Transient studies on methane oxidative coupling over alkali-metal promoted titanate catalysts

A transient method to study the role of the different oxygen species involved in oxidative coupling of methane is discussed. The method is applied to two new active catalysts for this process, which are based on alkali metal loaded titanates of lanthanum and nickel and also to a lithium/titania catalyst used in previous works. The results show that the participation of lattice oxygen in the formation of C2 products depends on the Li loading and the type of titanate used.     

Ecological efficiency and thermoeconomic analysis of a cogeneration system at a hospital

This work aims with an approach for cogeneration plants evaluation based on thermoeconomic functional diagram analysis. The second law of thermodynamics is used to develop a methodology to analyse cogeneration systems, based on exergoeconomics evaluation. The thermoeconomic optimisation method developed is applied to allow a better configuration of the cogeneration plant associated to a university hospital. Also ecological efficiency is evaluated. The method was efficient and contributes for thermoeconomics modelling and analysis and can be applied to any sort of thermal system, especially those with combined heat and power in thermal parity.     

The impact of alkali elements on the degradation of CIGS solar cells

Unencapsulated CIGS solar cells with high and low contents of sodium (Na) and potassium (K) were simultaneously exposed to damp heat and illumination. The solar cells with a high alkali (Na, K) content exhibited higher initial conversion efficiencies, but degraded severely within 100 h, while the alkali poor samples kept relatively stable performance under damp heat and illumination. The degradation of the samples with a high alkali content resulted in the formation of sodium rich spots on the top ZnO:Al surface of the samples. This is likely caused by light‐induced Na⁺ migration via the grain boundaries in the absorber to the depletion region, where the Na⁺ accumulated. This allowed subsequent Na⁺ transport through the depletion region due to the lowering of the internal electric field caused both by the Na⁺ accumulation and illumination. The migration resulted in the formation of shunt paths, which reduced the shunt resistance and open circuit voltage. Furthermore, ingression of water into the ZnO:Al is expected to be responsible for a slow but steady increase in series resistance for both high and low alkali solar cells. Additionally, sodium migration led to a severe increase of the series resistance in case of alkali rich samples. Copyright © 2015 John Wiley & Sons, Ltd.     

Development of a‐SiOx:H solar cells with very high Voc × FF product

In this study, deposition conditions for making a‐SiO_x:H are investigated systematically in order to obtain a high band gap material. We found that at given optical band gap, a‐SiO_x:H with favorable opto‐electronic properties can be obtained when deposited using low CO₂ flow rates and deposition pressures. We also found that a low radio frequency power density is required in order to limit the effect of ion bombardment on the material properties of i‐a‐SiO_x:H and thereby the solar cell performance. In addition, by decreasing the heater temperature from 300 to 200°C when making the i‐a‐SiO_x:H, the V_oc can be increased. We employed optimized p‐doped and n‐doped a‐SiO_x:H films into the p‐i‐n solar cells, and as a consequence, a high V_oc of over 1 V and high fill factor (FF) are obtained. When depositing on texture‐etched ZnO:Al substrates, a high efficiency a‐SiO_x:H single junction solar cell having a high V_oc × FF product of 0.761 (V_oc: 1.042 V, J_sc: 10.3 mA/cm², FF: 0.73, efficiency: 7.83%) was obtained. The a‐SiO_x:H solar cell shows comparable light degradation characteristics to standard a‐Si:H solar cells. Copyright © 2014 John Wiley & Sons, Ltd.     

Reconfigurable digital controller for a buck converter based on FPGA

This paper presents a complete digitally controlled dc–dc buck converter performed by FPGA circuitry. All tasks, analog to digital conversion, control algorithm and pulse width modulation, were implemented in the FPGA. This approach enables high-speed dynamic response and programmability by the controller, without external passive components. In addition, the controller’s structure can be easily changed without external components. The applied algorithm enables a switching frequency of 100 kHz.     

