New approach to unsupported ReS2 nanorod catalyst for upgrading of heavy crude oil using methane as hydrogen source

Highly active ReS₂ nanocatalysts were prepared by CVD method and characterized by XRD, BET -BJH, Raman spectroscopy, XPS, TPR, NH₃-TPD, SEM, and HRTEM techniques. Catalytic activities were used in upgrading heavy crude oil using methane as hydrogen source. The results showed a significant increase in API and decrease in sulfur and nitrogen content of crude oil. RSM technique was used to investigate the interactive effects of temperature (200–400 °C), pressure (20–40 bar) and dosage of nanocatalyst (0.5–2 wt. %) on the performance of HDS reaction. The results represent that the maximum predicted HDS activity (74.375%) was estimated under the optimal conditions (400 °C, 20 bars, and 2 wt % of nanocatalyst). Also, the effect of reaction temperature, pressure and dosage of ReS₂ nanorods catalyst on HDN of heavy crude oil was investigated and highest efficiency in the HDN process (93%) occurred at 400 °C and 40 bar using 2 wt % ReS₂.     

Fuzzy logic controller and cascade inverter for direct torque control of IM

In this paper, a five-level cascaded H-bridge multilevel inverters topology is applied on induction motor control known as direct torque control (DTC) strategy. More inverter states can be generated by a five-level inverter which improves voltage selection capability. This paper also introduces two different control methods to select the appropriate output voltage vector for reducing the torque and flux error to zero. The first is based on the conventional DTC scheme using a pair of hysteresis comparators and look up table to select the output voltage vector for controlling the torque and flux. The second is based on a new fuzzy logic controller using Sugeno as the inference method to select the output voltage vector by replacing the hysteresis comparators and lookup table in the conventional DTC, to which the results show more reduction in torque ripple and feasibility of smooth stator current. By using Matlab/Simulink, it is verified that using five-level inverter in DTC drive can reduce the torque ripple in comparison with conventional DTC, and further torque ripple reduction is obtained by applying fuzzy logic controller. The simulation results have also verified that using a fuzzy controller instead of a hysteresis controller has resulted in reduction in the flux ripples significantly as well as reduces the total harmonic distortion of the stator current to below 4 %.     

Mechanical characterization and modeling stress relaxation behavior of acrylic–polyurethane-based graft-interpenetrating polymer networks

The stress relaxation behavior of acrylic–polyurethane (PU)-based graft-interpenetrating polymer networks (IPNs) was characterized via dynamic mechanical analysis (DMA) and modeled using finite element method (FEM) analysis. Stress relaxation of glassy IPN specimens was experimentally studied under flexural testing, while rubbery IPN specimens were tested in tension. The effects of varying the styrene content in the acrylic copolymer phase, compatibility of the two phases in IPNs, and changing the concentration of acrylic copolymer and PU were studied. A higher percentage of styrene content resulted in higher homogeneity of IPN specimens, and decrease in initial modulus for acrylic copolymer specimens. Additionally, glassy IPN specimens with 90% styrene shows resistance to relaxation as high as acrylic copolymer samples. Experimental results were used to develop a numerical model to study stress relaxation response of specimens. While polymer systems have been studied computationally, numerical modeling of IPN systems is still in its infancy. A three-dimensional FEM model was developed using the Generalized Maxwell model and four-term Prony series constants, which were extracted from the stress relaxation experiments. With four terms in the Prony series, a good match was observed between experimental observations and results from the FEM model.     

Improving fairness in IEEE 802.11 networks using MAC layer opportunistic retransmission

This paper introduces DAFMAC (Decode And Forward MAC), a scalable opportunistic cooperative retransmission enhancement for the IEEE 802.11 MAC protocol which operates without the need for additional explicit control signalling. Distributed opportunistic retransmission algorithms rely on selecting a single suitable relay without direct arbitration between nodes. Simulations show that DAFMAC offers a significant improvement in fairness for both throughput and jitter, giving multiple parallel data flows a more equal opportunity to utilise the channel. DAFMAC cooperative retransmissions are shown to reduce node energy consumption for a given throughput. Further, the DAFMAC relay selection algorithm is shown to scale very well in terms of complexity and memory requirements in comparison to other cooperative retransmission schemes.     

Concept learning games

In this paper, we intend to have a game theoretic study on the concept learning problem in a multi-agent system. Concept learning is a very essential and well-studied domain of machine learning when it is studied under the characteristics of a multi-agent system. The most important reasons are the partiality of the environment perception for any agent and also the communication holdbacks, resulting into a deep need for a collaborative protocol in favor of multi-agent transactions. Here we wish to investigate multi-agent concept learning with the help of its components, thoroughly with a game theoretic taste, esp. on the pre-learning processes. Based on two standard notations, we address the non-unanimity of concepts, classification of objects, voting and communicating protocol, and also the learning itself. In such a game of concept learning, we consider a group of agents, communicating and consulting to upgrade their ontologies based on their conceptualizations of the environment. For this purpose, we investigate the problem in two separate and standard distinctions of game theory study, cooperation and competition. Several solution concepts and innovative ideas from the multi-agent realm are used to produce an approach that contains the reasoning process of the agents in this system. Some experimentations come at the end to show the functionality of our approach. These experimentations come distinctly for both cooperative and competitive views.     

