Performance in computer-mediated work: the moderating role of level of automation

Cognition, Technology & Work - Organizations require good performance from individuals to achieve their objectives. In view of the growing presence of technology, it becomes necessary to...     

Phase transition characteristics and dielectric properties of rare-earth (La,Pr, Nd,Gd) doped Ba(Zr0.09Ti0.91)O3 ceramics

A-site deficient rare-earth doped barium zirconate titanate (BZT) ceramics (Ba_1−yLn_2y/3)Zr_0.09Ti_0.91O₃ (Ln = La, Pr, Nd, Gd) are obtained by a modified solid-state reaction method. Perovskite-like single-phase compounds were confirmed from X-ray diffraction data. Morphological analysis on sintered samples shows that the addition of rare-earth ions inhibits the growth of the grain and remarkably changes the grain morphology. The effect of rare-earth addition to BZT on phase transition and dielectric properties is analyzed. A dramatic fall in the transition temperature occurs when BZT ceramic is doped with rare-earths. Moreover, diffusivity degree of the phase transition increases and a relaxor-type behaviour is induced due to both the increment of the lanthanide content and the increase of the ionic radius of the dopant element. High values of dielectric tunability are obtained for lanthanum doped BZT. A direct relation between transition temperature and tunability is discussed. Conclusively, low permittivity and high tunability materials can be obtained by the adequate substitution of rare-earths into BZT ceramics.     

Inkjet Printed Nanopatterned Aptamer‐Based Sensors for Improved Optical Detection of Foodborne Pathogens

The increasing incidence of infectious outbreaks from contaminated food and water supply continues imposing a global burden for food safety, creating a market demand for on‐site, disposable, easy‐to‐use, and cost‐efficient devices. Despite of the rapid growth of biosensors field and the generation of breakthrough technologies, more than 80% of the platforms developed at lab‐scale never will get to meet the market. This work aims to provide a cost‐efficient, reliable, and repeatable approach for the detection of foodborne pathogens in real samples. For the first time an optimized inkjet printing platform is proposed taking advantage of a carefully controlled nanopatterning of novel carboxyl‐functionalized aptameric ink on a nitrocellulose substrate for the highly efficient detection of E. coli O157:H7 (25 colony forming units (CFU) mL^?1 in pure culture and 233 CFU mL^?1 in ground beef) demonstrating the ability to control the variation within ±1 SD for at least 75% of the data collected even at very low concentrations. From the best of the knowledge this work reports the lowest limit of detection of the state of the art for paper‐based optical detection of E. coli O157:H7, with enough evidence (p > 0.05) to prove its high specificity at genus, species, strain, and serotype level.     

Interleukin 1 (IL-1) and IL-1-receptor antagonist (IL-1-RA) in middle ear cholesteatoma: an analysis of protein production and biological activity

Cytokine networks are now presumed to play an essential role in the pathogenesis of middle ear cholesteatoma. Of the factors identified in cholesteatoma, interleukin-I (IL-1)-alpha appears to be especially important because of its stimulation of keratinocyte proliferation as well induction of bone resorption. To further characterize the possible role of IL-1 in the pathogenesis of cholesteatoma, we quantified the levels of IL-1 and IL-1-receptor antagonist (IL-1-RA) present using the bicinchonic acid protein assay and enzyme-linked immunosorbent assay (ELISA) on tissue extracts from 20 cholesteatoma specimens. The presence of biologically active IL-1 was also analyzed, using the cell line LBRM-33 and an ELISA for the detection of interleukin-2 (IL-2). Human skin obtained from the external ear canal was used as control. The amounts of IL-1-alpha in cholesteatoma (34.9 +/- 19.5) were higher than in human skin (6.7 +/- 2.8). The observed differences were statistically significant by Student's t-test (P < 0.01). Skin samples showed elevated concentrations of IL-1-RA (248.3 +/- 30.2) in comparison to that in the cholesteatoma (80.8 +/- 13.5). This was also statistically significant (P < 0.01). Whereas IL-1 activity was not detected in skin samples, all cholesteatoma specimens studied showed a stimulation effect on the production of IL-2 when incubated with the cell line LBRM-33. The results point to an over-expression of IL-1 concurrent with a decreased secretion of IL-1-RA in middle ear cholesteatoma. Furthermore IL-1-RA production is deficient relative to total IL-1 production, resulting in the presence of active IL-1.     

