Poly(1,3,4-oxadiazoles). Effect of structure on polymer properties

Poly(1,3,4-oxadiazole-2,5-diylvinylene) and poly(1,4-phenylene-1,3,4-oxadiazole-2,5-diylvinylene) were prepared by polymerizing different quantities of terephthalic acid (T), maleic acid (M), and hydrazine sulfate (HS) in the presence of fuming sulfuric acid. Homopolymers of M and T and various copolymers of M:T were prepared. The polymers were characterized by viscosity, IR, UV, and elemental analysis. Their solubility in different solvents was investigated. The relative thermal stability of the polymers was evaluated by TGA and DTA.     

Comparison of TiAIN,AICrN, and AICrN/TiAIN coatings for cutting-tool applications

Monolayer and bilayer coatings of TiAlN, AlCrN, and AlCrN/TiAlN were deposited onto tungsten carbide inserts using the plasma enhanced physical vapor deposition process. The microstructures of the coatings were characterized using scanning electron microscopy （SEM） and atomic force microscopy （AFM）. The SEM micrographs revealed that the AlrN and AlCrN/TiAlN coatings were uniform and highly dense and contained only a limited number of microvoids. The TiAIN coating was non-uniform and highly porous and contained more micro droplets. The hardness and scratch resistance of the specimens were measured using a nanoindentation tester and scratch tester, respectively. Different phases formed in the coatings were analyzed by X-ray diffraction （XRD）. The AlCrN/TiAlN coating exhibited a higher hardness （32.75 GPa）, a higher Young＇s modulus （561.97 GPa）, and superior scratch resistance （LcN = 46 N） compared to conventional coatings such as TiAlN, A1CrN, and TiN.     

An Efficient Enhanced Full Homomorphic Encryption for Securing Video in Cloud Environment

Wireless Personal Communications - Users in practical cellular geographical areas are found to be non-uniformly distributed. Small cell (SC) deployments in heterogeneous user distribution in a...     

Crest Dwindling and Interposing for PAPR Reduction in OFDM Signal with Sustainable Spectral Efficiency

Wireless Personal Communications - OFDM (Orthogonal Frequency Division Multiplexing) is a common transmission method in various wireless communications. It makes use of numerous carriers that are...     

Multi-Objective Modified Particle Swarm Optimization for Test Suite Reduction (MOMPSO)

Software testing plays a pivotal role in entire software development lifecycle. It provides researchers with extensive opportunities to develop novel methods for the optimized and cost-effective test suite Although implementation of such a cost-effective test suite with regression testing is being under exploration still it contains lot of challenges and flaws while incorporating with any of the new regression testing algorithm due to irrelevant test cases in the test suite which are not required. These kinds of irrelevant test cases might create certain challenges such as code-coverage in the test suite, fault-tolerance, defects due to uncovered-statements and overall-performance at the time of execution. With this objective, the proposed a new Modified Particle Swarm optimization used for multi-objective test suite optimization. The experiment results involving six subject programs show that MOMPSO method can outer perform with respect to both reduction rate (90.78% to 100%) and failure detection rate (44.56% to 55.01%). Results proved MOMPSO outperformed the other stated algorithms.     

Characterization and Low Temperature Study of Iron Telluride Thin Films Upon Ageing and Oxygen Ion Irradiation

The occurrence of superconductivity in iron telluride thin films has been observed upon ageing. The superconducting transition is found to be very robust under an application of magnetic fields up to 10 T. Infrared and Raman spectroscopic characterization of the aged films reveal the formation of Fe_1+δTeO _x upon ageing. As an alternative method of introducing oxygen in FeTe thin film, oxygen ion irradiation has also been carried out It is found that the irradiated film becomes increasingly disordered and ultimately transforms to an amorphous phase upon increasing the irradiation dose. Investigation of electrical resistivity and optical reflectivity of the irradiated FeTe films indicates an interesting possibility of an ion irradiationinduced phase change memory material in analogy to the phase change characteristics of laserirradiated FeTe films.     

