Journal of Materials Science - Chitosan is one of the natural cationic polymers with unique properties such as non-toxicity, biodegradability, biocompatibility, environmentally friendly that has... 相似文献
Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction. 相似文献
Silicon - Nano-crystalline powders of Zn1−xCoxO with $\left (0.0\le x\le 0.07 \right )$ have been synthesized by sol-gel method. X-ray diffraction patterns of the prepared samples confirm the... 相似文献
Successful melting and Mg treatment were conducted using a vortex unit which produced spheroidal graphite (SG) Fe ingots having a percentage carbon equivalent (%CE) ranging from 3.782 to 5.240. Microstructure examination revealed graphite nodules embedded in a white matrix (unetched condition). The variation of %CE proved to have a pronounced effect on the nodule characteristics. The nodule count showed a maximum value at %CE of 4.613. For metal-mould ingots it reached a value of 1584 nodules mm–2, while for sand-mould ingots it reached a value of 970 nodules mm–2. Nodule size was found to be inversely proportional to the nodule count for both sand- and metal-mould ingots. The nodularity of all ingots was, in general, higher than 95%. The density of SG Fe was found to decrease gradually (at %CE=3.782) from 7242 to 6969 kg m–3. The modulus of elasticity (E) showed a boat-like curve having minimum values of 189 and 192 GPa for the sand and metal moulds, respectively. 相似文献
A roll-coating experimental system is used to study the effect of pre-wetting on dynamic contact angles, the interfacial displacement depth, and the associated phenomenon of air entrainment. The system consists of a roll, which is horizontally rotating in a liquid pool. The dynamic contact angle is recorded by a macrophotography system. The test liquids are glycerol solutions with viscosities in the range 104 < μ < 748 mPa · s. The value of (μV/ρg)0.5 is taken as the characteristic length to be used in the dimensionless relationships which correlate experimental measurements. The effect of base layer entry angle into the liquid pool on the dynamic contact angles and other flow parameters is studied. Comparison is made with measurements in dry tape-coating and other pre-wet roll–coating systems. 相似文献
For environmental considerations, the substitution of the conventionally used oil-based grinding fluids has nowadays become strongly recommended. Although several alternatives have been proposed, cryogenic cooling by liquid nitrogen is the non-polluting coolant that has been given relatively more attention because of its very low temperature. In this investigation, in order to contribute to developing this promising cooling mode, its beneficial effects on the ground surface integrity of the AISI 304 stainless steel and their consequences on the fatigue lifetime are explored. Results of this investigation show that grinding under cryogenic cooling mode generates surfaces with lower roughness, less defects, higher work hardening and less tensile residual stresses than those obtained on surfaces ground under oil-based grinding fluid. These surface enhancements result into substantial improvements in the fatigue behaviour of components ground under this cooling mode. An increasing rate of almost 15% of the endurance limit at 2 × 106 cycles could be realized. SEM analyses of the fatigue fracture surfaces have shown that the fatigue cracks observed on the specimens ground under cryogenic cooling are shorter (i.e., 30-50 μm) than those generated under oil-based cooling mode (i.e., 150-200 μm). The realized improvements in the surface integrity and in the fatigue behaviour are thought to be related to the reduction of the grinding zone temperature observed under cryogenic cooling, as no significant differences between the grinding force components for both cooling modes have been observed. 相似文献
Volleyball premier league (VPL) simulating some phenomena of volleyball game has been presented recently. This powerful algorithm uses such racing and interplays between teams within a season. Furthermore, the algorithm imitates the coaching procedure within a game. Therefore, some volleyball metaphors, including substitution, coaching, and learning, are used to find a better solution prepared by the VPL algorithm. However, the learning phase has the largest effect on the performance of the VPL algorithm, in which this phase can lead to making the VPL stuck in optimal local solution. Therefore, this paper proposed a modified VPL using sine cosine algorithm (SCA). In which the SCA operators have been applied in the learning phase to obtain a more accurate solution. So, we have used SCA operators in VPL to grasp their advantages resulting in a more efficient approach for finding the optimal solution of the optimization problem and avoid the limitations of the traditional VPL algorithm. The propounded VPLSCA algorithm is tested on the 25 functions. The results captured by the VPLSCA have been compared with other metaheuristic algorithms such as cuckoo search, social-spider optimization algorithm, ant lion optimizer, grey wolf optimizer, salp swarm algorithm, whale optimization algorithm, moth flame optimization, artificial bee colony, SCA, and VPL. Furthermore, the three typical optimization problems in the field of designing engineering have been solved using the VPLSCA. According to the obtained results, the proposed algorithm shows very reasonable and promising results compared to others.
The microstructure and mechanical properties of modified and non-modified stir-cast commercial aluminium alloys A-S7G03 and A-S4G have been investigated. Stir casting of these alloys resulted in spherical and/or rosette shape primary -phase, and the eutectic silicon was broken into miniature needle morphology. This stir-cast structure slightly improved the mechanical properties in comparison to those of conventionally cast alloys, however the fracture of the stir-cast alloys revealed intergranular brittle fracture. The addition of 0.02% strontium, in the form of Al-5 mass% Sr master alloy, during stir casting modified the eutectic silicon into a very fine spheroidal morphology, while the -phase particle showed the same morphology as the stir-cast alloys. This novel structure resulted in significant improvement of mechanical properties. The elongation of the modified stir-cast alloys was five times greater than that of the non-modified one. A transgranular mode of fracture was observed for the modified stircast alloys, moreover smooth ripple and dimple patterns were observed reflecting the high ductility of the modified stir-cast alloys. 相似文献