Doped/Undoped A1-A2 Typed Copolymers as ETLs for Highly Efficient Organic Solar Cells

The electron transport layer (ETL) is a critical component in achieving high device performance and stability in organic solar cells. Conjugated polyelectrolytes (CPEs) have become an attractive alternative due to film-forming properties and ease of preparation. However, p-type CPEs generally exhibit poor charge mobility and conductivity, incorporation of electron-withdrawing units forming alternated D-A conjugated backbone can make up for these deficiencies. Herein, the ratio of electron withdrawing moieties are further increased and two poly(A1-alt-A2) typed PIIDNDI-Br and PDPPNDI-Br based on the combination of naphthalene diimide (NDI) with isoindigo (IID) or diketopyrrolopyrrole (DPP) via direct arylation polycondensation are synthesized. These CPEs possess excellent alcohol solubility, a suitable lowest unocuppied molecular orbital energy level, and work function tunability. Surprisingly, the incorporation of IID and DPP units generate distinct self-doping behaviors, which are confirmed by UV–vis absorption and ESR spectra. However, no matter doped or undoped, both CPEs present better charge-transporting properties and conductivity when utilized as ETLs. The PIIDNDI-Br and PDPPNDI-Br display good universal compatibility with the blend of PM6:Y6 and PM6:L8-BO, and PCEs of 18.32% and 18.36% are obtained, respectively, which also present excellent storage stability. In short, the combination of two different acceptors demonstrates an efficient strategy to design highly efficient ETLs for high performance photovoltaic devices.     

高精度加速度计串行数据读出系统研究

加速度计是惯性导航系统的核心部件,通常加速度计输出为模拟电流信号,为便于导航计算机的数字处理,需经过A/D、I/F或V/F转换。针对应用背景实时、高精度、宽动态范围的要求,本文采用高分辨率模数转换器和嵌入式现场可编程门阵列组成石英挠性加速度计串行数据读出系统,设计了系统的硬件和软件,测试结果表明,读出系统达到了量程±20g,测量精度万分之一,每秒输出40000个数据的目标。     

EFFECT OF HEAT-TREATMENT ON THE MECHANICAL PROPERTIES OF AIN/SICw(Y_2O_3+SiO_2)COMPOSITE

In the paper, the effect of heat-treatment on thestrength and toughness of AlN-SiC whisker composites with Y_2O_3+SiO_2 additives have been studied. When the sample contining 10wt%Y_2O_3+SiO_2(Y_2O_3/SiO_2=1/0. 66) was treated at 1330℃ in air for 140hours,the flexural strength of composites was raised from 481 MPa to784 MPa the toughness was also enhanced slightly. The phase composi-tion microstructure and grain boundary phase structure have been char-acterized by combining XDR, SEM, TEM/EDXA and HREM tech-niques. reinforcenent and toughening mechanism of the composites re-sults from the crystallization of glass phase in the grain boundary atthe high temperature oxidizing atmosphere to form the crossing struc-ture of 2H°sialon fibrous phase and SiC whisker     

基于人工神经网络水性涂料电脑配色(英文)

本文提出了一种基于多层BP人工神经网络的水性涂料电脑配色方法。实验表明,BP神经网络模型经训练后能够较好地反映水性涂料反射样本色度参数空间到配方参数空间的非线性映射关系。     

基于CIECAM02模型的均匀色貌空间研究

本文利用BFD-CP小色差评估数据构造色分辨椭圆和孟塞尔新标数据集检验的方法,对基于国际照明委员会2002年推荐的色貌模型CIECAM02的颜色空间进行均匀性分析,并用线性回归方法调整初始颜色空间明度、彩度坐标的量表,推导出新的均匀颜色空间。并再次利用构造色分辨椭圆的方法和孟塞尔新标数据集检验了CIECAM02原始空间和优化色貌空间的均匀性,分析和比较了两者的性能;本文利用线性优化新建的色貌空间取得了较理想的效果,新建的优化色貌空间Jab的均匀性与CIECAM02原始空间相比有了较大的提高。     

Panda型保偏光纤偏振轴检测技术

保偏光纤偏振轴的测定是保偏光纤应用中的关键技术。在基于图像处理的Panda型保偏光纤定轴系统中,针对应力圆边缘检测存在伪边缘造成应力圆圆心定位不准的问题,提出了一种基于最小二乘法改进的圆检测方法,通过检测到的圆参量计算阈值并剔除阈值范围外的边缘点,进行迭代拟合,迭代过程中圆参量不发生变化后停止迭代。实验结果表明:该方法可以很好地去除噪声和伪边缘对圆检测造成的干扰,并对真实Panda型保偏光纤端面图像的处理有较好的鲁棒性。     

Binary code compression algorithm used for the real time compensation of the modulation error in miniaturized FOG

This paper presents a kind of novel binary code compression algorithm to reduce the size of the signal processing circuit and to realize real time compensation for the modulation error in fiber optic gyroscope (FOG). The disadvantage of general compensation method is figured out firstly. The modulation error is modeled and analyzed with taking the closed-loop characteristics into consideration. The analysis indicates the condition in which the error compensation is effective and real time. Then the compensation algorithm based on binary code compression operation is described. The functional design of the algorithm is realized in a single field programmable gate array (FPGA) by using modular design method, substituting some harewares in signal processing circuit, and system speed is very fast. The simulation and experiment results suggest that the algorithm and implementation is valid. The modulation error is real time compensated in every error detection cycle, and the error compensation resolution is enhanced from 2⁻¹⁰ to 2⁻¹⁶ rad/V.     

Zn2+掺加的包覆型Fe2O3/SiO2颜料的制备及其呈色性能

包覆型Fe2 O3/SiO2颜料由于包覆完整性并不理想,该颜料高于800℃时呈色会产生变黑、变暗的问题.采用溶胶-凝胶法制备包覆型Fe2 O3/SiO2颜料,研究催化剂浓度、反应温度、硅/铁质量比等因素对包覆型Fe2 O3/SiO2颜料呈色性能的影响.在此基础上,通过掺加Zn2+,进行了Zn2+掺加的包覆型Fe2 O3...     

采用相关辨识的光纤陀螺动态特性测试方法

动态特性是光纤陀螺的一项重要技术指标,传统的机械转台无法提供测试条件.提出了一种基于相关辨识的光纤陀螺动态特性测试方法;根据全数字闭环光纤陀螺采用数字阶梯波反馈实现闭环控制的工作原理,通过在闭环反馈信号中叠加伪随机信号的方法来进行动态特性测试.将反馈阶梯波上叠加的伪随机信号作为辨识输入信号,光纤陀螺闭环数字输出作为辨识...     

空间用特种光纤的辐射致衰减效应

为了评估掺铒光纤、保偏光纤、单模纯硅芯光纤和多模纯硅芯光纤等特种光纤在空间辐射环境下的适应性,采用60Coγ辐射源模拟空间电离辐射环境对4种光纤进行了辐射致衰减效应测试,得到了光纤辐射致衰减与辐射剂量间的关系曲线.引入能带理论分析光纤的辐射效应机理,结合速率方程理论推得了光纤的辐射致衰减与辐射剂量间的多成份饱和指数模型...