Oxidation of methane to formaldehyde over Fe/SiO2 and Sn---W mixed oxides

In an attempt to develop new catalysts for the formation of formaldehyde from methane, the promotion effect of Fe on SiO₂ and that of Sn on WO₃ have been studied. The formation of formaldehyde on silica can be appreciably enhanced by the impregnation of Fe, as far as iron loadings are kept below 0.1 atom.% (Fe/Si × 100). In the case of Sn---W---Ox catalysts, both the addition of Sn to WO₃, and that of W on SnO₂ were effective to the selective formaldehyde formation. Absorption spectra (UV-Vis) and ESR measurements revealed that tetrahedrally coordinated Fe³⁺ in the silica network plays an important role in the formation of formaldehyde. A thin surface layer consisting of W and Sn oxides can account for the selective formaldehyde formation on the Sn---W---Ox catalysts.     

Oxidation behavior of TiAl coated with a fine-grain Co-30Cr-4Al film

The oxidation behavior of TiAl coupons coated with a fine-grain Co-30Cr-4Al (mass %) film of about 30-m thickness has been studied at 1100–1400 K in a flow of purified oxygen at atmospheric pressure for up to 500 ks. Three oxidation stages were recognized: initial transient, parabolic, and accelerated stages. However, at 1100 K a parabolic stage continues for more than 800 ks. The activation energy for parabolic oxidation agrees with reported values for the oxidation of alumina-former alloys, although the mass gains during the parabolic stages are relatively small at 1200 and 1300 K. Micropores developed mainly at the scale/coating and coating/substrate interfaces as oxidation proceeded. This is attributable to recrystallization of the coating during oxidation and a Kirkendall effect due to preferential diffusion of Co into the substrate. The accelerated oxidation can be explained in terms of the formation of rutile mounds on the scale.     

Finite element polycrystal model simulation of cold rolling textures in deformation processed two-phase Nb／Al metal-metal composites

The finite element polyerystal model (FEPM) was extended and applied to simulate the development of the cold rolling textures of matrix aluminum in deformation processed two-phase 10% and 20% Nb/Al(in volume fraction) metal-metal composites on the basis of slip deformation of individual grains. This simulation method can assure the continuity of stress and displacement at the boundary during heterogeneous deformation and take arbitrary boundary conditions into consideration. The starting hot-extruded textures, as initial input condition, were taken into account in the FEPM simulation. The simulation results show that the main texture components and their evolution after various cold rolling reductions in 10% and 20% Nb/Al metal-metal composites are well qualitatively in agreement with the experimental ones. The initially extruded textures are rather weak, so they have no much influence on the simulated final cold rolling textures of the matrix aluminum for Nb/Al composites.     

Mechanical properties of porous titanium compacts prepared by powder sintering

Porous Ti compacts for biomedical applications are successfully fabricated in the porosity range from 5.0 to 37.1 vol% by controlling sintering conditions and Ti powder sizes. Young’s modulus and bending strength at the porosity of around 30 vol% are found to be similar to those of human cortical bone.     

An approximation algorithm dependent on edge-coloring number for minimum maximal matching problem

We consider the minimum maximal matching problem, which is NP-hard (Yannakakis and Gavril (1980) [18]). Given an unweighted simple graph G=(V,E), the problem seeks to find a maximal matching of minimum cardinality. It was unknown whether there exists a non-trivial approximation algorithm whose approximation ratio is less than 2 for any simple graph. Recently, Z. Gotthilf et al. (2008) [5] presented a -approximation algorithm, where c is an arbitrary constant.In this paper, we present a -approximation algorithm based on an LP relaxation, where χ^′(G) is the edge-coloring number of G. Our algorithm is the first non-trivial approximation algorithm whose approximation ratio is independent of |V|. Moreover, it is known that the minimum maximal matching problem is equivalent to the edge dominating set problem. Therefore, the edge dominating set problem is also -approximable. From edge-coloring theory, the approximation ratio of our algorithm is , where Δ(G) represents the maximum degree of G. In our algorithm, an LP formulation for the edge dominating set problem is used. Fujito and Nagamochi (2002) [4] showed the integrality gap of the LP formulation for bipartite graphs is at least . Moreover, χ^′(G) is Δ(G) for bipartite graphs. Thus, as far as an approximation algorithm for the minimum maximal matching problem uses the LP formulation, we believe our result is the best possible.     

