Tuning the alignment of liquid crystals by means of nano‐structured surfaces (Invited Paper)

Abstract— The solid‐surface/liquid‐crystal interactions, defining the field‐free alignment of the liquid crystal in conventional liquid‐crystal displays, are playing a vital role in their optical appearance and performance. Nano‐scale changes in the solid‐surface structure induced by light have been recently shown to affect the anchoring strength and the easy‐axis direction. Fine tuning of the anchoring strength is also demonstrated by nano‐structuring of the Langmuir‐Blodgett monolayer employed as liquid‐crystal alignment layers promoting homeotropic orientation. On the basis of nano‐engineering of the surface alignment properties, two novel alignment concepts have been introduced: electrically commanded surfaces (ECS) and high‐performance alignment layers (HiPAL). Nano‐structured polymers related to these concepts have been designed, synthesized, and used as materials for alignment layers in LCDs. ECS materials belong to the category of active alignment materials designed to mediate switching of the liquid crystal, whereas the HiPAL materials make possible the control of the molecular tilt angle in a broad range, from 0° to 90°, and they seem to enable the control of the anchoring strength as well. The nano‐structured alignment materials are strong candidates for implementation in a new generation of advanced liquid‐crystal displays and devices.     

Tuning catalytic performances of cobalt catalysts for clean hydrogen generation via variation of the type of carbon support and catalyst post-treatment temperature

Multi-walled carbon nanotubes, three types of activated carbons, single wall carbon nanotube and reduced graphene oxides were used to synthesize nano-sized Co catalysts for H₂ preparation via NH₃ decomposition. Catalyst samples were characterized by number of techniques such as N₂ physisorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopes (XPS), Transmission electron microscopy (TEM), CO chemisorption, temperature-programmed reduction (H₂-TPR) and temperature-programmed desorption (N₂-TPD). The catalytic activities of the studied catalysts for H₂ production via NH₃ decomposition were measured in a fixed-bed micro-reactor. Co catalyst supported on multi-wall carbon nanotubes has shown the highest catalytic activity. The Co particles size was significantly affected by the variation of the post-treatment temperature. The Co particles size in the range of 4.7–64.8 nm can be effectively controlled by varying post-treatment temperature between 230 and 700 °C. The maximum TOF of NH₃ decomposition was registered on cobalt catalyst post-treated at 600 °C.     

Validation of MERIS LAI and FAPAR products for winter wheat-sown test fields in North-East Bulgaria

Progress in deriving land surface biophysical parameters in a spatially explicit manner using remotely sensed data has greatly enhanced our ability to model ecosystem processes and monitor crop development. A multitude of satellite sensors and algorithms have been used to generate ready-to-use maps of various biophysical parameters. Validation of these products for different vegetation types is needed to assess their reliability and consistency. While most of the current satellite biophysical products have spatial resolution of one kilometre, a recent effort utilizing data from the Medium Resolution Imaging Spectrometer (MERIS) provided leaf area index (LAI), Fraction of Absorbed Photosynthetically Active Radiation (FAPAR), and other canopy parameters in a resolution as fine as 300 m over the European continent. This resolution would be more appropriate for application at the regional scale, particularly for crop monitoring. This higher-resolution MERIS product has been evaluated in a limited number of studies to date. This article aims to validate LAI and FAPAR from the MERIS 10-day composite BioPar BP-10 product over winter wheat fields in northeast Bulgaria. The ground measurements of LAI and FAPAR were up-scaled and 30 m resolution reference raster layers were created using empirical relationships with Landsat TM (RMSE = 0.06 and RMSE = 0.22 for FAPAR and LAI, respectively). MERIS FAPAR and LAI were found to have significant correlation with FAPAR and LAI from the reference raster layers (R² = 0.84 and R² = 0.78, respectively). When MERIS Green LAI was calculated (incorporating the fraction of vegetation and brown vegetation cover from the BioPar BP-10 product), better correspondence with LAI values from the reference raster layer was achieved, with RMSE and bias reduced by 30–35%. The results from this study confirm the findings of previous validations showing that MERIS Green LAI tends to overestimate LAI values lower than 1. As a conclusion of the study, the BioPar BP-10 product was found to provide reliable estimates of FAPAR and acceptably accurate estimates of LAI for winter wheat crops in North-East Bulgaria.     

