On the critical molecular chain length of polydimethylsiloxane

Because a study of the results reported for the chain dimensions of polydimethylsiloxane (PDMS), critical for the onset of this polymer's non-Newtonian flow behavior, obtained from the viscosity-molecular weight relationships available from the literature, clearly revealed that considerable differences exist between the reported data, a detailed analysis of these data was performed together with an additional examination of 10 new PDMS samples that were selected so as to have molecular weights that would fill the gaps observed in the polymer viscosity–chain length relationship constructed from the accepted literature data. The results obtained were analyzed by using several different procedures integrated into a recently described comparative method that could allow for determination of what is called the most realistic critical value, Z_wc. The latter was determined as 930 PDMS main-chain atoms, which corresponds to this polymer's degree of polymerization of 464.5 and the weight-average molecular weight of 34,500. It is not only shown that after elimination of some clearly erroneous data points from the previously reported relationships the obtained critical chain-length values could very well fit the earlier relationships, but also that appropriate “master” relationships were constructed including 48 pairs of the old and 10 pairs of the new data points. It is suggested that this relationship be accepted as the best-fit viscosity–polymer chain-length dependence for PDMS, and it is pointed out that the obtained PDMS critical chain-length value ranks this polymer's macromolecules as the most flexible of the corresponding long-chain molecules presently known. © 1993 John Wiley & Sons, Inc.     

Maximum Likelihood Approach for RFID Tag Set Cardinality Estimation with Detection Errors

Estimation schemes of Radio Frequency IDentification (RFID) tag set cardinality are studied in this paper using Maximum Likelihood (ML) approach. We consider the estimation problem under the model of multiple independent reader sessions with detection errors due to unreliable radio communication links and/or collisions. In every reader session, both the detection error probability and the total number of tags are estimated. In particular, after the $R$ -th reader session, the number of tags detected in $j$ ( $j=1,2,...,R$ ) reader sessions out of $R$ sessions is updated, which we call observed evidence. Then, in order to maximize the likelihood function of the number of tags and the detection error probability given the observed evidences, we propose three different estimation methods depending on how to treat the discrete nature of the tag set cardinality. The performance of the proposed methods is evaluated under different system parameters and compared with that of the conventional method via computer simulations assuming flat Rayleigh fading environments and framed-slotted ALOHA based protocol.     

Second‐Order Statistics of System with Microdiversity and Macrodiversity Reception in Gamma‐Shadowed Rician Fading Channels

In this letter, a wireless communication system with microdiversity and macrodiversity reception in gamma‐shadowed Rician fading channels is considered. Exact and rapidly converging infinite‐series expressions for the average level crossing rate and average fade duration at the output of the system are provided. Numerical results are presented graphically to illustrate the proposed mathematical analysis and to examine the effects of the system's parameters on the quantities considered.     

Characterization and Optimization of a Resonant Cavity Enhanced P-i-N Photodiode Response

This paper presents linear pulse response of a Resonant Cavity Enhanced (RCE) P-i-N fotodiode. The RCE P-i-N photodiode designed for high-speed aplication is analysed for various submicron thicknesses of absorption layer, bias voltages, active areas and incident pulse optical excitations. The results are obtained by numerical simulation of the complete phenomenological model for two valley semiconductor. Great enhancement of the quantum efficiency and the product bandwidth-quantum efficiency, is obvious from obtained results for this photodiode type.     

Analysis of blocking probability in optical burst switched networks

In this article, we study the blocking probability in a wavelength division multiplexing (WDM) based asynchronous bufferless optical burst switched (OBS) network, equipped with a bank of wavelength converters. Our analysis encloses two wavelength reservation schemes JIT (just-in-time) and JET (just-enough-time), and two-class data rate. The contribution of our work includes: (i) derivation of an accurate model for blocking probability of lower priority bursts in case of a non-preempted model; (ii) provision of the analytical model for blocking probability calculation in the OBS network, which includes these variables: two signaling schemes, partial wavelength conversion, two-class data, traffic intensity, cross-connect speed, number of wavelengths in WDM fiber, number of fibers in the node, number of wavelength converters, and number of nodes in the path; (iii) simulation results, which show that partial wavelength conversion provide quite satisfactory quality of service. We compare performance in a single OBS node, under various sets of parameter values. The OBS network shows great flexibility in terms of used multiclass data, and there is no dependence on the used higher layer protocol.     

