Optimizing simultaneously over the numerator and denominator polynomials in the Youla-Kuc/spl caron/era parametrization

Traditionally, when approaching controller design with the Youla-Kuc/spl caron/era parametrization of all stabilizing controllers, the denominator of the rational parameter is fixed to a given stable polynomial, and optimization is carried out over the numerator polynomial. In this note, we revisit this design technique, allowing to optimize simultaneously over the numerator and denominator polynomials. Stability of the denominator polynomial, as well as fixed-order controller design with H/sub /spl infin// performance are ensured via the notion of a central polynomial and linear matrix inequality (LMI) conditions for polynomial positivity.     

Improved Prediction of Ozone Levels in Urban and Rural Atmospheres

Based on data obtained in terms of the first International cooperative program on the effects of acidic precipitations on materials (ICP Materials) of the United Nations European Commission on Economics (UN ECE), the relations between the ozone O₃ and nitrogen dioxide NO₂ concentrations in combination with the sunshine effect (taken into account either as the solar radiation (Rad) or the sunshine duration (Sun)) are considered. Analysis based on monthly and annual averages led to a new equation recommended for predicting ozone levels over rural, urban, and industrial areas of Europe as a function of NO₂ concentration and Sun parameter. Using Rad instead of Sun provides similar results, but, for practical usage, the equation involving a more easily available parameter Sun was recommended. The new equation corrects and improves the earlier proposed one, in which the concentration of ozone was given as a function of NO₂ concentration solely, and is included in the UN ECE Manual on mapping critical loads / levels and geographical areas where they are exceeded.     

Interaction of Cucurbit[7]uril with Oxime K027, Atropine,and Paraoxon: Risky or Advantageous Delivery System?

Antidotes against organophosphates often possess physicochemical properties that mitigate their passage across the blood–brain barrier. Cucurbit[7]urils may be successfully used as a drug delivery system for bisquaternary oximes and improve central nervous system targeting. The main aim of these studies was to elucidate the relationship between cucurbit[7]uril, oxime K027, atropine, and paraoxon to define potential risks or advantages of this delivery system in a complex in vivo system. For this reason, in silico (molecular docking combined with umbrella sampling simulation) and in vivo (UHPLC—pharmacokinetics, toxicokinetics; acetylcholinesterase reactivation and functional observatory battery) methods were used. Based on our results, cucurbit[7]urils affect multiple factors in organophosphates poisoning and its therapy by (i) scavenging paraoxon and preventing free fraction of this toxin from entering the brain, (ii) enhancing the availability of atropine in the central nervous system and by (iii) increasing oxime passage into the brain. In conclusion, using cucurbit[7]urils with oximes might positively impact the overall treatment effectiveness and the benefits can outweigh the potential risks.     

The Classification System of ISO 9223 Standard and the Dose–Response Functions Assessing the Corrosivity of Outdoor Atmospheres

The ISO 9223 Standard Corrosion of Metals and Alloys–Corrosivity of Atmosphere–Classification which is now in force was based on the data obtained mainly in the temperate climate of Europe and North America. At present, it is being revised by using data from new programs of atmospheric tests carried out in cold, temperate, subtropical, and tropical climates. The paper tackles problems of assessing the atmospheric corrosivity from the environmental parameters. A model and dose–response functions characterising the corrosivity of the outdoor atmospheres are described. Suggestible ways of possibly improving the standard with the use of the functions derived are considered.     

Computer-controlled double-beam scanning microspectrophotometry for rapid microscopic image reconstructions.

