The Influence of Glow and Afterglow Cold Plasma Treatment on Biochemistry,Morphology, and Physiology of Wheat Seeds

Cold plasma (CP) technology is a technique used to change chemical and morphological characteristics of the surface of various materials. It is a newly emerging technology in agriculture used for seed treatment with the potential of improving seed germination and yield of crops. Wheat seeds were treated with glow (direct) or afterglow (indirect) low-pressure radio-frequency oxygen plasma. Chemical characteristics of the seed surface were evaluated by XPS and FTIR analysis, changes in the morphology of the seed pericarp were analysed by SEM and AFM, and physiological characteristics of the seedlings were determined by germination tests, growth studies, and the evaluation of α-amylase activity. Changes in seed wettability were also studied, mainly in correlation with functionalization of the seed surface and oxidation of lipid molecules. Only prolonged direct CP treatment resulted in altered morphology of the seed pericarp and increased its roughness. The degree of functionalization is more evident in direct compared to indirect CP treatment. CP treatment slowed the germination of seedlings, decreased the activity of α-amylase in seeds after imbibition, and affected the root system of seedlings.     

A novel facile synthesis and characterization of molybdenum nanowires

We describe a straightforward technique to synthesize pure Mo nanowires (NWs) from Mo₆S_yI_z (8,2 <y + z ≤ 10) NWs as precursor templates. The structural transformations occur when Mo₆S_yI_z NWs are annealed in Ar/H₂ mixture leading to the formation of pure Mo NWs with similar structures as initial morphologies. Detailed microscopic characterizations show that large diameters (>15 nm) Mo NWs are highly porous, while small diameters (<7 nm) are made of solid nanocrystalline grains. We find NW of diameter 4 nm can carry up to 30 μA current without suffering structural degradation. Moreover, NWs can be elastically deformed over several cycles without signs of plastic deformation.     

Murska Sobota新剧院

建筑的前身是一个始建于20世纪50年代的电影院,由现代主义建筑师Franc Novak设计,一直被用作电影放映,年久失修。到21世纪,其陈旧的结构已无法满足一个新的建筑综合体的要求。     

3D Visualization on mobile devices

This paper discusses current status and recent advancements of 3D graphics on mobile platforms and describes open issues concerning its usage in different applications. We have treated two particular application fields. Firstly, we deal with problems of visualization of complex data structures on mobile devices. The implementation of a 3D visualization renderer on the Symbian platform for mobile devices is written as a C++ application and based on the DieselEngine^® as a rendering engine. 3D visualization of data is generated in the form of a Virtual Reality Modelling Language (VRML) file meaning that actually any kind of 3D content written in VRML file format can be rendered on such a device. It was the result of a project the objective of which was to provide a user interface on a mobile platform displaying visualization of hierarchical Grid monitoring data. Secondly, we describe the system that brings face animation to embedded platforms. Face animation is considered to be one of the toughest tasks in computer animation today and its delivery to mobile platforms brings possibilities for development of new innovative and attractive services for the mobile market.     

pH-based one pot synthesis of biocompatible olive shaped inorganic particles

A novel, single-step, one-pot method for preparation of inorganic hollow particles is introduced. The concept is grounded on the classical theory of nucleation of growth and can be carried out entirely at room temperature. Starting from an appropriate solution, precipitation and selective dissolution of inorganic nanoparticles are triggered by continuous addition of a salt while carefully controlling the pH. The approach is demonstrated on the example of hollow calcium phosphate particles using calcium carbonate solid nanoparticles as a template. The proposed synthesis procedure is simple and cheap and can be extended to other biocompatible compounds. It also can be upgraded with an additional in situ step.     

