首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9011篇
  免费   455篇
  国内免费   37篇
电工技术   93篇
综合类   58篇
化学工业   1689篇
金属工艺   214篇
机械仪表   222篇
建筑科学   291篇
矿业工程   26篇
能源动力   198篇
轻工业   836篇
水利工程   60篇
石油天然气   35篇
武器工业   2篇
无线电   656篇
一般工业技术   1582篇
冶金工业   2346篇
原子能技术   60篇
自动化技术   1135篇
  2024年   22篇
  2023年   79篇
  2022年   109篇
  2021年   205篇
  2020年   188篇
  2019年   159篇
  2018年   286篇
  2017年   261篇
  2016年   282篇
  2015年   212篇
  2014年   249篇
  2013年   531篇
  2012年   460篇
  2011年   472篇
  2010年   339篇
  2009年   320篇
  2008年   387篇
  2007年   322篇
  2006年   271篇
  2005年   239篇
  2004年   199篇
  2003年   206篇
  2002年   191篇
  2001年   176篇
  2000年   170篇
  1999年   163篇
  1998年   737篇
  1997年   448篇
  1996年   295篇
  1995年   178篇
  1994年   145篇
  1993年   165篇
  1992年   43篇
  1991年   73篇
  1990年   44篇
  1989年   55篇
  1988年   56篇
  1987年   54篇
  1986年   33篇
  1985年   67篇
  1984年   32篇
  1983年   39篇
  1982年   46篇
  1981年   54篇
  1980年   35篇
  1979年   28篇
  1978年   41篇
  1977年   67篇
  1976年   92篇
  1973年   21篇
排序方式: 共有9503条查询结果,搜索用时 15 毫秒
1.
This work investigates the effect of the addition of small amounts of Ru (0.5‐1 wt%) to carbon supported Co (10 wt%) catalysts towards both NaBH4 and NH3BH3 hydrolysis for H2 production. In the sodium borohydride hydrolysis, the activity of Ru‐Co/carbon catalysts was sensibly higher than the sum of the activities of corresponding monometallic samples, whereas for the ammonia borane hydrolysis, the positive effect of Ru‐Co systems with regard to catalytic activity was less evident. The performances of Ru‐Co bimetallic catalysts correlated with the occurrence of an interaction between Ru and Co species resulting in the formation of smaller ruthenium and cobalt oxide particles with a more homogeneous dispersion on the carbon support. It was proposed that Ru°, formed during the reduction step of the Ru‐Co catalysts, favors the H2 activation, thus enhancing the reduction degree of the cobalt precursor and the number of Co nucleation centers. A subsequent reduction of cobalt and ruthenium species also occurs in the hydride reaction medium, and therefore the state of the catalyst before the catalytic experiment determines the state of the active phase formed in situ. The different relative reactivity of the Ru and Co active species towards the two investigated reactions accounted for the different behavior towards NaBH4 and NH3BH3 hydrolysis.  相似文献   
2.
3.
Nitrous oxide (N2O) effects were evaluated, as a behavioural model of inert gas narcosis, in rats performing a vigilance task in which they were required to respond to a slight luminous increment of the house-light. A dose-related decrease of correct responses was produced by the tested range of concentrations of N2O (from 30 to 70% N2O), with a parallel increase of anticipatory responses up to 60% N2O and a dramatic increase of omissions at 70% N2O. The influence of preparatory period duration on hits delays suggested a 'conditional probability effect' conserved under N2O. Pretreatment of animals with flumazenil (a central benzodiazepine receptor antagonist) did not improve performance under 40% N2O. Naltrexone, an opiate receptor antagonist, however, increased the N2O-induced deficits. These results suggest that benzodiazepine receptors are not involved in N2O-induced impairments in this attentional task, but opiate mechanisms may be implicated.  相似文献   
4.
5.
