Synthesis and evaluation of hexafluorodimethylcarbinol functionalized polymers as microsensor coatings

Polystyrenes, polyacrylates, and poly(3,4-isoprenes) incorporating the hexafluorodimethylcarbinol functionality have been synthesized, characterized, and tested as microsensor coatings on a surface acoustic wave (SAW) device for dimethyl methylphosphonate (DMMP) vapor absorption sensitivity. The syntheses involved monomer functionalization and polymerization or hexafluoroacetone reaction with preformed polymer. All fluoroalcohol functionalized polymer coatings displayed sub parts per million level sensitivity with the slope of the absorption isotherm steepest at low DMMP concentrations. The order of sensitivity for the isomeric polystyrene fluoroalcohols (meta > para ? ortho) paralleled that of the relative free hydroxyl to hydrogen-bonded hydroxyl content. Strong hydrogen bonding between the fluoroalcohol polymers and DMMP vapor was observed by IR spectroscopy. Acylation of the fluoroalcohol group markedly reduced the DMMP sensitivity.     

Presence of pressure ulcer prevention methods used among patients considered at risk versus those considered not at risk

PURPOSE: This study examined pressure ulcer-prevention strategies available for patients considered at risk versus those considered not at risk. DESIGN: The study used a prospective, longitudinal design. SETTING AND SUBJECTS: Six hundred ninety-four patients from units of five acute care hospitals, a rehabilitation facility, and two nurses' home care caseloads participated in the investigation. INSTRUMENTS: Data-collection instruments included the Braden Scale for risk assessment, demographic information, and the Pressure Ulcer-Prevention Strategies tool, which assessed for the presence of 16 pressure ulcer-prevention strategies. METHODS: All patients admitted to a participating unit during a 2-month period were followed up until discharge. Depending on the site, patients were assessed for the presence of pressure ulcer-prevention strategies one to three times per week. RESULTS: Patients in the at-risk group versus those in the not-at-risk group were more likely (p < 0.01) to have the head of the bed in a low position, a pressure-reducing bed surface, pressure ulcer prevention charted, a positioning wedge, incontinence cleanser and ointment, heel protection, a prevention care plan, a trapeze, and a posted turning schedule. The at-risk group had significantly (p < 0.01) more prevention strategies present than did the not-at-risk group. However, the percentage of patients placed on a pressure ulcer-prevention program was low for both groups. CONCLUSIONS: Pressure ulcer prevention was evident for the at-risk group, but at a low rate. Institutions must continue to explore this critical area affecting patient outcomes.     

Properties of 3He in thin 4He films

Substantial progress has been made in our understanding of the properties of ³He atoms in thin films of ⁴He. For such films the ³He occupies discrete quantum states in the film and the system is both rich and complex. Here we discuss progress in this field from several points of view; we briefly discuss early heat capacity and third sound results and concentrate on more recent NMR measurements of the magnetization and relaxation times T ₁ and T ₂. Further experimental work and theory for systems of finite ³He coverage is needed to fully understand this fascinating system.Presenter at the Elba Summer School; authors are listed alphabetically.     

First- and zero-sound velocity and fermi liquid parameter F 2 s in liquid3He determined by a path length modulation technique

We have measured the velocity of first- and zero-sound in liquid³He at 12.6 MHz over the pressure range of 0.6 to 14.5 bar using a path length modulation technique that we have recently developed. From these measurements, the pressure dependent value of the Fermi liquid parameter F ₂ ^s was calculated and found to be larger at low pressure than previously reported. These new values of F ₂ ^s indicate that transverse zero-sound is a propagating mode at all pressures. The new values are important for the interpretation of the frequencies of order parameter collective modes in the superfluid phases. The new acoustic technique permits measurements in regimes of very high attenuation with a sensitivity in phase velocity of about 10 ppm achieved by a feedback arrangement. The sound velocity is thus measured continuously throughout the highly attenuating crossover ( 1) regime, even at the lowest pressures.     