New Paradigms in Wireless Communication Systems

This paper discusses what a new paradigm can be in wireless communication systems of the twenty-first century. First, it suggests two directions for the new paradigm; one is “micro- and nano-device communication system” which is the projected scenario considering that the entities in source and destination have been shrinking throughout the history of wireless communication systems. The second direction is “networked robot system”, which emerges as a natural extension of mobile ad hoc networking where the networking is closely related to motion control of robots. Secondly, it shows two interesting research topics, “the new communication protocol design” and “signal processing”, respectively, that arise in the wake of the fusion between the two directions in the novel communication paradigm. Finally, it considers a new science of wireless communications in the twenty-first century. Shinsuke Hara received the B.Eng., M.Eng. and Ph.D. degrees in communications engineering from Osaka University, Osaka, Japan, in 1985, 1987 and 1990, respectively. From April 1990 to March 1997, he was an assistant professor in the Department of Communication Engineering, School of Engineering, Osaka University, and from October 1997 to September 2005, he was an associate professor in the Department of Electronic, Information and Energy Engineering, Graduate School of Engineering, Osaka University. Since October 2005, he has been a professor in the Department of Physical Electronics and Informatics, Graduate School of Engineering, Osaka City University. In addition, from April 1995 to March 1996, he was a visiting scientist at Telecommunications and Traffic Control Systems Group, Delft University of Technology, Delft, The Netherlands. His research interests include wireless communications systems and digital signal processing. Hiroyuki Yomo received B.S. degree in communication engineering from Department of Communication Engineering, Osaka University, Osaka, Japan, in 1997, and M.S. and Ph.D. degrees in communication engineering from Department of Electronic, Information, and Energy Engineering, Graduate School of Engineering, Osaka University, Osaka Japan, in 1999 and 2002, respectively. From April 2002 to March 2004, he was a Post-doctoral Fellow in Department of Communication Technology, Aalborg University, Denmark. From April 2004 to September 2004, he was at Internet System Laboratory, NEC Corporation, Japan. Since October 2004, he has been an Assistant Research Professor in Center for TeleInfrastructure (CTIF), Aalborg University, Denmark. His main research interests are access technologies, radio resource management, and link-layer techniques in the area of short-range communication, cellular network, cognitive radio, and sensor network. Petar Popovski received the Dipl.-Ing. in electrical engineering and M.Sc. in communication engineering from the Faculty of Electrical Engineering, Sts. Cyril and Methodius University, Skopje, Republic of Macedonia, in 1997 and 2000, respectively. He received a Ph.D. degree from Aalborg University, Denmark, in 2004. From 1998 to 2001 he was a teaching and research assistant at the Institute of Telecommunications, Faculty of Electrical Engineering in Skopje. He is currently Assistant Professor at the Department of Communication Technology at the Aalborg University. His research interests are related to the PHY-MAC aspects of wireless protocols, wireless sensor networks, random access protocols, and network coding. Kazunori Hayashi received the B.E., M.E. and Ph.D. degrees in communication engineering from Osaka University, Osaka, Japan, in 1997, 1999 and 2002, respectively. He spent 3 months in 2000 at Aalborg University, Denmark, as a Visiting Scholar. Since 2002, he has been with the Department of Systems Science, Graduate School of Informatics, Kyoto University. He is currently an Assistant Professor there. His research interests include digital signal processing for communications systems.     

Outage analysis of selection diversity over Rayleigh fading channels with multiple co-channel interferers

In this paper an approach to the performance analysis of signal-to-interference (SIR) based selection combining (SC) operating over the Rayleigh fading channels experiencing an arbitrary number of multiple, Rayleigh co-channel interferers is presented. We have presented a general analysis of multibranch SC where each branch experiences an arbitrary number of multiple equal power co-channel interferers. Useful closed form expressions are derived for the probability density function (PDF) and cumulative distribution function (CDF) at the output of the combiner. Also an outage analysis is performed in order to show the effects of the number of multiple interferers, diversity order and input SIR unbalance to the system performances.     

Contributing to sustainability: addressing the core problems

Clean Technologies and Environmental Policy -     

Extended vertical lists for temporal pattern mining from multivariate time series

In this paper, the problem of mining complex temporal patterns in the context of multivariate time series is considered. A new method called the Fast Temporal Pattern Mining with Extended Vertical Lists is introduced. The method is based on an extension of the level‐wise property, which requires a more complex pattern to start at positions within a record where all of the subpatterns of the pattern start. The approach is built around a novel data structure called the Extended Vertical List that tracks positions of the first state of the pattern inside records and links them to appropriate positions of a specific subpattern of the pattern called the prefix. Extensive computational results indicate that the new method performs significantly faster than the previous version of the algorithm for Temporal Pattern Mining; however, the increase in speed comes at the expense of increased memory usage.