Summary Polyimides (PI) having different molecular weights were prepared by condensation of oxydiphthalic anhydride with 9,9-bis-(4-aminophenyl)fluorene in nitrobenzene solution at 180°C. These polyimides carried two amino chain ends which allowed us to fix polycaprolactam chains (PA6) to obtain PA6-PI-PA6 type copolymers. The elemental analysis and infrared spectroscopic determination gave the proportion of PA6 (or PI) in the copolymers. The studies of thermal properties-DSC and TGA-allowed us to characterize the copolymers.  相似文献   
6.
A new system based on the harnessing of solar and wind power is presented for heat dissipation in air conditioning facilities. The innovation offered by the new system is the integration of two well-known subsystems: a cooling tower and a solar chimney which increases the air flow without the use of electric power. The system is described and presented together with a model for its study. The field data acquired from the prototype built in southern Spain establishes the actual potential of the system, which provides a new approach to a sustainable technological development.  相似文献   
7.
The extinction coefficient ? at 2.9 μm for OH in fluoride glasses is measured by determining the amount of HF evolved during heating of the glass under steam and the corresponding intensity of the OH absorption band. This coefficient is respectively equal to 31 litre mole?1 cm?1 for BTYbZ glass (15 BaF2 - 29 ThF4 - 28 YbF3 - 28 ZnF2) and 19.5 litre mole?1 cm?1 for BALLA glass (34 BaF2 - 57 ZrF4 - 4 AlF3 - 5 LaF3).  相似文献   
8.
To obtain more biologically relevant data there is a growing interest in the use of living cells for assaying the biological activity of unknown chemical compounds. Density ‘multiplex’ cell‐based assays, where different cell types are mixed in one well and simultaneously investigated upon exposure to a certain compound are beginning to emerge. To be able to identify the cells they should be attached to microscopic carriers that are encoded. This paper investigates how digitally encoded microparticles can be loaded with cells while keeping the digital code in the microcarriers readable. It turns out that coating the surface of the encoded microcarriers with polyelectrolytes using the layer‐by‐layer (LbL) approach provides the microcarriers with a ‘highly functional’ surface. The polyelectrolyte layer allows the growth of the cells, allows the orientation of the cell loaded microcarriers in a magnetic field, and does not hamper the reading of the code. It has further been shown that the cells growing on the polyelectrolyte layer can become transduced by adenoviral particles hosted by the polyelectrolyte layer. It is concluded that the digitally encoded microparticles are promising materials for use in biomedical and pharmaceutical in‐vitro research where cells are used as tools.  相似文献   
9.
This paper deals with error estimators based on residuals on the constitutive relation which have been developed for the past 20 years at Cachan. Especially in the case of elasticity, these error estimators can become poor in situations where the material and the mesh are strongly anisotropic. The crucial point herein is the construction of equilibrated stress fields from the computed finite element solution. Therefore, in this paper, the approach and in particular this last point are re-examined. Several important modifications are introduced in the concepts and basic techniques. Hence, a new generation of error estimators which seem to be extremely robust upon initial applications has been generated.  相似文献   
10.
A comparative pharmacokinetic study has been performed in 19 healthy male volunteers in a single-dose, randomized, two way cross-over design with two preparations of gemfibrozil (CAS 25812-30-0) capsules each of them containing 300 mg active ingredient. The test preparation was Innogem 300 mg capsule. The plasma concentration of gemfibrozil was determined by a validated HPLC-UV analytical method. The statistical comparison of individual pharmacokinetic parameters (AUC0-16, AUC0-oc Cmax, tmax) of the two capsule preparations was performed by three-way analysis of variance (ANOVA), Wilcoxon's, Westlake's, Schuirmann's and Hanck-Anderson's method as well as by the calculation of confidence intervals on the ratio of test/reference. The relative bioavailability of the test preparation with respect to the reference preparation in terms of the AUC0-oc was 104.06 +/- 21.61%. No statistically significant difference was found between the pharmacokinetic parameters, calculated from plasma concentration-time curves, indicating that the two preparations were bioequivalent.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号