Optimal DLC protocol configuration for realistic broadband fixed wireless access networks based on ATM

DLC protocols, scheduling, and multiplexing issues for broadband fixed wireless access networks based on ATM are discussed. The established DSA++ mac protocol has been developed at ComNets and has been widely applied within the German project ATMmobil. It has been a fundamental contribution to the etsi bran standardisation of HIPERLAN /2. The DSA++ is here modified to perform optimal within the fixed wireless access network environment. Therefore, realistic traffic as well as radio channel models for the respective scenarios are introduced. Simulation results are presented, showing the feasibility of the respective protocol stack for offering broadband multimedia services with reasonable quality of service. In addition to this advanced protocol approach, two systems are discussed which are currently under standardisation process. The IEEE 802.16 as well as the European hiperaccess systems are both proposed for fixed wireless access networks. Expected scenarios and applications are presented and basic requirements the standards have to fulfil are derived. As another aspect of access networks, their impact on the global information society is discussed.     

Potential and Limitations of Natural Chabazite for Selective Catalytic Reduction of NOx with NH3

The potential of the natural chabazite for the selective catalytic reduction (SCR) of NOx with NH₃ is evaluated in the present work. Activity tests were performed under technically relevant reaction and temperature conditions for the fresh and hydrothermally aged catalysts. The natural chabazite before and after alkaline removal as well as after iron and copper addition were compared. The structural as well as surface and bulk properties were elucidated by a variety of complementary characterization techniques, i.e. XRD, XPS, EPR, BET, NH₃‐TPD, ex situ and in situ XAS. The results indicate that an important facet for using the natural chabazite for the standard and fast SCR reactions is the removal of alkaline metals, which at the same time also leads to a partial change of the structure and the size of the iron‐containing particles. The performance and especially the hydrothermal stability can be further improved by copper addition.     

Electrochemically switchable polypyrrole coated membranes

A method for coating membranes with polypyrrole (PPy) has been developed. Different membranes, such as microfiltration as well as ion exchanger membranes have been coated with PPy to yield electrical conductivity of the membranes.The coated membranes have been investigated by cyclic voltammetry and scanning electron microscopy and their permeability and permselectivity have been tested. The results show that PPy can be tailored as cation or anion exchanger and its porosity can be controlled to avoid any impairment of the membrane by the polymer layer. These PPy coated membranes can be applied as electrochemically switchable, functionalised membranes with controllabel and variable separation properties.     

Optimal Design of Experiments for Parameter Identification of Ceramic Porous Membranes

Six different experimental schemes for mass transfer through porous membranes are compared for the efficiency with respect to parameter identification, namely dynamic single‐gas permeation, dynamic multi‐gas permeation, steady‐state single‐gas permeation, steady‐state multi‐gas permeation, transient diffusion, and isobaric diffusion experiments. The comparison is made under optimal experimental conditions, which are obtained from optimal experimental design (OED) based on the Fisher information matrix. The covariance matrix of the parameters for each experimental scheme is estimated by the Cramér‐Rao lower bound. To solve the optimization problems, a hybrid optimizer which combines a genetic algorithm and a gradient‐based algorithm is used.     

Parameter identification for ordinary and delay differential equations by using flat inputs

The concept of differential flatness has been widely used for nonlinear controller design. In this contribution, it is shown that flatness may also be a very useful property for parameter identification. An identification method based on flat inputs is introduced. The treatment of noisy measurements and the extension of the method to delay differential equations are discussed. The method is illustrated by two case studies: the well-known FitzHugh-Nagumo equations and a virus replication model with delays.     

Biotransformation of alkylglycerols in plant cell cultures: Production of platelet activating factor and other biologically active ether lipids

Plant cells in culture are capable of incorporating exogenous 1-O-alkyl-sn-glycerols into various neutral and ionic ether lipids. 1-O-Alkyl-2-acyl-sn-glycerol-3-phosphocholines, the major class of compounds thus formed, are used for the preparation of platelet activating factor (PAF) in high yields. Similarly, the prochiral 2-O-alkyl-sn-glycerols are transformed to chiral 2-O-alkyl glycerophospholipids from which compounds can be obtained that exhibit antiviral activity in plant and animal cells. Reaction of 1-O-alkyl-2-acyl-sn-glycerol-3-phosphocholines with phospholipase D in the presence of ethanolamine leads to 1-O-alkyl-2-acyl-sn-glycerol-3-phosphoethanolamines, which serve as starting material, for the preparation of 1-O-alkyl-2-acyl-sn-glycero-3-phospho-(N-acyl)ethanolamines, compounds known to have antitumor activity. Based on a paper presented at the Third International Conference on Platelet-Activating Factor and Structurally Related Alkyl Ether Lipids, Tokyo, Japan, May 1989. Dedicated to Professor Morris Kates, Ottawa, on the occasion of his retirement.