Er-Doped LiMn<Subscript>2</Subscript>O<Subscript>4</Subscript>

LiMn_2-x Er_xO₄ (x ≤ 0.02) materials were synthesized by a rheological phase reaction method. The thermal behavior of the materials was examined by thermogravimetric and differential scanning calorimetry. X-ray diffraction showed that the samples (x ≤ 0.02 ) exhibited the same phase as the pure spinel. The lattice parameter of the Er-doped spinel was smaller than that of the undoped one and decreased with increasing doping level. Cyclic voltammograms showed two reversible processes corresponding to the typical response of spinel LiMn₂O₄ and revealed an insertion-extraction reaction occurring at two stages in the 4-V region. The electrochemical performances of the samples were studied and displayed a better reversibility and cyclability.__________From Neorganicheskie Materialy, Vol. 41, No. 6, 2005, pp. 740–743.Original English Text Copyright © 2005 by Haowen Liu, Li Song, Kelli Zhang.This article was submitted by the authors in English.     

Hitting the wall: errors in developing and code inspecting a `simple' spreadsheet model

Field audits and experiments have found substantial error rates when students and professionals have built spreadsheet models. In this study, 102 undergraduate MIS majors and 50 MBA students developed a model from a word problem that was relatively simple and free of domain knowledge. Even so, 35% of their 152 models were incorrect. There was no significant difference in errors per model between undergraduates and MBAs. Even among the 17 MBAs with 250 h or more of experience, 24% of the models contained errors. The cell error rate (CER)—the percentage of cells with errors—was 2.0%. When 23 undergraduates attempted to audit their models through code inspection, only three with incorrect spreadsheets (15%) produced clean spreadsheets when they finished the audit.     

A spectral‐element method for modelling cavitation in transient fluid–structure interaction

In an underwater‐shock environment, cavitation (boiling) occurs as a result of reflection of the shock wave from the free surface and/or wetted structure causing the pressure in the water to fall below its vapour pressure. If the explosion is sufficiently distant from the structure, the motion of the fluid surrounding the structure may be assumed small, which allows linearization of the governing fluid equations. In 1984, Felippa and DeRuntz developed the cavitating acoustic finite‐element (CAFE) method for modelling this phenomenon. While their approach is robust, it is too expensive for realistic 3D simulations. In the work reported here, the efficiency and flexibility of the CAFE approach has been substantially improved by: (i) separating the total field into equilibrium, incident, and scattered components, (ii) replacing the bilinear CAFE basis functions with high‐order Legendre‐polynomial basis functions, which produces a cavitating acoustic spectral element (CASE) formulation, (iii) employing a simple, non‐conformal coupling method for the structure and fluid finite‐element models, and (iv) introducing structure–fluid time‐step subcycling. Field separation provides flexibility, as it admits non‐acoustic incident fields that propagate without numerical dispersion. The use of CASE affords a significant reduction in the number of fluid degrees of freedom required to reach a given level of accuracy. The combined use of subcycling and non‐conformal coupling affords order‐of‐magnitude savings in computational effort. These benefits are illustrated with 1D and 3D canonical underwatershock problems. Copyright © 2004 John Wiley & Sons, Ltd.     

走向可持续设计与绿色设计的医疗建筑

<正>议题的背景2008年某期《华尔街日报》曾报道,到公元2050年地球总人口数量将从现在的69.1亿增加到91.9亿多。因此,人类对于稀有资源和不可再生资源的需求将会加剧,同时也将急需新的开发资源的     

Trends in use and prospects for the future harvest of world fisheries resources

Estimates of the potential yield from the marine environment have varied between 20–1000 million metric tons because they were based on poor and incomplete data and differing approaches to trophic level evaluation. The data is improving slightly and the estimates are beginning to agree within half an order of magnitude. We believe that the yield of marine fisheries could ultimately be expanded to ca. 400 million metric tons, by utilizing presently known but underutilized resources, by opening new fisheries in areas like the Indian Ocean and Antarctic and by improving systems of regulating the catch and fishing effort. In order to meet the maximum potential of the marine environment we will have to harvest at a lower trophic level in the food chain because most fish in higher trophic levels are being harvested at their maximum sustainable yield. This increasing harvest of smaller fish, plus the increasing demand for fishmeal for animal feed will cause an increasing proportion of the fish harvested to be used for reduction to fishmeal and oil. One of 11 papers presented in the symposium “World Supply of Edible Oils and Proteins,” Atlantic City, October 1971.