Optical properties of evaporated Ge20Se80−x Tl x thin films

Chalcogenide glasses with composition Ge₂₀Se_80–x Tl _x (x=10, 15, 20, 25, 35%) have been prepared by the usual melt-quenching technique. Thin films of the mentioned compositions have been prepared by the electron beam evaporation. In addition, another set taken from the composition ofX=30 at % with different thicknesses (d=14.7, 30.0, 56.5, 70.0, 101.0, 180.0 nm) have been taken into consideration. The X-ray diffraction (XRD) analysis revealed the amorphous nature of the prepared films. It was found that, in contrast to the optical gap (E _op), both the extent of the band tailing (B), and the band gap (E _e) increase with increasing thallium content. In other side,E _op showed thickness independency. The refractive index (n) showed obvious dependence on both composition and thickness also on the energy of the incident radiation.     

Modeling of notch tensile behavior of martensitic steels

Notch tensile tests have been carried out on six grades of a high-strength martensitic steel at different hardness levels to investigate the effects of stress triaxiality at the net section and uniaxial tensile properties on fracture behavior. Cylindrical V-notched specimens were used in these tests with the notch-root radius, ρ, ranging from 0.03–1.4 mm, and with the value of the net-to-gross diameter ratio being 0.6. The notch strength ratio (NSR) was found to attain its maximum value at ρ=0.38 mm. The test results were used successfully for screening the fracture toughness behavior of the martensitic steel by extrapolating the corresponding ρ-NSR curve to ρ=0.0. Further, finite element computation of the average stress triaxiality factor ( ) enabled the development of a model more accurate than that reported in the literature for estimating NSR for a ductile material as a function of and its uniaxial tensile properties.     

Stability and calibration of platinum/palladium thermocouples following heat treatment

In this paper we describe the changes in the thermo EMF of Pt/Pd thermocouples in the temperature range from 0 to 1100 °C following a series of heat treatment at 960 °C. The magnitudes of the changes in EMF, the short and long term stability of the thermocouple were estimated, experimental results are presented. For the calibration of the thermocouple we have employed a reference polynomial function given in the literature [Metrologia 35 (1998) 761] for Pt/Pd thermocouples based on the International Temperature Scale of 1990 (ITS-90).     

Variations in ascorbic acid content of gramineae during germination and the effect of β- and γ- radiation

The ascorbic acid content of three types of Gramineae, viz., Triticum vulgare, Hordeum vulgare and Zea mays (Nab El-Gamal and Beladi), is given and also the average variations in the seeds during germination are shown. The effects on the seedlings of β-irradiation emitted from small doses of radioactive H₃³²PO₄ as well as by irradiation with 131 I, are investigated.     

The coefficient of performance for a solar absorption dual cycle

The traditional definition of the coefficient of performance (COP) can create misleading results because this definition does not define the heat input base to be used for estimating the COP. Furthermore, such one-dimensional definitions do not consider other important factors which may affect the system selection.

A new selection criterion for a solar powered dual absorption system will be presented in this paper. The dual cycle, which has the advantage of not using a cooling tower, has often been ignored because of the misleading definition of the COP.

The present paper also describes a lithium bromide dual absorption cycle.     

A solar-powered LiBr dual cycle

The absorption system is one of the most suitable techniques for utilising solar energy for air-conditioning purposes. Although it uses solar energy directly with minimum conversion, it consumes considerable quantities of water for the cooling tower. This is a serious disadvantage where solar energy is available whilst water is scarce.The main purpose of this paper is to introduce the lithium bromide (LiBr) absorption cycle which avoids the use of a wet cooling tower. The characteristics of this dual cycle will be examined and new selection criteria for such solar-powered dual absorption systems will be introduced.     