Hydrogen storage in coiled carbon nanotubes

We report a density functional calculation of the adsorption of molecular hydrogen on the external surface of coiled carbon nanotube (CCNT). Binding energies of single molecule have been studied as a function of three different orientations and at three different sites like hexagon, pentagon and heptagon. The binding energy values are larger than linear (5,5) armchair nanotube, which has approximately same diameter as that of coiled carbon nanotube. The curvature and topology of CCNT are responsible for this considerable enhancement. The system with full coverage is also studied. When the nanotube surface is fully covered with one molecule per graphitic hexagon, pentagon and heptagon gives the 6.8 wt% storage capacity. The binding energy per molecule decreases due to repulsive interactions between neighbor molecules. It gives good storage medium for hydrogen. Almost it meets the DOE target.     

A Light Weight Secure Communication Scheme for Wireless Sensor Networks

Wireless Personal Communications - The majority of security systems for wireless sensor networks are based on symmetric encryption. The main open issue for these approaches concerns the...     

Inhibitory effects of black tea theaflavin derivatives on 12-O-tetradecanoylphorbol-13-acetate-induced inflammation and arachidonic acid metabolism in mouse ears

Tea has been shown to possess several health beneficial properties primarily due to its polyphenolic content. The major polyphenolic compounds in black tea leaves are theaflavins (TFs) formed by oxidative coupling of catechins in tea leaves during its processing. In this paper, we report the characterization of 12-O-tetradecanoylphorbol-13-acetate (TPA)-induced mouse ear inflammatory model and the inhibitory effects of major black tea TFs derivatives on this inflammation. In addition, the effect on inflammatory biomarkers, such as proinflammatory cytokines and arachidonic acid metabolites, are reported as well. A single topical application of TPA to ears of CD-1 mice induced a time- and dose-dependent increase in edema as well as formation of proinflammatory cytokine proteins interleukin-1beta (IL-1beta) and interleukin-6 (IL-6) in mouse ears. A single topical application of equimolar of black tea constituents (TF, theaflavin-3-gallate, theaflavin-3'-gallate, and theaflavin-3,3'-digallate) strongly inhibited TPA-induced edema of mouse ears. Application of TFs mixture to mouse ears 20 min prior to each TPA application once a day for 4 days inhibited TPA-induced persistent inflammation, as well as TPA-induced increase in IL-1beta and IL-6 protein levels. TFs also inhibited arachidonic acid (AA) metabolism via both cyclooxygenase (COX) and lipoxygenase pathways. This observation was substantiated by decreased amounts of AA metabolites prostaglandin E2 (PGE2) and leukotriene B4 (LTB4) levels. Combined application of TF and sulindac, a nonsteroidal anti-inflammatory drug resulted a significant synergetic anti-inflammatory effect. Oral administration of TFs or the hot water extract of black tea leaves also significantly inhibited TPA-induced edema in mouse ears. In conclusion, proinflammatory cytokines, IL-1beta and IL-6, as well as the intermediated metabolites of AA, PGE2, and LTB4 are good biomarkers for inflammation. Black tea constituents, TF and its derivatives, had strongly anti-inflammatory activity in vivo which may be due to their ability to inhibit AA metabolism via lipoxygenase and COX pathways.     

Thermal analysis of poly(1,3,4-oxadiazole-2,5 diyl-1,2-ethenediyl) and poly(1,4-phenylene-1,3,4-oxadiazole-2,5 diyl-1,2 ethendiyl)

Poly(1,3,4-oxadiazole-2,5-diyl-1,2-ethendiyl) and poly(1,4-phenylene-1,3,4-oxadiazole-2,5 diyl-1,2-ethenediyl) have been prepared by condensation polymerization using fuming sulfuric acid and different quantities of terephthalic acid (T), fumaric acid (F), and hydrazine sulfate (HS). Homopolymers of F and T and various copolymers of F:T have been prepared. The polymer structure was investigated by IR and visible-range spectra and elemental analysis. The existence of poly(1,3,4-oxadiazole-diylphenylene) and poly(hydrazoterephthaloyl) structures was revealed by these studies. These polymers were thermally stable, and most of them did not show a weight loss below 350°C. The relative thermal stabilities of the various polymers have been evaluated by “integral procedural decomposition temperature” and activation energy measurements.