Validation of LAI and assessment of winter wheat status using spectral data and vegetation indices from SPOT VEGETATION and simulated PROBA-V images

Due to the information gap between the VEGETATION sensors and Sentinel-3 mission, the Belgian state decided to build a small satellite, Project for Onboard Autonomy-Vegetation (PROBA-V), to ensure the continuity of the data record for vegetation studies. In this study, simulated PROBA-V data generated by the Landsat Thematic Mapper (TM) were used to evaluate the potential of this mission to assess winter wheat status. The root mean square error (RMSE) of PROBA-V's leaf area index (LAI), which was generated using the exponential method and the interpolation method, is 0.33 and 0.96 for March 2011 and 1.40 and 3.33 for May 2011, respectively. Système Pour l'Observation de la Terre (SPOT) VEGETATION's LAI does not show a significant relationship with the reference LAI values except for the LAI values during the stem elongation 100% phenological stage generated using the exponential method (correlation coefficient, r = 0.91; p = 0.01). For the tillering and stem elongation 100% phenological stages, linear regression models for the fraction of absorbed photosynthetically active radiation (FAPAR) with PROBA-V's normalized difference vegetation index (NDVI) were developed (coefficient of determination, R ², of 0.94 and 0.88). Exponential models for LAI (R ² of 0.91 and 0.93) and fresh weight of above-ground biomass (AGBf) (R ² of 0.90 and 0.93) with PROBA-V's near-infrared (NIR) and visible and near-infrared bands (VNIR B2) were developed accordingly. The assessment of winter wheat status showed that the highest and the lowest values of PROBA-V's simulated data (SD), i.e. NDVI, normalized difference water index (NDWI), and LAI of Field 2 and Field 4, correspond to the ground-measured biometric parameters.     

Influence of molecular tilt angle on the SHG response of pyroelectric liquid crystal polymers

Second harmonic generation in novel pyroelectric liquid crystal polymers (PLCP) made from a series binary mixtures, was studied using 1100 nm as the fundamental wavelength. The PLCPs were prepared by photo-polymerization of binary mixtures of two monomers which exhibit a smectic C^* phase, A2c (4″-(R)-(−)-2-[(10-acrylo-yloxy)decyl]oxy-3-nitrophenyl 4-{4′-[(11-acryloyloxy)-undecyloxy]phenyl}benzoate) and Alb (4″-((R)-(+)-2-octyloxy)-3″-nitrophenyl 4-(4′-(11-acryloyloxy)undecyloxy)-phenyl)-benzoate). The highest d₁₆ and d₂₃ coefficients were found to be in the range 0.65–0.8 pm/V, and differed depending on the detailed preparation of the sample. All cases of polymers formed from the chiral smectic C* phase showed an SHG-signal with no external field present, indicating that polar order became fixed. The SHG-signal was found to increase with the tilt angle of the FLC molecules.     

Eigenschaften von PE-erzeugnissen nach der bewitterung

In the last years in a joint action with Institute of Chemical Industry - Sofia wide research work was completed on lightstabilized (atmospheric resistant) types of polyethylene high density creation and its implementation in transport packaging production. Quite interesting and unexpected result in relevant improvement of tested articles operating properties in the initial stages of the natural ageing after which they regularly change for the worse. Dynamic properties optimum of the polyethylene articles is reached in one to three months of the production date and direct open exhibition. It is found out that main influence on the results got is by some additives existance and concentration in the polyethylene composition. Available data and influences found out are mainly of quality nature but allow assumption that processes as recrystallization and disorientation in unbalanced structure created in treatment process are carried out which in the initial stages of operation predominate over ageing processes. An research is made on determination of exact quantity ratio between composition of the polyethylene (type and quantity of the additives) and treatment conditions (articles configuration and process parameters). Results with essential implementation value are expected.     

