Surface Reconstruction Engineering with Synergistic Effect of Mixed-Salt Passivation Treatment toward Efficient and Stable Perovskite Solar Cells

Surface passivation treatment is a widely used strategy to resolve trap-mediated nonradiative recombination toward high-efficiency metal-halide perovskite photovoltaics. However, a lack of passivation with mixture treatment has been investigated, as well as an in-depth understanding of its passivation mechanism. Here, a systematic study on a mixed-salt passivation strategy of formamidinium bromide (FABr) coupled with different F-substituted alkyl lengths of ammonium iodide is demonstrated. It is obtained better device performance with decreasing chain length of the F-substituted alkyl ammonium iodide in the presence of FABr. Moreover, they unraveled a synergistic passivation mechanism of the mixed-salt treatment through surface reconstruction engineering, where FABr dominates the reformation of the perovskite surface via reacting with the excess PbI₂. Meanwhile, ammonium iodide passivates the perovskite grain boundaries both on the surface and top perovskite bulk through penetration. This synergistic passivation engineer results in a high-quality perovskite surface with fewer defects and suppressed ion migration, leading to a champion efficiency of 23.5% with mixed-salt treatment. In addition, the introduction of the moisture resisted F-substituted groups presents a more hydrophobic perovskite surface, thus enabling the decorated devices with excellent long-term stability under a high humid atmosphere as well as operational conditions.     

Relation between the cavity detuning and the output opticalintensity in free-electron lasers

The authors use a simple model of saturation in free-electron lasers operating with pulsed beams to study the intensity growth as a function of the cavity mismatch and of the coupling parameter. In spite of the simplicity of the model, the dependence of the intracavity power, as a function of the cavity detuning, is reproduced remarkably well. It is also pointed out that an enhancement of the optical power is obtained by adjusting the cavity length while the optical signal grows. The problem is analyzed qualitatively and realization schemes are proposed     

Rice and beans--effect of milk, mineral, and vitamin A, on weight gain, food intake, and body protein retention

Weanling rats were fed on diets of rice/beans (RB) with or without mineral (M) supplement; vitamin A (A); M + A (MA); or milk (L), containing from 3 to 14% protein. As determined by various measures, the best results were observed in the group fed the RB diet, supplemented with L. This group was followed by those receiving the MA and M diets. Protein utilization in the RB diet, as well as minimum protein requirement for maintaining body weight, depend on the supplementary nutrients. The mechanism of this effect may be related to the appetite of the animals and to the voluntary intake, which is influenced and regulated by the diet composition.     

An Empirical Study on Views of Importance of Change Impact Analysis Issues

Change impact analysis is a change management activity that previously has been studied much from a technical perspective. For example, much work focuses on methods for determining the impact of a change. In this paper, we present results from a study on the role of impact analysis in the change management process. In the study, impact analysis issues were prioritised with respect to criticality by software professionals from an organisational perspective and a self-perspective. The software professionals belonged to three organisational levels: operative, tactical and strategic. Qualitative and statistical analyses with respect to differences between perspectives as well as levels are presented. The results show that important issues for a particular level are tightly related to how the level is defined. Similarly, issues important from an organisational perspective are more holistic than those important from a self-perspective. However, our data indicate that the self-perspective colours the organisational perspective, meaning that personal opinions and attitudes cannot easily be disregarded. In comparing the perspectives and the levels, we visualise the differences in a way that allow us to discuss two classes of issues: high-priority and medium-priority. The most important issues from this point of view concern fundamental aspects of impact analysis and its execution.     

An experimental investigation of personality types impact on pair effectiveness in pair programming

In this paper, pair programming is empirically investigated from the perspective of developer personalities and temperaments and how they affect pair effectiveness. A controlled experiment was conducted to investigate the impact of developer personalities and temperaments on communication, pair performance and pair viability-collaboration. The experiment involved 70 undergraduate students and the objective was to compare pairs of heterogeneous developer personalities and temperaments with pairs of homogeneous personalities and temperaments, in terms of pair effectiveness. Pair effectiveness is expressed in terms of pair performance, measured by communication, velocity, design correctness and passed acceptance tests, and pair collaboration-viability measured by developers’ satisfaction, knowledge acquisition and participation. The results have shown that there is important difference between the two groups, indicating better communication, pair performance and pair collaboration-viability for the pairs with heterogeneous personalities and temperaments. In order to provide an objective assessment of the differences between the two groups of pairs, a number of statistical tests and stepwise Discriminant Analysis were used.

Towards an ICT-based psychology: E-psychology

Cognitive science is the scientific domain which studies, analyzes, simulates and infers for various aspects, functions and procedures of human mentality such as, thinking, logic, language, knowledge, memory, learning, perception and the ability to solve problems. E-psychology is in close relation with the cognitive science domain, but expands beyond it, as e-psychology is the efficient convergence of psychology and Information and Communication Technologies (ICTs). E-psychology offers a number of services such as supporting, diagnosis, assessment, therapy, counseling, intervention and tests through an effective exploitation of ICTs. This article presents a user-friendly, flexible and adaptive electronic platform, which supports both synchronous and asynchronous e-psychology activities through the use of informative and communicative tools and services, which can be adapted to support various methods of e-psychology activities. It is important to underline that e-psychology is not an alternative psychology field, but a resource to enhance the conventional psychology process.     

Fitness functions in evolutionary robotics: A survey and analysis

This paper surveys fitness functions used in the field of evolutionary robotics (ER). Evolutionary robotics is a field of research that applies artificial evolution to generate control systems for autonomous robots. During evolution, robots attempt to perform a given task in a given environment. The controllers in the better performing robots are selected, altered and propagated to perform the task again in an iterative process that mimics some aspects of natural evolution. A key component of this process–one might argue, the key component–is the measurement of fitness in the evolving controllers. ER is one of a host of machine learning methods that rely on interaction with, and feedback from, a complex dynamic environment to drive synthesis of controllers for autonomous agents. These methods have the potential to lead to the development of robots that can adapt to uncharacterized environments and which may be able to perform tasks that human designers do not completely understand. In order to achieve this, issues regarding fitness evaluation must be addressed. In this paper we survey current ER research and focus on work that involved real robots. The surveyed research is organized according to the degree of a priori knowledge used to formulate the various fitness functions employed during evolution. The underlying motivation for this is to identify methods that allow the development of the greatest degree of novel control, while requiring the minimum amount of a priori task knowledge from the designer.     

Estimating the development cost of custom software

In this paper an approach for the estimation of software development costs is presented. The method is based on the characterization of the software to be developed in terms of project and environment attributes and comparison with some similar completed project(s) recovered from a historical database. A case study is also presented, focusing on the calibration and application of the method on 59 information systems implementing supply chain functions in industry. Various strategies are explored, the best of which predicted effort quite effectively, with a mean estimation error of 24% with respect to the actual effort.