Improved frequency characteristics of the randomized PWM boost rectifier

A randomized pulse width modulation (RPWM) algorithm is applied in the control unit of the boost rectifier to achieve improved frequency characteristics in the wide band. First, the introduction of the RPWM switching is reflected in a smaller increase of the total harmonic distortion (THD) factor in the input current. Nevertheless, decrease of the power factor is negligibly small. Second, the power spectrum density (PSD) of the input current is estimated and measured to evaluate the influence of randomization in the high-frequency range. This approach offers an effective and credible prediction method for reduction of conductive electromagnetic interference (EMI) by using the RPWM switching.     

Kinetics, acid sites and deactivation of H-mordenite during the SCR of NOx with CH4

H-mordenites are active for the SCR reaction but they suffer irreversible partial deactivation after being on stream for one hour at 650°C. The reaction orders and activation energies are not significantly affected by deactivation. This indicates that deactivation originates in a decrease in the number of active sites due to dealumination and possible pore blockage. The NO disappearance rate correlates with TPD NH₃ between 300 and 700°C; FTIR confirms these results. ¹²⁹Xe NMR of adsorbed xenon shows that pore blockage occurs and is due to the presence of aluminum species in the main zeolite channels. The overall deactivation process and the role of acid sites is discussed in terms of the current literature. This revised version was published online in July 2006 with corrections to the Cover Date.     

High-temperature dielectric response of ferroelectric relaxors

It has long been considered that polar nanoregions in relaxors form at Burns temperature T(d) ≈ 600K. High-temperature dielectric investigations of Pb(Mg(1/3)Nb(2/3)) O(3) (PMN) single crystal, PMN-PbTiO(3) ceramics, and (Pb,La) (Zr,Ti)O(3) ceramics reveal, however, that dielectric dispersion, detected around 600K, is due to the Maxwell-Wagner-type contributions of surface layers. The intrinsic response was analyzed in terms of the universal scaling, taking into account the asymptotic and the correction-to-scaling behavior, and the results imply much higher T(d) or formation of polar nanoregions in a broad temperature range. High values of the dielectric constant indicate, however, that polar order already exists at the highest measured temperatures of 800K. The obtained critical exponents indicate critical behavior associated with universality classes typically found in spin glasses.     

Use of 2,4-Dihydroxybenzophenone-2‘-ammonium Sulphonate to Prevent the Yellowing of Wool by Ultraviolet Radiation

The use of 2,4-dihydroxybenzophenone-2′-ammonium sulphonate (das) to prevent the yellowing of wool by ultraviolet radiation is discussed. The optimum conditions of application of this absorber to wool have been determined. The Yellowness Index, a measure of the degree of yellowing, was used to determine the effect of the concentration of das on its protective action against ultraviolet radiation. Exposure in a Xenotest apparatus indicated that initially bleaching occurred, followed by yellowing, which decreased with increase in the concentration of das. The washing and dry-cleaning fastness properties of das on wool were assessed and the effect of dye on these properties was also determined, das has poor washing fastness, but this can be improved by mordanting the wool before treatment with das. This absorber does not significantly improve the light fastness of acid dyes on wool.     

Waterbody mapping: a comparison of remotely sensed and GIS open data sources

Surface water maps are essential for many environmental applications. Waterbody delineation from satellite images remains a challenging task due to sensor limitations, the presence of clouds, the low albedo surfaces in urban areas, topographic, and atmospheric conditions. In this paper, a model based on the Supported Vector Machine (SVM) classifier was adopted for waterbody extraction from Sentinel-2, Landsat 8 Operational Land Imager (OLI) and RapidEye satellite images. As well, the accuracy of two other sources (OpenStreetMapping (OSM) and Military Geographic Institute (MGI)) was tested. The free images from Sentinel-2 and Landsat 8 OLI were more accurate (Kappa (KHAT):0.89, 0.88) data sources than commercial RapidEye images (KHAT: 0.79). Regarding the performance between Sentinel-2 and Landsat 8 OLI, Sentinel-2 obtained the most accurate results (overall accuracy 94.49 vs. 94.17, commission error 1.34 vs. 1.87). Due to the variable spatial resolution of OSM and MGI data, it was not possible to detect small waterbodies with these sources, and therefore high values of omission error and a strong underestimation of the area of surface water were obtained. This study demonstrates the suitability of free images for mapping and monitoring of surface waterbodies, including small water bodies.