Interpretation of long-chain structure from dilute solution properties of ultrahigh molecular weight polymers

Summary Systematic studies on solution properties of ultrahigh molecular weight polymers showed the existence of some special features as compared to usual length polymers. The paper discusses the possible appearance of branched structures in the polymerization process, structures able to influence the mentioned features. From experimental data on poly(methyl methacrylate), poly(butyl methacrylate) and polyacrylonitrile it appears that branching can be excluded, and the very high molecular weight domain considered may be responsible for the modifications observed in the molecular weight dependences on 2>, A₂ or [].     

Stability analysis of bilinear systems under aperiodic sampled-data control

This note considers the problem of local stability of bilinear systems with aperiodic sampled-data linear state feedback control. The sampling intervals are time-varying and upper bounded. It is shown that the feasibility of some linear matrix inequalities (LMIs), implies the local asymptotic stability of the sampled-data system in an ellipsoidal region containing the equilibrium. The method is based on the analysis of contractive invariant sets, and it is inspired by the dissipativity theory. The results are illustrated by means of numerical examples.     

Conformational transitions in poly(butyl methacrylate)

Summary Temperature dependence of viscosity data was investigated on poly(butyl methacrylate) fractions in dilute solution. A discontinuity in intrinsic viscosity was observed in the 25°C–35°C temperature range. Sharp changes of unperturbed dimensions were visualized from this behaviour. The phenomenon can be accounted for by assuming conformational changes of the chain in different solvents.     

Semantic Web computing in industry

The Semantic Web has attracted significant attention during the last decade. On the one hand, many research groups have changed their focus towards Semantic Web research and research funding agencies particularly in Europe have explicitly mentioned Semantic Web in their calls for proposals. On the other hand, industry has also begun to watch developments with interest and a number of large companies have started to experiment with Semantic Web technologies to ascertain if these new technologies can be leveraged to add more value for their customers or internally within the company, while there are already several offers of vendors of Semantic Web solutions on the market. The essence of the Semantic Web is to structure Web-based information to make it more interoperable, machine-readable and thereafter to provide a means to relate various information concepts more easily and in a reusable way. The Semantic Web acts as an additional layer on the top of the Web, and is built around explicit representations of information concepts and their relationships such as ontologies and taxonomies. Furthermore, Semantic Web technologies are not only valuable on an open environment like the Web, but also in closed systems such as in industrial settings. Hence, these technologies can be efficiently deployed for domains including Web Services, Enterprise Application Integration, Knowledge Management and E-Commerce, fulfilling existing gaps in current applications. This paper focuses on this synthesis between Semantic Web technologies and systems problems within industrial applications. There will be a short review of Semantic Web standards, languages and technologies followed by a more detailed review of applications of Semantic Web computing in industry. The paper covers theoretical considerations as well as use cases and experience reports on the topic, and we also present some current challenges and opportunities in the domain.     

A state dependent sampling for linear state feedback

In this work, a new state-dependent sampling control enlarges the sampling intervals of state feedback control. We consider the case of linear time invariant systems and guarantee the exponential stability of the system origin for a chosen decay rate. The approach is based on LMIs obtained thanks to sufficient Lyapunov–Razumikhin stability conditions and follows two steps. In the first step, we compute a Lyapunov–Razumikhin function that guarantees exponential stability for all time-varying sampling intervals up to some given bound. This value can be used as a lower-bound of the state-dependent sampling function. In a second step, an off-line computation provides a mapping from the state-space into the set of sampling intervals: the state is divided into a finite number of regions, and to each of these regions is associated an allowable upper-bound of the sampling intervals that will guarantee the global (exponential or asymptotic) stability of the system. The results are based on sufficient conditions obtained using convex polytopes. Therefore, they involve some conservatism with respect to necessary and sufficient conditions. However, at each of the two steps, an optimization on the sampling upper-bounds is proposed. The approach is illustrated with numerical examples from the literature for which the number of actuations is shown to be reduced with respect to the periodic sampling case.     

New Poly(N-isopropylacrylamide-butylacrylate) Copolymer Biointerfaces and Their Characteristic Influence on Cell Behavior In Vitro

Designing and obtaining new synthetic smart biointerfaces with specific and controlled characteristics relevant for applications in biomedical and bioengineering domains represents one of the main challenges in these fields. In this work, Matrix-Assisted Pulsed Laser Evaporation (MAPLE) is used to obtain synthetic biointerfaces of poly(N-isopropyl acrylamide-butyl acrylate) p(NIPAM-BA) copolymer with different characteristics (i.e., roughness, porosity, wettability), and their effect on normal HEK 293 T and murine melanoma B16-F1 cells is studied. For this, the influence of various solvents (chloroform, dimethylsulfoxide, water) and fluence variation (250–450 mJ/cm²) on the morphological, roughness, wettability, and physico–chemical characteristics of the coatings are evaluated by atomic force microscopy, scanning electron microscopy, contact angle measurements, Fourier-transform-IR spectroscopy, and X-ray photoelectron spectroscopy. Coatings obtained by the spin coating method are used for reference. No significant alteration in the chemistry of the surfaces is observed for the coatings obtained by both methods. All p(NIPAM-BA) coatings show hydrophilic character, with the exception of those obtained with chloroform at 250 mJ/cm². The surface morphology is shown to depend on both solvent type and laser fluence and it ranges from smooth surfaces to rough and porous ones. Physico–chemical and biological analysis reveal that the MAPLE deposition method with fluences of 350–450 mJ/cm² when using DMSO solvent is more appropriate for bioengineering applications due to the surface characteristics (i.e., pore presence) and to the good compatibility with normal cells and cytotoxicity against melanoma cells.     

Chemical transformation of PVC by phase transfer catalysis

Summary Suspension type PVC was reacted with sodium phenoxide in presence of different quaternary ammonium halides in THF or THF/water mixtures. The competition elimination vs. substitution of chlorine atoms depends on the homogeneity of the system, i.e. the more homogeneous the reaction mixture the less substituted the polymer.Dedicated to the 60th anniversary of Prof. Otto Vogl