基于WSN的粮情监测系统LEACH改进协议研究与应用

首先介绍了基于WSN的粮情仓储监测系统的结构,针对粮仓温度监控的特殊环境,分析了经典LEACHE协议中簇头节点能量消耗过大和簇头节点与网关通信距离长的不足,提出以节点综合信息作为簇头节点选取的标准,同时通过限制簇内节点数目,在传输中结合簇内单跳、簇间与网关单跳与多跳结合的数据传输方式;最后将提出的改进算法在布设50个节点的粮仓中运行半年,经测量回收节点电池电压,90%节点均有效减少消耗,延长网络整体生存时间,较好地满足实际应用要求,为大型粮库设施现代化管理奠定了基础。     

基于 MMS服务的继电保护装置协议漏洞挖掘方法

工控系统网络安全的测评认证在国内还处于起步阶段,测试方法、测试流程和推广程度仍有待完善.结合IEC 61850继电保护装置特点和目前工控网络协议测试现状,围绕MMS服务在电力系统中的实际应用场景,对继电保护装置进行更深入的协议漏洞挖掘.     

A formal framework for service mashups with dynamic service selection

The service mashup programming paradigm is a blooming faction of service oriented Architecture for developing web applications. A mashup application constructs its functionality by combining data, presentation and functionalities obtained from online services published by service providers such as Google and Amazon. This paradigm significantly facilitates the implementation of application and reduces the workload. But it also makes the application rely on the availability and qualities of the online services which beyond its control in which case the robustness of the system requires more concern. This paper proposes a formal model to specify and analyze the behavior and robustness of service mashups under a certain environment where some services may become unavailable. The specification contains both system specification and environment situation. Refinement theory are employed to specify the correctness of dynamic service selection. The framework realizes the service selection by allowing virtual service requests to be handled by any online service having consistent interface and refined functionality. The framework provides a clear definition of the robustness of mashup systems and proposes several rules as well as approaches to preserve the robustness during the development and maintenance of the system.     

基于SSH2框架的Web应用

本文给出了SSH2框架的设计原理和实现,即如何借助Struts2、Spring3、Hibernate3以及Ajax技术实现Web应用。文中先给出了整体框架的优势,并按照MVC模式对每层分别进行详细说明,最后以高校科研管理系统设计与实现为例,对整合的架构应用进行具体地实现。结果表明,整个系统具有平台无关性,并提高了应用系统的灵活性、可维护性、可扩展性、可移植性和组件的可复用性。     

Preparation of YAG powder by co-precipitation method in a narrow pH-change environment

YAG(Y3Al5O12) powder was prepared by co-precipitation method.To avoid pH values changing intensely during titration process,the 4 3 NH HCO solution with 4 3 NH NO was used as precipitant solution.The pH change of precipitant solution during titration process,compositions of precursor,phase formation process and morphology of the prepared powder were investigated by means of pH meter,FT-IR,XRD and TEM.The results show that the presence of 4 3 NH NO in 4 3 NH HCO solution is crucial to alleviate the pH change,lower the calcination temperature and meliorate the morphology of YAG powder.The mechanisms were studied in detail.The YAG phase can be obtained at a lower temperature of 900 ℃.The obtained powder,composed of elliptical particles,showed a meliorated morphology.     

两步干法腈纶工艺聚合反应配方的特点

对恒定反应条件下 ,两步干法腈纶工艺不同聚合产率配方中各物料的用量进行了分析 ,提出了物料用量的选择依据与合理范围。从反应机理上探讨了中和剂与终止剂的作用本质 ;HSO3- /SO4 -·比例可以作为催化剂用量选择范围的代用指标 ;受亚磺酸稳定性的影响 ,第三单体用量随反应产率的提高而显著下降。     