Effect of preparation methods on the catalyst performance of Co/MgLa mixed oxide catalyst for COx-free hydrogen production by ammonia decomposition

This work deals with the effect of catalyst preparation method of the mixed Co, Mg and La oxide catalysts on their structure and catalytic properties for ammonia decomposition. Two methods are used for catalysts preparations impregnation and co-precipitation (in air and in pure O₂ atmosphere), The Mg/La = 2 molar ratio and 5 wt% of cobalt content was maintained same in all catalysts. The catalyst performance was evaluated in the temperature range 300–550 °C at atmospheric pressure. The prepared catalysts were characterized by BET, XRD, TPR, XPS, CO₂-TPD and SEM techniques. No pronounced differences were observed in BET among the catalysts. It was found that the 5CML-OXY (5 wt%Co over MgLa catalyst prepared by co-precipitation method in oxygen atmosphere) has superior activity among the other catalysts. This could be attributed to availability of easily reducible cobalt species determined by TPR studies and enhanced interaction between Mg and La determined by SEM and XPS. The moderate basic site density determined by CO₂-TPD results was also increased in 5CML–OXY catalysts compared with other catalysts. These consequences are might be one of the reasons for enhanced activity of 5CML–OXY catalyst compared to other catalysts. Hence catalyst preparation by co-precipitation in oxygen atmosphere is the best method which might be one of the parameters that influenced on catalytic properties of the cobalt on MgOLa₂O₃ system, for ammonia decomposition.     

Nano-engineering of the anchoring of liquid crystals on solid surfaces

The solid surface in the conventional liquid crystal displays, being responsible for the liquid crystal alignment in the absence of external fields, is playing only a passive role in the switching of the liquid crystal layer. Recently, we have shown that the anchoring strength and the easy axis, two important parameters characterizing the liquid crystal alignment, can effectively be controlled by light via photo-induced nano-scale changes of the solid surface properties. We have also introduced two novel concepts of commanded anchoring, the electrically commanded surfaces (for mediating switching of the liquid crystal) and the high performance alignment layers (for facilitating the switching of the liquid crystal) realized practically by means of a proper nano-engineering of the alignment layer. Electrically commanded anchoring concepts are strong candidates for implementation in a new generation of advanced liquid crystal displays and devices.     

Structure and catalytic properties of Ni/MWCNTs and Ni/AC catalysts for hydrogen production via ammonia decomposition

The structure and catalytic properties of nickel catalysts supported on multi-wall carbon nanotubes (MWCNTs) and on three different types of activated carbon (AC) were studied. The surface areas of AC carriers were defining the size of supported nickel particles. Large surface area of AC led to small Ni nanoparticles and high Ni dispersion. Turnover frequency (TOF_NH3) of ammonia decomposition decreased with decreasing of Ni particle size. The highest degree of ammonia conversion was observed on Ni/AC prepared by using of AC support with largest surface area. The catalytic activity of Ni/MWCNTs was much higher than catalytic activity of the studied Ni/AC catalysts. The synergic nickel-support interaction and special electronic conductivity properties of MWCNTs were responsible for high catalytic activity of Ni/MWCNTs catalyst.     

Features of the attenuation and single-sided imaging potential of near-infrared laser radiation in tissue-like liquid turbid media

Tissue-like phantoms are important tools in studying light propagation and scattering in biological tissues and in the development, testing and calibration of novel optical diagnostic and therapeutic methods and instruments. This motivates the interest in characterizing the optical properties of tissue-simulating turbid media. In the present work, using an original approach, the specific features have been revealed experimentally and interpreted physically (as owing to the polydispersity of the ensemble of scatterers) of the generally non-linear behaviour of the extinction (total attenuation) coefficient of Intralipid-20% dilutions in distilled water, depending on the Intralipid concentration, for near-infrared laser radiation of different wavelengths. At relatively low incremental concentrations, the values obtained of the extinction coefficient are shown to increase linearly being in agreement at each wavelength of concern with results for the integral scattering coefficient predicted by empiric formulae found by other authors. Comparative estimation has been performed as well, depending on the radiation wavelength, of the potentialities of single-sided optical sensing of tissue-like media. The estimates obtained outline the advantage of the wavelengths around the upper limit of the tissue optical window.