A Fuzzy Logic-Based Method for Replica Placement in the Peer to Peer Cloud Using an Optimization Algorithm

The Peer to Peer-Cloud (P2P-Cloud) is a suitable alternative to distributed cloud-based or peer-to-peer (P2P)-based content on a large scale. The P2P-Cloud is used in many applications such as IPTV, Video-On-Demand, and so on. In the P2P-Cloud network, overload is a common problem during overcrowds. If a node receives many requests simultaneously, the node may not be able to respond quickly to user requests, and this access latency in P2P-Cloud networks is a major problem for their users. The replication method in P2P-Cloud environments reduces the time to access and uses network bandwidth by making multiple data copies in diverse locations. The replication improves access to the information and increases the reliability of the system. The data replication's main problem is identifying the best possible placement of replica data nodes based on user requests for data access time and an NP-hard optimization problem. This paper proposes a new replica replacement to improve average access time and replica cost using fuzzy logic and Ant Colony Optimization algorithm. Ants can find the shortest path to discover the optimal node to place the duplicate file with the least access time latency. The fuzzy module evaluates the historical information of each node to analyze the pheromone value per iteration. The fuzzy membership function is also used to determine each node's degree based on the four characteristics. The simulation results showed that the access time and replica cost are improved compared to other replica replacement algorithms.

     

Colloidal Quantum Dot Infrared Lasers Featuring Sub-Single-Exciton Threshold and Very High Gain

The use of colloidal quantum dots (CQDs) as a gain medium in infrared laser devices has been underpinned by the need for high pumping intensities, very short gain lifetimes, and low gain coefficients. Here, PbS/PbSSe core/alloyed-shell CQDs are employed as an infrared gain medium that results in highly suppressed Auger recombination with a lifetime of 485 ps, lowering the amplified spontaneous emission (ASE) threshold down to 300 µJ cm⁻², and showing a record high net modal gain coefficient of 2180 cm⁻¹. By doping these engineered core/shell CQDs up to nearly filling the first excited state, a significant reduction of optical gain threshold is demonstrated, measured by transient absorption, to an average-exciton population-per-dot 〈N^th〉_g of 0.45 due to bleaching of the ground state absorption. This in turn have led to a fivefold reduction in ASE threshold at 〈N^th〉_ASE = 0.70 excitons-per-dot, associated with a gain lifetime of 280 ps. Finally, these heterostructured QDs are used to achieve near-infrared lasing at 1670 nm at a pump fluences corresponding to sub-single-exciton-per-dot threshold (〈N^th〉_Las = 0.87). This work brings infrared CQD lasing thresholds on par to their visible counterparts, and paves the way toward solution-processed infrared laser diodes.     

Designing a fuzzy system for controlling the armament fire in dynamic siege

This paper presents a fuzzy system for controlling the fire command in a surface-to-surface engagement by assuming siege of friendly side by enemy forces. The system must be capable of interacting with a dynamic and uncertain battle world in a real-time manner. In siege situation, it is assumed that the enemy troops are advancing toward friendly side in different directions and the defence resources are limited and nonrenewable at a single platform. Thus, resource allocation problem in a real-time manner is an important and vital component of battle management until coming of auxiliary forces. This paper addresses the design of a fuzzy system as an efficient tool for real-time decision-making in order to optimize the defense resource allocation in engagement.     

Disturbance and recovery of trunk mechanical and neuromuscular behaviours following prolonged trunk flexion: influences of duration and external load on creep-induced effects

Trunk flexion results in adverse mechanical effects on the spine and is associated with a higher incidence of low back pain. To examine the effects of creep deformation on trunk behaviours, participants were exposed to full trunk flexion in several combinations of exposure duration and external load. Trunk mechanical and neuromuscular behaviours were obtained pre- and post-exposure and during recovery using sudden perturbations. Intrinsic trunk stiffness decreased with increasing flexion duration and in the presence of the external load. Recovery of intrinsic stiffness required more time than the exposure duration and was influenced by exposure duration. Reflexive trunk responses increased immediately following exposure but recovered quickly (～2.5 min). Alterations in reflexive trunk behaviour following creep deformation exposures may not provide adequate compensation to allow for complete recovery of concurrent reductions in intrinsic stiffness, which may increase the risk of injury due to spinal instability. STATEMENT OF RELEVANCE: An increased risk of low back injury may result from flexion-induced disturbances to trunk behaviours. Such effects, however, appear to depend on the type of flexion exposure, and have implications for the design of work involving trunk flexion.     

Corrosion control in underground concrete structures using double waterproofing shield system (DWS)

High level of structural and waterproofing stability leads to long-term service life in underground infrastructures. Interaction between aggressive groundwater with tunnel causes corrosion and damage in concrete structure due to steel reinforcement corrosion and concrete cracks. This study introduces a double waterproofing shield system (DWS) as an innovative solution to waterproofing and structural failures in underground concrete structures. In this method, ordinary shotcrete mixture replaces by an organic polymer concrete (OPC) to construct a water-resistant temporary support right after each partial excavation. Two groups of specimens including reference concrete and OPC specimens were provided and tested in accordance with ASTM C 642. Waterproofing parameters including porosity, pore volume, permeability and hydraulic conductivity have been determined. Results show a remarkable reduction in mentioned parameters for OPC compared with ordinary concrete. Improvement in waterproofing performance of temporary support corresponds to a healthy final lining and increase in service life of the structure.