Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash

Ceramics with mullite whiskers were prepared from coal fly ash and Al₂O₃ raw materials, with AlF₃ used as an additive. The phase structures and microstructures of the ceramics were identified via X-ray diffraction and scanning electron microscopy, respectively. The results show that pickling of coal fly ash is an effective method for enhancing the flexural strength of ceramics. Sintering temperature and AlF₃ addition were also key factors influencing the creation of ideal ceramics. The ceramic made from pickled coal fly ash, 6?wt% AlF₃, and sintered at 1200?°C, exhibited the highest flexural strength of 59.1?MPa, and had a bulk density of 1.32?g/cm³ and porosity of 26.8%. The results show that ceramic materials made under these conditions are ideal candidates for manufacturing ceramic proppants for the exploitation of unconventional oil and gas resources.     

结合RDF实现对XML文档的RBAC

文章提出了一种面向XML文档的基于XMLschema并结合RDF的访问控制模型,它实现了对XML文档的细粒度的安全访问控制,同时提供了对XML文档中associationsecurityobject的安全访问控制。     

Pd催化剂上乙酰丙酸与腈还原胺化制吡咯烷酮类化合物

采用柠檬酸络合法,通过调整CeO2含量(x=5％、10％、20％、30％)(以Al2O3的质量计,下同)制备出一系列xCeO2-Al2O3复合氧化物,以此为载体用沉积-沉淀法制备了Pd负载量(以Al2O3的质量计,下同)为5％的5％Pd/xCeO2-Al2O3催化剂.采用XRD、N2吸附-脱附、TEM、XPS对催化剂的物化性质进行了表征,探讨了催化剂对生物质基乙酰丙酸与腈类化合物"一锅法"还原胺化合成N-取代基-5-甲基-2-吡咯烷酮类化合物的催化性能.结果表明,在温和的反应条件下(90℃、1.5 MPa H2),催化剂5％Pd/10％CeO2-Al2O3上乙酰丙酸与苯甲腈反应5 h,N-苄基-5-甲基-2-吡咯烷酮收率高达87.5％.在该催化剂上,乙酰丙酸(酯)与其他多种腈类化合物反应同样获得了较高的吡咯烷酮类化合物收率(76.3％～87.4％).催化剂5％Pd/10％CeO2-Al2O3循环4次后,活性无明显下降.     

全相位与Geiger算法的岩石声发射源定位方法

Geiger定位算法在岩石定位分析中得到广泛应用,但是对初始值要求非常严格,若初始值选择不当,则很难进入收敛范围。为了提高定位精度,减少迭代次数,针对这些问题,提出全相位与Geiger算法的岩石声发射源定位方法。首先进行花岗岩（50 mm×100 mm×50 mm）断铅实验,接着充分利用全相位FFT相位不变性的优势分析断铅信号,通过相位差法求出时延同时反演声发射源求出Geiger迭代初始值,最后综合最小二乘法与Geiger算法,迭代求出最优解。实验仿真结果显示此算法的平均误差相比美国PCI-2型声发射仪器定位结果降低了约5 mm,有效解决了Geiger初始值选取的问题,能够迅速进入收敛范围,提高了收敛速度和定位精度。     

网络扫描技术的智能化研究

针对现有网络扫描技术中存在的扫描静态性和分析评估功能有限等不足,在对网络扫描基本原理综合分析的基础上,进行了网络扫描技术智能化策略的分析探讨,同时提出了一个符合智能化策略的网络扫描系统概念模型.     

基于用户聚类的播客节目推荐

许多播客推荐机制一般根据整体点击次数来向用户推荐节目,但是一些点击次数很高的节目未必就是某类用户所喜欢的,因而推荐的节目对用户的喜好针对性不是很强.为了提高推荐节目对用户喜好特点的针对性,提出基于用户聚类的节目推荐.对用户在播客平台上的采集数据进行聚类分析后,把用户归为某一类型,并把该类型的所有节目根据点击次数多少存放入相应的推荐表.在用户下次登录时,根据其所属用户类型从推荐表中选出其最可能观看的尚未浏览的节目.试验结果证明,该播客推荐系统能很好地根据用户的喜好特点来进行针对性节目推荐.     

Research on the location of acoustic emission source of rock breaking point by using phase difference method and Geiger algorithm

Geiger iterative algorithm is very strict to the initial value. If the initial value is not selected suitably, it is difficult to enter the convergence range, thus increasing the number of iterations. The acoustic emission source location based on phase difference time delay estimation method reduces the error of acoustic emission location, but it has some shortcomings in accuracy. Based on the above problems, this paper presents a new algorithm for Geiger optimization based on source localization. Firstly, the initial value of Geiger is obtained by using the phase difference method. Then, the optimal solution is obtained by the iterative solution of Geiger algorithm and the least square method. The simulation results show that this method can effectively solve the problem of selecting the initial value of Geiger, so that it can quickly enter the convergence range, improving the convergence speed and positioning accuracy, comparing the positioning results of the United States PCI-2 type acoustic emission instrument, the average error reduced by about 5 mm.     

Sintering mechanism of high-intensity and low-density ceramic proppants prepared by recycling of waste ceramic sands

Waste ceramic sands were effectively used to prepare the high-intensity and low-density ceramic proppants, realising the recycling of the waste ceramic sands. The technology involved the pelletising in an intensive mixer, in which the waste ceramic sands and other starting materials were added, and followed by heat-treatment under different sintering conditions. The sintering temperature, holding time and heating rate were optimised by investigating the crystalline phase, microstructure, density and breakage ratio of the obtained proppants. The results showed that the proppants sintered at 1260°C for 2?h with a heating rate of 5°C?min^–1 under air atmosphere exhibited high crush resistance and low density, with the breakage ratio of 8.5% under 52?MPa closure pressure and bulk density of 1.65?g?cm^–3. The proppants prepared by bauxite, waste ceramic sands and sintering aids are promising candidates as high-intensity and low-density fracturing proppants in future applications.     

Preparation and characterization of aluminum borate whiskers reinforced ceramics with MnO2 addition

Ceramics with aluminum borate whiskers (ABWs) were prepared from H₃BO₃ and Al₂O₃ reagent, with and without 6 wt% MnO₂ used as an addition. The microstructures, phase composition, and crystal structure of the ceramics were analyzed via scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction, respectively. The results show that MnO₂ is an effective addition for enhancing the flexural strength of ceramics. The MnO₂ could lead to the distortion of lattice, and improve the mechanical strength via a solid solution strengthening mechanism. Moreover, the content of H₃BO₃ and the sintering temperature were also key factors in the manufacture of optimal ceramics. The ceramic made from 6 wt% MnO₂ addition, 25 wt% H₃BO₃, and sintered at 1200°C, showed the highest flexural strength of 88.5 (±1.9) MPa, and had a bulk density of 1.64 g/cm³ and porosity of 44.2%.     

基于混沌粒子群优化算法的NOMA功率分配研究

非正交多址接入(NOMA)技术使多个用户共享一个时频资源块,显著地提高了频谱利用率,已成为5G多址技术的研究热点。针对NOMA系统能量效率最大化问题,对非正交多址接入技术中功率分配进行了研究,提出了基于混沌粒子群优化算法的NOMA功率分配方案。建立了能量效率最大化的NOMA优化模型,利用混沌粒子群优化算法对系统功率进行分配,使NOMA系统的能量效率得到优化。仿真结果表明,当发射功率为36 dBm时,系统能量效率最大,且与传统粒子群算法相比所需迭代次数更少,获得的能量效率更优。