Power characteristics of multiple inductively coupled RF discharges inside a metallic chamber

The characteristics of an innovative configuration of multiple radiofrequency (RF) coils immersed in a large metallic chamber are presented. Water-cooled copper coils were mounted within the slits of double-walled glass tubes, which were immersed into a stainless-steel chamber. The coils were connected in parallel to a gamma-type matching network, powered by an RF generator operating at industrial frequency. Adjustable leads enabled optimisation of the line impedances and thus uniformly distributed RF power across the four coils. Transitions from E- to H-mode and vice versa were measured for all coils at various oxygen pressures between 5 and 25 Pa. A uniform plasma was sustained in H-mode at the absorbed power threshold, which increased monotonously with increasing pressure in the metallic chamber. All coils exhibit the same E- to H-mode transition hysteresis and need the same amount of power for transitioning from E- to H-mode. The setup enables maintaining uniform plasma in virtually any number of coils at high power without the risk of arcing and without the dead volume typical for a classical configuration with coils mounted outside the metallic chamber.     

Biocompatibility and Mechanical Stability of Nanopatterned Titanium Films on Stainless Steel Vascular Stents

Nanoporous ceramic coatings such as titania are promoted to produce drug-free cardiovascular stents with a low risk of in-stent restenosis (ISR) because of their selectivity towards vascular cell proliferation. The brittle coatings applied on stents are prone to cracking because they are subjected to plastic deformation during implantation. This study aims to overcome this problem by using a unique process without refraining from biocompatibility. Accordingly, a titanium film with 1 µm thickness was deposited on 316 LVM stainless-steel sheets using magnetron sputtering. Then, the samples were anodized to produce nanoporous oxide. The nanoporous oxide was removed by ultrasonication, leaving an approximately 500 nm metallic titanium layer with a nanopatterned surface. XPS studies revealed the presence of a 5 nm-thick TiO₂ surface layer with a trace amount of fluorinated titanium on nanopatterned surfaces. Oxygen plasma treatment of the nanopatterned surface produced an additional 5 nm-thick fluoride-free oxide layer. The samples did not exhibit any cracking or spallation during plastic deformation. Cell viability studies showed that nanopatterned surfaces stimulate endothelial cell proliferation while reducing the proliferation of smooth muscle cells. Plasma treatment further accelerated the proliferation of endothelial cells. Activation of blood platelets did not occur on oxygen plasma-treated, fluoride-free nanopatterned surfaces. The presented surface treatment method can also be applied to other stent materials such as CoCr, nitinol, and orthopedic implants.     

Formation of Nanocrystalline Transition-Metal Ferrites inside a Silica Matrix

Nanocrystalline transition-metal ferrites were synthesized inside an amorphous silica matrix by the sol–gel method. The formation of spinel ferrites began above 400°C, giving fine particles of about 10 nm at 800°C. This is associated with a specific role of the silica matrix, which facilitates the diffusion of the reacting cations, enhancing the ferrite formation. Above 1000°C the MnFe₂O₄ and CuFe₂O₄ nanoparticles lost their fine nature. The dried gels and crystalline materials were characterized by X-ray diffraction, thermal, FTIR, and BET analyses as well as by high-resolution scanning transmission electron microscopy.     

Bioactive glass–ceramic coated titanium implants prepared by electrophoretic deposition

Surface modification of Ti alloys towards an improved osteoinductive behaviour is one of the major challenges in orthopaedic implant technology nowadays. One way to achieve this is by applying a bioactive coating which can increase the rate of osseointegration and chemical bonding of surrounding bone to the implant. In the present work, the production of a bioactive glass–ceramic coating on flat Ti alloys by electrophoretic deposition is demonstrated. The coatings are applied by cathodic deposition from non-aqueous suspensions followed by sintering in vacuum, avoiding uncontrolled oxidation of the Ti substrates. The use of non-aqueous suspensions both allowed to reduce the deposition time and yielded homogeneous coatings with a uniform thickness of 8 μm. Evaluation of the coating adhesion confirmed the good mechanical performance of the coatings with a tensile bond strength of 41.0 ± 11.1 MPa. Additionally, a feasibility study demonstrated the potential of electrophoretic deposition as a coating technique for commercial complex implants.