-time systems. Finally, a realistic design of a second-order modulator with a compensation of the non-ideal behavior of the DAC is given. Moreover, simulation results show a good agreement with the theoretical predictions.     

New high accuracy CMOS current conveyors

In this paper, a new CMOS CCII⁺ is proposed. The circuit is characterized by high precision in voltage tracking and exhibits very low input resistance. An adaptive voltage offset cancellation methodology is introduced and then applied to the proposed circuit. As a result, a higher accuracy CCII⁺ is presented. For both circuits, the voltage offset cancellation is independent of the input current and voltage. To demonstrate the strength of the proposed architectures, fair comparisons with Liu and Yodprasit CCII realizations are held.     

New Wide Band Low Power CMOS Current Conveyors

New Class-A second-generation CMOS current conveyor (CCII) suitable for high frequency applications is proposed. It provides low input impedance and accurate voltage and current tracking. Targeting low power dissipation, the Class-AB version of the proposed Class-A architecture is introduced as well. Simulation results are included.     

Water-Food-Energy: Nexus and Non-Nexus Approaches for Optimal Cropping Pattern

Given the water-food-energy interconnections, integrated planning, policy and management using the nexus approach are required for the food production system. In this study the nexus and non-nexus approaches are compared to propose an optimal cropping patternthat considers water, energy and economic parameters. Linear optimization was applied to compare i) the nexus approach utilizing an objective function to maximize a water-food-energy nexus index and 2) the non-nexus approach utilizing three objective functions for water use, energy use, and agricultural net return. The study showed that the nexus approach is the best. Applying it through a water-food-energy nexus index provides a holistic method for identifying an optimal cropping pattern that reduces water and energy consumption and increases the agricultural net return.     

Ionic liquids as novel surfactants for potential use in enhanced oil recovery

The screening and use of benign chemicals for enhanced oil recovery (EOR) applications is important because of their properties and relationship to the embedded fluids. We investigated a special type of ionic liquids (ILs) called “Ammoeng” for potential use in surfactant EOR to replace the currently used surfactants that have many disadvantages. The interfacial tension (IFT) between a representative oil sample from Saudi reservoirs and solutions of Ammoeng? ILs at different concentrations in 10 wt% NaCl aqueous solutions were measured as a function of temperature. It was found that the IFT values decreased with the increase of IL concentration. However, the effect of temperature on the IFT depended on the type of IL. Ammoeng? 102 gave the lowest IFT values among the screened ILs. The comparison of the results to those resulting from TritonX100, a commercially used surfactant, showed that the IFT values using Ammoeng? 102 were smaller than the corresponding values when TritonX100 was used at the same conditions. The possibility of having a synergetic effect when using a mixture of Ammoeng? 102 and Triton X 100 was also investigated. The results showed that the IFT values depended on the total concentration, the surfactant to IL mass ratio, and the temperature.     

Target delivery and controlled release of the chemopreventive drug sulindac by using an advanced layered double hydroxide nanomatrix formulation system

Target delivery and controlled release of the chemopreventive drug sulindac that possesses low water solubility present a great challenge for its pharmaceutical industry. Here, we offered an advanced nanomatrix formulation system of sulindac based on layered double hydroxide materials. The X-ray analysis and infrared spectroscopy confirmed the incorporation of sulindac into the gallery of the layered double hydroxides. The incorporation ratios of sulindac were recorded to be 45, 31 and 20 for coprecipitation, anion-exchange and reconstruction techniques, respectively. The scanning electron microscopy showed a nanomatrix-structure of ~50 nm. The release studies of sulindac-nanomatrix showed a 96% controlled release at the small intestine solution during 3 h(s), indicating an enhancement in the dissolution profile of sulindac after the matrix formation. The layered structure of the matrix supplied sulindac with a well-ordered structure and a relatively hydrophobic microenvironment that controlled the guest hydrolysis and reactivity during the release process. The laminar structure of layered double hydroxides offered a safe preservation for sulindac against photodecarboxylation, and enhanced the drug thermal stability from 190 to 230° C. The ionic electrostatic interaction of sulindac through its acidic group with layered double hydroxides demolished the gastrointestinal ulceration.