A method for automated collection of various specific data from an entire microscopical preparation and their quantitative evaluation is described. Its application to the study of neuronal connections is discussed in some detail. Brain sections are scanned using a computer-controlled microscope for reflectance, fluorescences or absorbance signals. Two illuminating beams are used, one of them being amplitude modulated. By means of a synchronous detection the two signals are recorded simultaneously: for example, in an autoradiograph, the reflectance (measuring the density of the silver grains in emulsion) and the absorbance (allowing to localize the underlying counterstained cells). The data are stored in a computer. Various off-line processing schemes allow the reconstruction of the data with respect to the corresponding spatial coordinates. Thus pseudo-three-dimensional, analogue or digital, graphic displays may be obtained in which the patterns of neuronal connections can be recognized and interpreted. A method for the detection of weakly labelled nerve fibres based on digital filtering is presented. The whole processing for a frontal section of the mouse brain (7 X 10 mm area) takes less than 1 h. In addition to the evaluation of microscopically labelled material (grains of autoradiographs, horseradish peroxidase, nucleic acids) the technique described has been successfully used for the study of naturally fluorescent intracellular components in living tissue cultures.     

Partial model matching via static feedback (the multivariable case)

The problem of partial model matching is studied for the case of multi-input/multi-output (MIMO) linear time-invariant systems. Using a regular static state feedback law, the necessary and sufficient conditions for the problem to have a solution are established, the general analytic expressions of the controller matrices are derived. For the case of single-input/single-output systems sufficient conditions are derived for the solution of the partial model matching problem with simultaneous stabilizability. For the same type of systems the necessary and sufficient conditions for the solution of the partial model matching problem with simultaneous regulation of the free response of the closed loop system are established. Finally, the problem of partial model matching, via regular static measurement output feedback, is solved for the case of MIMO systems     

Calculation of temperature coefficients of reactivity for EBR-II kinetic analyses

Component and regional temperature coefficients of reactivity for four loading configurations of the Experimental Breeder Reactor-II (EBR-II) are compared. The coefficients are calculated by summations of microcoefficients obtained by fine axial delineations of every subassembly. A special-sum method for obtaining effective coefficients for use in kinetics code channels representing subassembly groupings is described. Evaluations of rod-bank suspension coefficients and of grid-plate radial-expansion coefficients are also presented.     

Sulfonation of solid polystyrene using gaseous sulfur trioxide

Kinetics of the heterogeneous sulfonation of polystyrene (PS) beads using gaseous SO₃ was investigated. Scanning electron microscopy (SEM) and electron diffraction scattering spectroscopy (EDS) was employed to study the kinetics of diffusion of SO₃ into the PS particles. The diffusion of SO₃ through the barrier of sulfonated polystyrene (SPS) on the beads surface was the primary parameter determining the rate and the yield of the sulfonation reaction. The measurement of the time dependence of the thickness of sulfonated layer formed on the solid PS surface provided for the hypothesis that the sulfonation in heterogeneous phase was diffusion controlled. Diffusion coefficients of SO₃ in PS at ?5°C, 22°C, and at 50°C and activation energy of SO₃ diffusion to the solid PS were determined from these experimental data assuming in the first approximation a simple diffusion unaffected by the ongoing sulfonation reaction. The experimental data were fitted using Johanson‐Mehl‐Avrami‐Jerofyeev‐Kolgomorov's equation to obtain an overall rate constant of heterogeneous sulfonation on solid PS surface. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers     

Wait-free deflection routing of long messages

In order to obtain the lowest possible latency, routing algorithms should try to avoid a message waiting for resources (network links) blocked by other messages or multiplexing of more messages over one physical channel. This requirement becomes especially important in the case of long messages. The only type of protocols able to guarantee waiting free routing under heavy load are algorithms based on deflection (also called nonminimal adaptive or hot potato) routing. This paper deals with problems connected with the use of deflection algorithms. In contrast to the case of nonadaptive or partially (e.g., minimal) adaptive routing, it is very infrequent that an unrestricted deflection routing becomes deadlocked and, similarly, livelock is not a serious problem. On the other hand, there is another phenomenon, called a deflection jam, that limits throughput of deflection algorithms used to route long messages. It has been observed for many deflection heuristics, interconnection network topologies, and both virtual cut-through and wormhole routing. A deflection jam is a sudden and persistent saturation of a network which sometimes occur, after a very long period of undisturbed communication. This paper describes events that trigger this saturation which suggest ways to design improved and stable deflection routing algorithms