ZnO rice like nonarchitects are grafted on the graphene carbon core via a rapid microwave synthesis route. The prepared grafted systems are characterized via XRD, SEM, RAMAN, and XPS to examined the structural and morphological parameters. Zinc oxide grafted graphene sheets (ZnO-G) are further doped in β-phase of polyvinylidene fluoride (PVDF) to prepare the polymer nanocomposites (PNCs) via mixed solvent approach (THF/DMF). β-phase confirmation of PVDF PNCs is done by FTIR studies. It is observed that ZnO-G filler enhances the β-phase content in the PNCs. Non-doped PVDF and PNCs are further studied for rheological behavior under the shear rate of 1–100 s−1. Doping of ZnO-G dopant to the PVDF matrix changes its discontinuous shear thickening (DST) behavior to continues shear thickening behavior (CST). Hydrocluster formation and their interaction with the dopant could be the reason for this striking DST to CST behavioral change. Strain amplitude sweep (10−3% -10%) oscillatory test reveals that the PNCs shows extended linear viscoelastic region with high elastic modulus and lower viscous modulus. Effective shear thickening behavior and strong elastic strength of these PNCs present their candidature for various fields including mechanical and soft body armor applications. 相似文献
Journal of Materials Science - Hybrid oxidation methodologies (HOMs) and active site enrichment of 2D nanocatalyst through defects induction are ubiquitously used for generating adequate reactive... 相似文献
The scintillator detectors are recalibrated against the datasheet given by the manufacturer. Optimal and mutual dependent values of (a) high voltage at PMT (Photomultiplier Tube), (b) amplifier gain, (c) average time to count the radiation particles (set by operator), and (d) number of instances/sample number are estimated. Total 5: two versions of Central Limit Theorem (CLT), (3) industry preferred Pulse Width Saturation, (4) calibration based on MPPC coupled Gamma-ray detector, and (5) gross method are used. It is shown that the CLT method is the most optimal method to calibrate the detector and its respective electronics couple. An inverse modeling-based Computerized Tomography method is used for verification. It is shown that statistically averaging results are more accurate and precise data than mode and median if the data is not skewed and a random number of samples are used during the calibration process. It is also shown that the average time to count the radiation particle is the most important parameter affecting the optimal calibration setting for precision and accurate measurements of gamma radiation.
Sustainable and efficient food supply chain has become an essential component of one’s life. The model proposed in this paper is deeply linked to people's quality of life as a result of which there is a large incentive to fulfil customer demands through it. This proposed model can enhance food quality by making the best possible food quality accessible to customers, construct a sustainable logistics system considering its environmental impact and ensure the customer demand to be fulfilled as fast as possible. In this paper, an extended model is examined that builds a unified planning problem for efficient food logistics operations where four important objectives are viewed: minimising the total expense of the system, maximising the average food quality along with the minimisation of the amount of CO2 emissions in transportation along with production and total weighted delivery lead time minimisation. A four objective mixed integer linear programming model for intelligent food logistics system is developed in the paper. The optimisation of the formulated mathematical model is proposed using a modified multi-objective particle swarm optimisation algorithm with multiple social structures: MO-GLNPSO (Multi-Objective Global Local Near-Neighbour Particle Swarm Optimisation). Computational results of a case study on a given dataset as well as on multiple small, medium and large-scale datasets followed by sensitivity analysis show the potency and effectiveness of the introduced method. Lastly, there has been a scope for future study displayed which would lead to the further progress of these types of models. 相似文献
Finite element analysis of the hip implant is conducted in this paper for representative femoral cross-section geometries and development of stress in the presence of bone cement is elucidated. Differences in cement stresses generated by varying implant cross-sections were compared with conventional features derived from representative implants. The analysis was performed under idealized implant assemblies by constraining the implant movement in the assembly. The cross-sections and implant geometries used are generic and intended to be representative of available geometries. This paper is a part of student research projects, prepared from a series of activities in biomedical implant research currently underway at Ohio Northern and Arkansas Tech Universities. 相似文献
Theoretical and practical ranges of leak rates measurable by the helium mass spectrometer are characterized. The effect of noise due to: 1) background helium present in the spectrometer and 2) desorption of helium that attaches itself to the specimen surface during bombing is quantified experimentally. The results guide a framework to extract the true leak rate from the measured leak rate profile. An optical interferometry based hermeticity measurement technique for ultra-fine leaks is proposed. The setup to implement the technique is described and a preliminary experimental result is reported. 相似文献
A remarkable nonlinearity has been observed for electric transport in K-TCNQ (potassium tetracyanoquinodimethane) quasi-one-dimensional
conductor. The negative differential resistance region appears afterVm (turn over voltage), beyond which voltage goes down with increase of current. A possible mechanism is discussed in terms
of dynamics of charged solitons and domain walls in one-dimensional molecular stacks of these types of crystals. 相似文献
Boiler tubes in power plants have finite life because of prolonged exposure to high temperature, stress and aggressive environment. Service-exposed platen superheater and reheater tubes (148,900 h) made of 2.25Cr-1 Mo steels in a 120 MW boiler of a thermal power plant were evaluated for remnant life. The investigation included hot tensile tests, hardness measurement, dimensional measurement, microscopy and creep tests. Experimentally determined yield and ultimate tensile strength, and estimated 10,000–100,000 h rupture strength in the temperature range 520–580 °C, exhibited a decreasing trend with increasing temperature. Microstructural study did not reveal any significant degradation in terms of creep cavities, cracks, graphitization, etc. Analysis of tensile and stress rupture data revealed that although there was degradation of the tubes due to prolonged service exposure in terms of the ultimate tensile strength values, stress rupture plots showed that the service exposed superheater and reheater tubes could remain in service for a length of more than 10 years at the operating hoop stress of 40 MPa/540 °C, provided no localised damage in the form of cracks or dents develop. 相似文献
Sickle operation in harvesting has been analysed with reference to design features of nine different types of sickles, and field and laboratory based investigations on biomechanical stresses and physiological valuation on six farmers. It has been indicated that the blade geometry contributes significantly to human performance and there is ample scope for further design optimisation. The suggested modifications are: (i) sickle weight - 200 g; (ii) total length of sickle - 33 cm; (iii) handle length - 11 cm; (iv) handle diameter - 3 c cm; (v) radius of blade curvature - 15 cm; (vi) blade concavity - 5 cm; (vii) serrated sickle: tooth pitch - 0.20 cm and tooth angle - 60 degrees; (viii) ratio of the length of cutting surface to chord length - 1.20. 相似文献