Potentiometric Study of Carbon Nanotube/Surfactant Interactions by Ion-Selective Electrodes. Driving Forces in the Adsorption and Dispersion Processes

The interaction (adsorption process) of commercial ionic surfactants with non-functionalized and functionalized carbon nanotubes (CNTs) has been studied by potentiometric measurements based on the use of ion-selective electrodes. The goal of this work was to investigate the role of the CNTs’ charge and structure in the CNT/surfactant interactions. Non-functionalized single- (SWCNT) and multi-walled carbon nanotubes (MWCNT), and amine functionalized SWCNT were used. The influence of the surfactant architecture on the CNT/surfactant interactions was also studied. Surfactants with different charge and hydrophobic tail length (sodium dodecyl sulfate (SDS), octyltrimethyl ammonium bromide (OTAB), dodecyltrimethyl ammonium bromide (DoTAB) and hexadecyltrimethyl ammonium bromide (CTAB)) were studied. According to the results, the adsorption process shows a cooperative character, with the hydrophobic interaction contribution playing a key role. This is made evident by the correlation between the free surfactant concentration (at a fixed [CNT]) and the critical micellar concentration, cmc, found for all the CNTs and surfactants investigated. The electrostatic interactions mainly determine the CNT dispersion, although hydrophobic interactions also contribute to this process.     

A long-term view of water consumption in Barcelona (1860–2011): from deprivation to abundance and eco-efficiency?

Water consumption in Barcelona in Spain, and the corresponding water imprint, followed a path resembling an Environmental Kuznets Curve. They grew slowly from the mid-19th century before reaching a peak in 1967–70, and a downward trend followed up to 2010. This paper uses a decomposition analysis to assess the role played by population growth, income increase and water intensity as determinants of these trends. It is stressed that water intensity does not express technical change alone, but includes social inequalities, consumer habits and cultural perceptions as well. It can be explained by taking into account the social conflicts and public policies of each period.     

Physical properties of the (K0·44Na0·52Li0.04)0.97La0·01Nb0·9Ta0·1O3 ceramic with coexisting tetragonal and orthorhombic monocrystalline grains at room temperature

A structural and physical properties study on ferroelectric (K_0·44Na_0·52Li_0.04)_0.97La_0·01Nb_0·9Ta_0·1O₃ ceramics with monocrystalline grains of orthorhombic (O) and tetragonal (T) perovskite phases coexisting at room temperature (RT) is presented. Different sintering temperatures were evaluated. XRD analysis demonstrates high crystalline quality of both phases with volume fractions depending of the sintering temperature. SEM shows grain facets and morphologies of both phases in all samples. Raman analysis confirms the dopant incorporation and the coexistence of both phases. The contributions of each phase in the dielectric response are deconvoluted using the frequency-temperature dielectric analysis. The orthorhombic-to-tetragonal (T_O-T) and tetragonal-to-cubic (T_T-C) phase transition temperatures shift ~100 °C below those reported for pure-KNN in all samples, as consequence of the Li, La, and Ta doping combination. Li doping promotes T-phase grain growth and decreases T_O-T below RT. La incorporation promotes the O-phase grain growth and decreases T_O-T and T_T-C. The optimal sintering temperature is 1180 °C with 50-50 volume fractions of T-O phases. Piezoresponse studies show a complex 180°-domain structure.     

Growth and characterization of BLZT–CFO composite thin films

Composite Ba_0.90La_0.067Zr_0.09Ti_0.91O₃–CoFe₂O₄ (BLZT–CFO) thin films were prepared by rf-magnetron sputtering from a 0.68 BLZT–0.32 CFO mixed target at a substrate temperature of 1033 K in a high oxygen pressure atmosphere. Single-crystal conducting Nb-doped (1%) SrTiO₃ and Pt-coated Si substrates were used. X-ray diffraction (XRD) patterns revealed that the films had both BLZT and CFO phases. Scanning electron microscopy (SEM) showed that the CFO phase was intermixed into a BLZT matrix. X-ray photoelectron spectroscopy (XPS) data in depth profile mode showed that all constituent elements were present and confirmed the favourable TiO₆-octahedron distortion in the BLZT-perovskite structure. The Au/BLZT–CFO/substrate capacitors were ferroelectric and magnetic at room temperature. The magnetoelectric nature of the composite thin films was demonstrated through the reduction of measured ferroelectric polarization with the application of an external magnetic field.     

Deformation stabilization of lattice structures via foam addition

Stochastic foams are soft but absorb energy efficiently under compressive loading; in contrast, periodic lattice structures are strong but generally exhibit poor energy-absorbing characteristics. Here we present and assess a hierarchical composite concept that aims to combine the desirable attributes of stochastic foams and lattice structures. The composite comprises a low-density polymer lattice structure with centimeter-scale voids and stochastic foam with pores in the sub-millimeter scale in the spaces between the lattice struts. The assessment is made on the basis of compressive response. We show that the post-yielding strength of the lattice can be doubled with the addition of even a weak (low-density) foam: the strength exceeds the combined contributions from the lattice structure and the foam alone. Addition of slightly denser foams can lead to an even larger strength increase. Using X-ray computed tomography, we show that the strength elevation is attributable to the stabilization of the strut members against buckling when surrounded by foam. Finite-element calculations of lattice structures alone and lattice/foam composites show similar characteristics. This composite concept may allow attainment of combinations of strength and energy absorption capacity that cannot be accessed by either foams or lattice structures alone.