First and second law investigations of a new solar‐assisted thermodynamic cycle for triple effect refrigeration

This investigation is persuaded for the first and second law analyses of a new solar‐driven triple‐effect refrigeration cycle using Duratherm 600 oil (Duratherm Extended Life Fluid, NY, USA) as the heat transfer fluid is performed. The proposed cycle is an integration of ejector, absorption, and cascaded refrigeration cycles that could produce refrigeration output of different magnitude at different temperature simultaneously. Both exergy destruction and losses in each component and hence in the overall system are determined to identify the causes and locations of the thermodynamic imperfection. The effects of some influenced parameters such as hot oil outlet temperature, refrigerant turbine inlet pressure, and the evaporator temperature of ejector and cascaded refrigeration cycle have been observed on the first and second law performances. It is found that maximum irreversibility occurs in central receiver as 52.5% and the second largest irreversibility of 25% occurs in heliostat field. The second law efficiency of the solar driven triple effect refrigeration cycle is 2%, which is much lower than its first law efficiency of 11.5%. Analysis clearly shows that performance evaluation based on the first law analysis is inadequate and hence, more meaningful evaluation must be included in the second law analysis. Copyright © 2013 John Wiley & Sons, Ltd.     

Performance analysis of an industrial waste heat‐based trigeneration system

The thermodynamic performance of an industrial waste heat recovery‐based trigeneration system is studied through energy and exergy efficiency parameters. The effects of exhaust gas inlet temperature, process heat pressure, and ambient temperature on both energy and exergy efficiencies, and electrical to thermal energy ratio of the system are investigated. The energy efficiency increases while electrical to thermal energy ratio and exergy efficiency decrease with increasing exhaust gas inlet temperature. On the other hand, with the increase in process heat pressure, energy efficiency decreases but exergy efficiency and electrical to thermal energy ratio increase. The effect of ambient temperature is also observed due to the fact that with an increase in ambient temperature, energy and exergy efficiencies, and electrical to thermal energy ratio decrease slightly. These results clearly show that performance evaluation of trigeneration system based on energy analysis is not adequate and hence more meaningful evaluation must include exergy analysis. The present analysis contributes to further information on the role of exhaust gas inlet temperature, process heat pressure, ambient temperature influence on the performance of waste heat recovery‐based trigeneration from a thermodynamic point of view. Copyright © 2009 John Wiley & Sons, Ltd.     

Thermodynamic performance assessment of an indirect intercooled reheat regenerative gas turbine cycle with inlet air cooling and evaporative aftercooling of the compressor discharge

This study provides a computational analysis to investigate the effects of cycle pressure ratio, turbine inlet temperature (TIT), and ambient relative humidity (φ) on the thermodynamic performance of an indirect intercooled reheat regenerative gas turbine cycle with indirect evaporative cooling of the inlet air and evaporative aftercooling of the compressor discharge. Combined first and second‐law analysis indicates that the exergy destruction in various components of gas turbine cycles is significantly affected by compressor pressure ratio and turbine inlet temperature, and is not at all affected by ambient relative humidity. It also indicates that the maximum exergy is destroyed in the combustion chamber; which represents over 60% of the total exergy destruction in the overall system. The net work output, first‐law efficiency, and the second‐law efficiency of the cycle significantly varies with the change in the pressure ratio, turbine inlet temperature and ambient relative humidity. Results clearly shows that performance evaluation based on first‐law analysis alone is not adequate, and hence more meaningful evaluation must include second‐law analysis. Decision makers should find the methodology contained in this paper useful in the comparison and selection of gas turbine systems. Copyright © 2006 John Wiley & Sons, Ltd.     

Exergy analysis of double effect vapor absorption refrigeration system

Energy and exergy analyses previously performed by the authors for a single effect absorption refrigeration system have been extended to double effect vapor absorption refrigeration system with the expectation of reducing energy supply as well as an interest in the diversification of the motive power employed by HVAC technologies. The total exergy destruction in the system as a percentage of the exergy input from a generator heating water over a range of operating temperatures is examined for a system operating on LiBr–H₂O solution. The exergy destruction in each component, the coefficient of performance (COP) and the exergetic COP of the system are determined. It is shown that exergy destructions occur significantly in generators, absorbers, evaporator2 and heat exchangers while the exergy destructions in condenser1, evaporator1, throttling valves, and expansion valves are relatively smaller within the range of 1–5%. The results further indicate that with an increase in the generator1 temperature the COP and ECOP increase, but there is a significant reduction in total exergy destruction of the system for the same. On the other hand, the COP and ECOP decrease with an increase in the absorber1 temperature while the total exergy destruction of the system increases significantly with a small increase in the absorber1 temperature. The results show that the exergy method can be used as an effective criterion in designing an irreversible double effect absorption refrigeration system and may be a good tool for the determination of the optimum working conditions of such systems. Copyright © 2007 John Wiley & Sons, Ltd.     