Evaluation of 3 esterase tests for the diagnosis of subclinical mastitis at dry-off and freshening in dairy cattle

Subclinical mastitis (SCM) and intramammary infection (IMI) increase esterase activity in the glandular secretions of dairy cattle. Our objective was to evaluate the clinical performance of 3 commercially available esterase tests for diagnosing SCM and IMI. Foremilk samples were collected from 380 quarters (96 cows) at dry-off and from 329 quarters (83 cows) within 4 to 7 d after calving. Quarter somatic cell count (SCC) was measured using the reference method (DeLaval cell counter; De Laval International AB, Tumba, Sweden) with SCM defined as SCC >200,000 cells/mL. Bacterial culture of foremilk samples was used to diagnose IMI based on the growth of ≥100 cfu/mL. The SCC was estimated using 3 PortaSCC tests (PortaCheck, Moorestown, NJ) from the measured esterase activity and the California Mastitis Test (CMT). Clinical performance was evaluated using logistic regression to determine the area under the receiver operating characteristic curve (AUC) and identify test sensitivity (Se) and specificity (Sp) at the optimal cut-point for diagnosing SCM and IMI. Test agreement was also evaluated using the kappa coefficient (κ) and weighted κ. The PortaSCC color test was the best-performing PortaSCC test for diagnosing SCM at dry-off (AUC = 0.90, Se = 0.91, Sp = 0.81, κ = 0.71) and at freshening (AUC = 0.86, Se = 0.74, Sp = 0.95, κ = 0.72), at an optimal cut-point of ≥250,000 cells/mL but required 45 min to produce a result. For comparison, the CMT required 2 min to produce a result and a CMT score of trace or higher was superior to the PortaSCC color test for diagnosing SCM at dry-off (AUC = 0.95, Se = 0.95, Sp = 0.86, κ = 0.81) and freshening (AUC = 0.88, Se = 0.79, Sp = 0.95, κ = 0.76). The PortaSCC quick test was the best-performing PortaSCC test for diagnosing IMI at dry-off (AUC = 0.81, Se = 0.81, Sp = 0.78 κ = 0.40) and required 5 min to produce a result, whereas the PortaSCC color test was the best performing PortaSCC test for diagnosing IMI at freshening (AUC = 0.80, Se = 0.75, Sp = 0.79 κ = 0.38). For comparison, the CMT was inferior to the PortaSCC quick test for diagnosing IMI at dry-off (AUC = 0.73, Se = 0.76, Sp = 0.60, κ = 0.20) but was equivalent to the PortaSCC color test at freshening (AUC = 0.79, Se = 0.58, Sp = 0.93, κ = 0.50). The PortaSCC color and quick tests and CMT were considered good tests for diagnosing SCM and IMI because clinically useful tests typically have an AUC >0.80 and κ >0.6. Based on the test sensitivity, cost, and analysis time, there does not appear to be a persuasive reason to select the PortaSCC tests over the traditional CMT for diagnosing SCM and IMI.     

Evaluation of the analytical performance of a portable ion-selective electrode meter for measuring whole-blood,plasma, milk,abomasal-fluid,and urine sodium concentrations in cattle

A portable ion-selective electrode (ISE) meter (LAQUAtwin B-722; Horiba Instruments Inc., Irvine, CA) is available for measuring the sodium ion concentration ([Na]) in biological fluids. The objective of this study was to characterize the analytical performance of the ISE meter in measuring [Na] in whole-blood, plasma, milk, abomasal fluid, and urine samples from cattle. Method comparison studies were performed using whole-blood and plasma samples from 106 sick calves and 11 sick cows admitted to a veterinary teaching hospital, 80 milk and 206 urine samples from 16 lactating Holstein-Friesian cows with experimentally induced free water, electrolyte, and acid-base imbalances, and 67 abomasal fluid samples from 7 healthy male Holstein-Friesian calves fed fresh milk with or without an oral electrolyte solution. Deming regression and Bland-Altman plots were used to determine the accuracy of the meter against reference methods. The meter used in direct mode on undiluted samples measured whole-blood [Na] 9.7 mmol/L (7.3%) lower than a direct ISE reference method and plasma [Na] 16.7 mmol/L (12.7%) lower than an indirect ISE reference method. The meter run in direct mode measured milk [Na] 3.1 mmol/L lower and abomasal fluid [Na] 9.0% lower than indirect ISE reference methods. The meter run in indirect mode on diluted samples accurately measured urine [Na] compared with an indirect ISE reference method. We conclude that, after adjustment for the bias determined from Bland-Altman plots, the LAQUAtwin ISE meter provides a clinically useful and low-cost cow-side instrument for measuring [Na] in whole blood, plasma, milk, and abomasal fluid.