Catalytic aminolysis of epoxide by alumina prepared from amine-protected Al precursor

The catalytic activities of alumina prepared from an Al alkoxide-amine adduct monomer for the reaction of cyclopentene oxide with piperidine was determined after various pretreatments, including calcination and exposure to moisture. They were compared with the activity of alumina prepared by the conventional hydrolysis method. It was found that the as-prepared sample from the alkoxide-amine monomer preparation was five times more active than a conventional preparation, suggesting that it has a higher density of surface Lewis acid sites. However, its activity was much more severely suppressed by exposure to moisture.     

Power Analysis Attacks and Countermeasures

This article focuses on power analysis attacks because they have received by far the most attention in recent years. They are powerful and can be executed relatively easily. This article provides an introduction to these attacks and discusses countermeasures against them. In particular, we focus on countermeasures that can be implemented at the cell level. This article presents an overview of power analysis attacks, which are based on the measurement of the power consumed by cryptographic ICs, and countermeasures against them.     

Origin of petroporphyrins. 2. Evidence from stable carbon isotopes

Compared with the carbon-13 isotopic composition of the ubiquitous C32DPEP (DPEP, deoxophylloerythroetioporphyrin) the heavy but equivalent carbon-13 isotopic composition for the porphyrin structures 15(2)-methyl-15,17-ethano-17-nor-H-C30DPEP and 15,17-butano-, 13,15-ethano-13(2),17-propano-, and 13(1)-methyl-13,15-ethano-13(2),17-propanoporphyrin suggests a common precursor, presumably chlorophyll c, for these petroporphyrins isolated from the marine Julia Creek oil shale and the lacustrine Condor oil shale. Similarly, the heavy but variable carbon-13 isotopic composition of 7-nor-H-C31DPEP compared with C32DPEP is consistent with an origin from both chlorophyll b and chlorophyll c3. The equivalent carbon-13 isotopic composition for 13(2)-methyl-C33DPEP compared with C32DPEP suggests a common origin resulting from a weighted average of chlorophyll inputs.     

PM10 remote sensing from geostationary SEVIRI and polar-orbiting MODIS sensors over the complex terrain of the European Alpine region

The subject of this study is to investigate the capability of spaceborne remote sensing data to predict ground concentrations of PM₁₀ over the European Alpine region using satellite derived Aerosol Optical Depth (AOD) from the geostationary Spinning Enhanced Visible and InfraRed Imager (SEVIRI) and the polar-orbiting MODerate resolution Imaging Spectroradiometer (MODIS). The spatial and temporal resolutions of these aerosol products (10 km and 2 measurements per day for MODIS, ∼ 25 km and observation intervals of 15 min for SEVIRI) permit an evaluation of PM estimation from space at different spatial and temporal scales. Different empirical linear relationships between coincident AOD and PM₁₀ observations are evaluated at 13 ground-based PM measurement sites, with the assumption that aerosols are vertically homogeneously distributed below the planetary Boundary Layer Height (BLH). The BLH and Relative Humidity (RH) variability are assessed, as well as their impact on the parameterization. The BLH has a strong influence on the correlation of daily and hourly time series, whilst RH effects are less clear and smaller in magnitude. Despite its lower spatial resolution and AOD accuracy, SEVIRI shows higher correlations than MODIS (r_SEV∼ 0.7, r_MOD∼ 0.6) with regard to daily averaged PM₁₀. Advantages from MODIS arise only at hourly time scales in mountainous locations but lower correlations were found for both sensors at this time scale (r∼ 0.45). Moreover, the fraction of days in 2008 with at least one satellite observation was 27% for SEVIRI and 17% for MODIS. These results suggest that the frequency of observations plays an important role in PM monitoring, while higher spatial resolution does not generally improve the PM estimation. Ground-based Sun Photometer (SP) measurements are used to validate the satellite-based AOD in the study region and to discuss the impact of aerosols' micro-physical properties in the empirical models. A lower error limit of 30 to 60% in the PM₁₀ assessment from space is estimated in the study area as a result of AOD uncertainties, variability of aerosols properties and the heterogeneity of ground measurement sites. It is concluded that SEVIRI has a similar capacity to map PM as sensors on board polar-orbiting platforms, with the advantage of a higher number of observations. However, the accuracy represents a serious limitation to the applicability of satellites for ground PM mapping, especially in mountainous areas.     

Extracranial to intracranial vascular anastomosis for occlusive cerebrovascular disease: experience in 110 patients

In an attempt to ascertain the value of extra- to intracranial arterial bypass for cerebrovascular disease, the general topic of bypass surgery is reviewed and the results of this procedure in 110 patients are analyzed. The feasibility of high patency rates of the anastomosis with acceptably low permanent morbidity and operative mortality rates is demonstrated. Lesions producing transient ischemic attacks which previously were considered to be inoperable or inaccessible can be bypassed by this procedure, and there appears to be a dramatic improvement in the symptomotology of virtually all patients. Patients with a mild stroke or "progressive stroke" also appear to benefit from bypass, but the erratic natural history of these entities precludes irrefutable substantiation of this conclusion. Patients with moderate-to-serve neurological deficits do not appear to be improved by this procedure. In our group of 20 patients presenting with transient ischemic attacks who have had more than 3 years of follow-up, only one patient has suffered a stroke and that was located in the opposite hemisphere.     

Shared-memory parallelization of the data association problem inmultitarget tracking

The focus of this paper is to present the results of our investigation and evaluation of various shared-memory parallelizations of the data association problem in multitarget tracking. The multitarget tracking algorithm developed was for a sparse air traffic surveillance problem, and is based on an Interacting Multiple Model (IMM) state estimator embedded into the (2D) assignment framework. The IMM estimator imposes a computational burden in terms of both space and time complexity, since more than one filter model is used to calculate state estimates, covariances, and likelihood functions. In fact, contrary to conventional wisdom, for sparse multitarget tracking problems, we show that the assignment (or data association) problem is not the major computational bottleneck. Instead, the interface to the assignment problem, namely, computing the rather numerous gating tests and IMM state estimates, covariance calculations, and likelihood function evaluations (used as cost coefficients in the assignment problem), is the major source of the workload. Using a measurement database based on two FAA air traffic control radars, we show that a “coarse-grained” (dynamic) parallelization across the numerous tracks found in a multitarget tracking problem is robust, scalable, and demonstrates superior computational performance to previously proposed “fine-grained” (static) parallelizations within the IMM     

Ein Konzept zur Wirkungsgradoptimierung von Einzylinder-Dieselgeneratoren mittels Optimalsteuerung und Extremum-Seeking

In this contribution the problem of maximizing the efficiency of a hybrid power unit at a specified output power level by optimizing the generator current trajectory as well as the design variables that can be chosen during the machine design process is investigated. The concept is demonstrated based on a hybrid single-cylinder diesel engine that is coupled to an electric generator. By developing a model of the system and using open-loop optimal control the optimal operating strategy and the optimal machine design are determined. Besides that, the problems occurring in the application of this strategy to a test rig are discussed. For this purpose, a model-free real-time optimization concept based on extremum seeking control is presented. The effectiveness of both the model-based and the model-free concept are demonstrated by simulation and experimental results.     

A note on the long-run elasticities from the energy consumption–GDP relationship

The goal of this paper is to examine the long-run elasticities of the impacts of energy consumption on GDP and GDP on energy consumption. The energy consumption–GDP relationship is amongst the most popular relationships examined in the energy economics literature. The bulk of the extant literature has assumed a positive relationship between energy consumption and real GDP. Our analysis shows that in only around 60% of the countries considered the relationship is positive.