一种巴特沃斯低通滤波器构成的PWM转DAC设计

本文提出一种巴特沃斯有源低通滤波器构成的PWM转DAC设计,利用STC8单片机片内12位分辨率的PWM发生器产生了频率为10 kHz、占空比可变的PWM信号。将信号送入巴特沃斯低通滤波器后,PWM信号转换为直流电压,电压幅度与PWM信号占空比呈正比变化,转换得到的直流电压纹波小于0.2 mV,转换分辨率可达1/12位。转换电路线性度较高、纹波小、谐波抑制比较高。相比于专用DAC芯片或PAC芯片而,该方案性价比高,可以适配于分辨率要求高、建立时间要求一般的应用场景。     

基于人工神经网络的铝熔体中氢的预测

用HyscanⅡ型测氢仪测定了铝熔体在不同温度和保温时间下的氢含量 ,通过对BP人工神经网络的分析和改进 ,采用了结构为 2 4 2 1的BP神经网络模型 ,用所获得的试验数据对其进行训练和测试 ,当BP神经网络经过 3× 10 5次学习后 ,最大训练误差 (MaxTrainingError)和训练均方差 (RMSTrainingError)分别为 0 .5 5 %和 0 .18% ,同时相应的最大测试误差 (MaxTestError)和测试均方差 (RMSTestTraining)分别达到了 0 .72 %和 0 .3 3 % ,对铝熔体中氢的预测达到了很高的精度 ,从而建立了熔炼条件 (温度、保温时间 )和氢含量的映射模型     

Selenium Substitution in Bithiophene Imide Polymer Semiconductors Enables High-Performance n-Type Organic Thermoelectric

Designing n-type polymers with high electrical conductivity remains a major challenge for organic thermoelectrics (OTEs). Herein, by devising a novel selenophene-based electron-deficient building block, the pronounced advantages of selenium substitution in simultaneously enabling advanced n-type polymers is demonstrated with high mobility (≈2 orders of magnitude higher versus their sulfur-based analogues due to both intensified intra- and inter-chain interactions) and much improved n-doping efficiency (enabled by the largely lowered LUMO level with a ≈0.2 eV margin) of the resulting polymers. Via side chain optimization and donor engineering, the selenium-substituted polymer, f-BSeI2TEG-FT, achieves a highest conductivity of 103.5 S cm⁻¹ and power factor of 70.1 µW m⁻¹ K⁻², which are among the highest values reported in literature for n-type polymers, and f-BSeI2TEG-FT greatly outperformed the sulfur-based analogue polymer by 40% conductivity increase. These results demonstrate that selenium substitution is a very effective strategy for improving n-type performance and provide important structure-property correlations for developing high-performing n-type OTE materials.     

An Efficient One-Arrow-Two-Hawks Strategy Achieves High Efficiency and Stable Batch Variance for Benzodifuran-based Polymer Solar Cells

With the development of organic solar cells (OSCs), the high-performance and stable batch variance are becoming a new challenge for designing polymer donors. To obtain high photovoltaic performance, adopting polymers with high molecular weight as donors is an ordinary strategy. However, the high molecular weight need to subtly control the reaction time and state, inevitably caused batch-to-batch variations. Herein, a strategy of steric effect is applied to benzodifuran (BDF)-based polymer by introducing different positions of Cl atom, producing two polymers PBDFCl-1 and PBDFCl-2. The more twisted side chains conformation not only achieve the control of moderate molecular weight for PBDFCl-2, but also easily form molecular stacking through adopting BDF unit and maintain sufficient polymeric crystallinity. Due to the optimized stacking mode and good blend miscibility, PBDFCl-2-based device exhibitsa more elegant power conversion efficiency (PCE) of 17.00% compared to PBDFCl-1-based device. This is the highest efficiency record for BDF-based binary OSCs. Meanwhile, the PCE device variation of the different molecular weights for PBDFCl-2 is little, indicating the reduction of the batch variation. Therefore, smartly using steric effect of Cl atom in strong crystalline BDF unit can form efficient molecular stacking regulations and realize the coordination of high-performance and stable batch variance.