A systolic algorithm for Euclidean distance transform

The Euclidean distance transform is one of the fundamental operations in image processing. It has been widely used in computer vision, pattern recognition, morphological filtering, and robotics. This paper proposes a systolic algorithm that computes the Euclidean distance map of an N /spl times/ N binary image in 3N clocks on 2N/sup 2/ processing cells. The algorithm is designed so that the hardware resources are reduced; especially no multipliers are used and, thus, it facilitates VLSI implementation.     

Calculations from texture of earing in deep drawing for FCC metal sheets

The present study aims to calculate the height at each peripheral position of a cup drawn from polycrystalline sheet using texture data. In the analytical treatment the polycrystalline sheet is simplified to an aggregation of many single crystals with various orientations, and the texture is represented by a three-dimensional crystallite orientation distribution function. The ear is calculated crystallographically using the orientation distribution function as a volume fraction of a certain oriented crystal. In the experiment aluminium, Al-Mg alloy and copper sheets which are treated under various conditions of cold rolling and heat treatment are used. The average textures over the thicknesses of the sheets are measured by the Schulz reflection method. The calculated ears based on the measured textures are compared with the experimental ears for each material. The results show that all the principal features of the ears of drawn cups are predicted satisfactorily by the calculation.     

A control law for vehicle merging inspired by dragonfly behavior

Autonomous control of vehicles has recently attracted considerable attention. In this sense, vehicle merging has become an important topic in this field of research. However, in conventional studies, the controlled vehicle must calculate the movement of other surrounding vehicles to complete the merge, requiring high computational costs. In this paper, we focus on dragonfly behavior to solve this issue. Indeed, insects can behave adaptively in the complex real world in spite of the limited size of their brains. They reduce the computational requirements of their brain by relying on different properties of their surroundings, basing their intelligent behaviors on simple strategies. The behavior of a dragonfly when chasing a prey is an example of these strategies. In this study, we address the vehicle merging maneuver by applying dragonfly’s strategies to control the movement of the merging vehicle. We propose a simple control method inspired by the aforementioned strategies and, finally, we present simulation results that were conducted to demonstrate the effectiveness of this method.     

Nickel‐Catalyzed Suzuki–Miyaura Coupling of a Tertiary Iodocyclopropane with Wide Boronic Acid Substrate Scope: Coupling Reaction Outcome Depends on Radical Species Stability

We describe a nickel‐catalyzed Suzuki–Miyaura arylation of a tertiary iodocyclopropane with arylboronic acids; this is an efficient and convergent strategy for providing various enantioenriched arylcyclopropanes with a quaternary stereogenic center. This is the first metal‐catalyzed coupling between a tertiary alkyl electrophile and a wide range of aromatics, including heteroaromatics. We found that the outcome of the Ni‐catalyzed coupling with halides as electrophiles was dependent on the stability of the radical species formed during the reaction. The use of tert‐butyl alcohol (t‐BuOH) as the reaction solvent was very effective, because of its stability under the radical‐generating reaction conditions.

     

Spray-dry synthesis of β-Cu1.8Zn0.2V2O7 ceramic fine particles showing giant negative thermal expansion

We used spray-dry method to synthesize fine powder of β-Cu_1.8Zn_0.2V₂O₇ showing large negative thermal expansion (NTE) linearly to temperature over a wide temperature range. The NTE of β-Cu_1.8Zn_0.2V₂O₇ is produced by microstructures consisting of voids and anisotropic thermal deformation of crystal grains in ceramics. By reducing the size of the microstructures that produce NTE, large NTE equivalent to that of bulk was realized, even for ceramic particles of about 2 μm size. Comparison with particles produced using a conventional method demonstrates that the particle size distribution is narrow and that the particles are nearly spherical. This achievement is expected to pave the way to use of NTE materials in micrometer-scale control of thermal expansion.