Role of Pb substitution and a study of synthesizing procedure for Bi-based superconductors

Bulk superconductors of the (Bi_1–x Pb _x )₂Sr₂Ca₂Cu₃O _y system have been synthesized by changing the Bi/Pb ratio. The effect of Pb substitution onT _c has been studied by standard d.c. resistivity measurements. An appropriate thermal procedure and time for the preparation of the 110 K phase has also been studied at length. The experiments indicate that the best results are obtained forx=0.2 and that a slow cooling process is necessary for a better control of the thermal process. Indexed X-ray diffraction patterns indicate the lattice parameters of low- and high-T _c phases asa _L=0.54004 nm,b _L=0.5445 nm,c _L=3.084 nm anda _H=0.5483 nm,b _H=0.5339 nm,c _H=3.772 nm, respectively. The observed superconducting behaviour is stable on thermal cycling between 77 and 300 K.     

Role of barium addition on the properties of bismuth-based superconductors

The effect of the addition of barium on the zero resistance temperature,T _c, of Bi_1.6Pb_0.4Sr_1.6Ca₂Ba _x Cu₄O _y ,x= 0.4, 0.5, 0.6, 0.8 and 1.6 was studied. The added barium had the effect of raisingT _c to a higher temperature region, although too much barium gave rise to semiconducting resistance temperature behaviour. X-ray diffraction analysis showed that as the barium concentration,x, increased from 0.4 to 0.8, a decrease in the lowT _c phase and peaks due to CuO and BaBiO₃ appeared, whereas an increase in the peaks due to the highT _c phase and BaCuO₂ were seen. Critical current densities were also measured in zero field at 77 K.     

Optimized structure and electrochemical properties of sulfonated carbon nanotubes/Co–Ni bimetallic layered hydroxide composites for high-performance supercapacitors

Technical development in electronic devices is frequently stifled by their insufficient capacity and cyclic stability of energy-storage devices. The nano-structured materials have sensational importance for providing novel and optimized combination to overcome exiting boundaries and provide efficient energy storage systems. Metal hydroxide materials with high capacity for pseudo-capacitance properties have grabbed special attention. Lately, the blend of nickel and cobalt hydroxides has been considered as a favorable class of metallic hydroxide materials owing to their comparatively high capacitance and exceptional redox reversibility. The sulfonated carbon nanotube fluid (SCNTF) was prepared by the ion exchange method to be utilized as the exceptional templates due to astonishing specific surface area, ensuring the maximum utilization of the active material. The CoNi-layered double hydroxides (LDHs)/SCNTF core-shell nanocomposite was prepared by the simple solvothermal method. Structural analysis showed that the composite material had the high conductance of carbon materials, the pseudo-capacitance characteristics of metal hydroxides, and porous structure, which facilitates the ion shuttle when the electrolyte reacts with the active material. Electrochemical analysis results showed that CoNi-LDHs/SCNTF had excellent rate performance, reversible charge-discharge properties and cycle stability. It exhibited an extreme specific capacity of 1190.5 F g^?1 at a current density of 1 A g^?1; whereas specific capacity remained 953.7 F g^?1 at the current density was 10 A g^?1. In addition, the capacity retention rate after 5000 charge-discharge cycles at a current density of 20 A g^?1 was 81.0%. The results indicated that the CoNi-LDHs/SCNTF core-shell nanocomposite material is cost efficient and an effective substitute in energy storage applications.     

Fabrication of the τ5c Intermetallic Compound Monoliths by a Novel Powder Metallurgy and Hot-Dipping Approach

Metallurgical and Materials Transactions B - The precipitation of discrete iron-based intermetallic compounds (IMC) is an inevitable phenomenon in a steel strip alloy coating pot due to the...     

Processing of metallic fiber hybrid spun yarns for better electrical conductivity

This research was aimed at processing of metallic fiber hybrid spun yarns consisting of polyester/stainless steel and viscose/stainless steel staple fibers to achieve better electrical conductivity. Conventional ring spinning machine and ring twister machine were used to produce the single and plied yarns respectively. The linear electrical resistance of yarns was analyzed with reference to the three levels of twist multiplier (TM) for same yarn count, three levels of yarn fineness (Ne) at the same TM level, and number of plies for the same final yarn count. These results showed that by increasing twist, the electrical conductivity of yarn was increased. However, yarn fineness was in inverse relation with the electrical conductivity of yarns. The effect of yarn plying and twisting to produce the Ne 10s yarn was also found critical in governing the electrical properties. The electrical conductivity of viscose and stainless steel hybrid yarn was found more sensitive to increase with an increase in relative humidity contrary to that of polyester and stainless steel hybrid yarns. The findings of the study are significant to produce the hybrid spun conductive yarns for their potential applications in a variety of tailor-made functional, protective and smart textiles.     

Application of local error method to SSSF simulation of vector propagation in dispersion compensated optical links

A local error method based on an analytical scheme previously developed for the scalar optical fiber channel is applied to the second-order symmetrized split-step Fourier simulation of polarization multiplexed signal propagation through dispersion compensated optical fiber links. It is found that the global simulation accuracy for the vector propagation can be satisfied using the local error bound from a scalar propagation model for the same global error over a large range of simulation accuracy, chromatic dispersion, and differential group delay. Furthermore, carefully designed numerical simulations are used to show that similar local simulation error are obtained for vector simulations and that the similar local error leads to higher computational efficiency compared to other prevalent step-size selection schemes. The scaling of the global simulation error with respect to the number of optical fiber spans is demonstrated, and global error control for multi-span simulations is proposed. Combining the local error and global error control, the developed simulation scheme can significantly speed up the time-consuming simulations in coherent optical fiber communication system analysis and design.