Inside Front Cover: The Elastic Properties and Plastic Behavior of Two‐Dimensional Polymer Structures Fabricated by Laser Interference Lithography (Adv. Funct. Mater. 10/2006)

The probing of the micromechanical properties within a two‐dimensional polymer structure with sixfold symmetry fabricated via interference lithography reveals a nonuniform spatial distribution in the elastic modulus “imprinted” with an interference pattern in work reported by Tsukruk, Thomas, and co‐workers on p. 1324. The image prepared by M. Lemieux and T. Gorishnyy shows how the interference pattern is formed by three laser beams and is transferred to the solid polymer structure. The elastic and plastic properties within a two‐dimensional polymer (SU8) structure with sixfold symmetry fabricated via interference lithography are presented. There is a nonuniform spatial distribution in the elastic modulus, with a higher elastic modulus obtained for nodes (brightest regions in the laser interference pattern) and a lower elastic modulus for beams (darkest regions in the laser interference pattern) of the photopatterned films. We suggest that such a nonuniformity and unusual plastic behavior are related to the variable material properties “imprinted” by the interference pattern.     

The electrochemical behaviour of nitrogen-containing austenitic stainless steel in methanolic solution

The corrosion behaviour of nitrogen-containing austenitic stainless steel in methanol containing different concentrations of H₂SO₄, HCl, LiCl and H₂SO₄ + HCl has been investigated using a potentiostatic polarization method. The cathodic reaction in the H₂SO₄, HCl and H₂SO₄ + HCl solutions was proton reduction whereas in the neutral LiCl solution, oxygen reduction was the predominant cathodic reaction. Active, passive and transpassive behaviours were observed only for higher concentrations of H₂SO₄ (0.01–2.0 M) due to the inherent water content. A cathodic loop, characterized by measured negative current in the anodic region, was also observed in solutions, in which the concentration of H₂SO₄ was 1.0 M or higher. The relative stability of the passive films decreased as the H₂SO₄ concentration increased, and thus the steel suffered from mild pitting corrosion. In the chloride environment, the rate of corrosion increased as the Cl⁻ ion concentration increased. The presence of acid along with Cl⁻ ions enhanced corrosion, and the corrosion rate increased significantly. The steel suffered from mild intergranular corrosion in acidic chloride solutions of methanol. In the H₂SO₄ + HCl solutions, passive films were only formed when the H₂SO₄ to HCl concentration ratio was greater than ∼10:1.     

The effects of a “distinct window” screen design on computer-mediated group decision making

An experiment was performed to test a distinct-window conferencing screen design as an electronic cue of social status differences in computer-mediated group decision-making. The screen design included one distinct window to symbolize high-status, and two nondistinct windows to symbolize low-status. The results indicated that the distinct-window screen design did produce status affects in groups of peers making decisions on judgmental problems. Randomly assigned occupants of the distinct window had greater influence on group decisions and member's attitudes than occupants of nondistinct windows.The authors would like to thank Shyam Kamadolli and Phaderm Nangsue, the programmers who developed the software used in this experiment. We would also like to thank the editor and our three anonymous reviewers for exceedingly helpful comments on an earlier draft of this article.     

Shape control of multivalent 3D colloidal particles via interference lithography

We present a new route for the fabrication of highly nonspherical complex multivalent submicron particles. This technique exploits the ability of holographic interference lithography to control geometrical elements such as symmetry and volume fraction in 3D lattices on the submicron scale. Colloidal particles with prescribed complex concave shapes are obtained by cleaving low volume fraction connected structures fabricated by interference lithography. Controlling which Wyckoff sites in the space group of the parent structure are connected assures specific "valencies" of the particles. Two types of particles, 2D "4-valent" and 3D "6-valent" particles are fabricated via this technique. In addition to being able to control multivalent particle shape, this technique has the potential to provide tight control over size, yield, and dispersity.     

Anti-embolism stockings,the similarities and differences

The medical textiles sector is growing annually, estimated to reach $2.7 billion by 2018. Predominantly attributed to the growing and ageing population, and consequently there has been a vast increase in venous disorders. Currently 61% of the British population are thought to be at risk of deep vein thrombosis (DVT), of which the majority is avoidable given the correct prophylaxis. Anti-embolism stockings (AES) are used to prevent DVT when hospitalised patients are supine for long periods of time. The market place is competitive, with numerous brands striving to win the local British National Health Service contract. It is a commodity market, with low profit margins but high volumes. The aim of this research was to seek an understanding of the AES on the market, exploring the different construction techniques, knit notations and yarn characteristics in three popular AES brands, with the overall aim of providing a basis of knowledge to improve product development, product efficacy and ultimately save lives.     

Effect of microwave treatment on the cooking and macronutrient qualities of pulses

The effect of microwave treatment to reduce the cooking times of five pulses, namely red lentil, chickpea, pigeon pea, mung bean, and pinto bean, were determined in this study. Pulses from 10 to 18% moisture contents were treated using 400 to 600 W microwaves for 14 to 56 s. The cooking times of microwave-treated pulses were significantly lower than that of the control samples. The lowest cooking time was observed for 18% moisture content chickpea and pigeon pea treated with 600 W for 56 s. The Fourier transform mid-infrared spectra in both lipids and fingerprint regions showed the macronutrients differences among the five pulses. Major changes were observed in the amide I region of microwave treated pulses. This effect of microwave treatment was higher in red lentil, chickpea, and mung bean than in pigeon pea and pinto bean at 10% moisture content. At 18% moisture content, the change of β-sheets to aggregates was observed in all pulses due to microwave treatment.     

The Elastic Properties and Plastic Behavior of Two‐Dimensional Polymer Structures Fabricated by Laser Interference Lithography

The elastic and plastic properties within a two‐dimensional polymer (SU8) structure with sixfold symmetry fabricated via interference lithography are presented. There is a nonuniform spatial distribution in the elastic modulus, with a higher elastic modulus obtained for nodes (brightest regions in the laser interference pattern) and a lower elastic modulus for beams (darkest regions in the laser interference pattern) of the photopatterned films. We suggest that such a nonuniformity and unusual plastic behavior are related to the variable material properties “imprinted” by the interference pattern.     

Effect of CdCl2 treatment on physical properties of CdTe films with different compositions fabricated by chemical molecular beam deposition

CdTe films with different compositions (Cd-rich, Te-rich and stoichiometric) were fabricated by revolutionary novel and low cost chemical molecular beam deposition (CMBD) method in the atmospheric pressure hydrogen flow. Cd and Te granules were used as precursors. The films were deposited on ceramic (SiO₂: Al₂O₃) substrates at 600°C. The growth rate was varied in the range of 20–30 Å/s. The composition of the samples was changed by controlling the molecular beam intensity (MBI) ratio Cd/Te. Effect of CdCl₂ treatment on morphology, photoluminescence and electrical properties of CdTe films was investigated by AFM, Raman, photoluminescence (PL) and Hall methods.