Improving Deep Attractor Network by BGRU and GMM for Speech Separation

Deep Attractor Network (DANet) is the state-of-the-art technique in speech separation field, which uses Bidirectional Long Short-Term Memory (BLSTM), but the complexity of the DANet model is very high. In this paper, a simplified and powerful DANet model is proposed using Bidirectional Gated neural network (BGRU) instead of BLSTM. The Gaussian Mixture Model (GMM) other than the k-means was applied in DANet as a clustering algorithm to reduce the complexity and increase the learning speed and accuracy. The metrics used in this paper are Signal to Distortion Ratio (SDR), Signal to Interference Ratio (SIR), Signal to Artifact Ratio (SAR), and Perceptual Evaluation Speech Quality (PESQ) score. Two speaker mixture datasets from TIMIT corpus were prepared to evaluate the proposed model, and the system achieved 12.3 dB and 2.94 for SDR and PESQ scores respectively, which were better than the original DANet model. Other improvements were 20.7% and 17.9% in the number of parameters and time training respectively. The model was applied on mixed Arabic speech signals and the results were better than that in English.     

Determination of Activity Coefficients of Semi-Volatile Organic Aerosols Using the Integrated Volume Method

We demonstrate the use of the Integrated Volume Method (IVM) to estimate activity coefficients of semi-volatile organic compounds pertinent to ambient/atmospheric aerosols in binary mixtures. We generate binary solution aerosols with different mole fractions of individual components; for each mixture, we measure total change in aerosol volume upon heating from 25 ^○ C to 35 ^○ C, with the aerosols being at equilibrium in both states. The change in aerosol volume, or in other words, the partitioning between the particle phase and the gas phase, is used to determine activity coefficients of the compounds as a function of their mole fraction in the mixture. We demonstrate this method using the following four model systems. System 1: adipic acid–pimelic acid, which illustrates polar organic–polar organic interactions. Non-ideal behavior was observed with activity coefficients around three at infinite dilution. System 2: adipic acid–dioctyl sebacate, which illustrates polar organic–non-polar organic interactions. The compounds in this experiment did not form a solution. System 3: adipic acid–ammonium sulfate, which illustrates polar organic–inorganic interactions. The compounds in this experiment did not form a solution. System 4: adipic acid–ambient extracts, which illustrates the potential use of the method to study partitioning behavior of individual components in a complex matrix approximating that of real ambient aerosol. The measured activity coefficients of adipic acid were less than unity for the tested range of mixing ratios, indicating suppression of volatility of this compound in ambient organic matrix.     

The Effect of Alkyl Spacers on the Mixed Ionic-Electronic Conduction Properties of N-Type Polymers

Conjugated polymers with mixed ionic and electronic transport are essential for developing the complexity and function of electrochemical devices. Current n-type materials have a narrow scope and low performance compared with their p-type counterparts, requiring new molecular design strategies. This work presents two naphthalene diimide-bithiophene (NDI-T2) copolymers functionalized with hybrid alkyl-glycol side chains, where the naphthalene diimide unit is segregated from the ethylene glycol (EG) units within the side chain by an alkyl spacer. Introduction of hydrophobic propyl and hexyl spacers is investigated as a strategy to minimize detrimental swelling close to the conjugated backbone and balance the mixed conduction properties of n-type materials in aqueous electrolytes. It is found that both polymers functionalized with alkyl spacers outperform their analogue bearing EG-only side chains in organic electrochemical transistors (OECTs). The presence of the alkyl spacers also leads to remarkable stability in OECTs, with no decrease in the ON current after 2 h of operation. Through this versatile side chain modification, this work provides a greater understanding of the structure-property relationships required for n-type OECT materials operating in aqueous media.     

Effect of Aerosol Generation Method on Measured Saturation Pressure and Enthalpy of Vaporization for Dicarboxylic Acid Aerosols

To date, most studies of the thermodynamic properties of organic aerosols have utilized test aerosols generated by spray atomization followed by a diffusion drying step. Some evidence points to possible biases in measured thermodynamic properties stemming from the presence of residual solvent (water or alcohol) in the dried aerosol. In the current study we compared measurements of thermodynamic properties of organic aerosols generated by atomization of aqueous solutions to those generated by homogeneous condensation using a modified Sinclair-La Mer generator. In particular, using the Integrated Volume Method (Saleh et al. 2008 Saleh, R., Walker, J. and Khlystov, A. 2008. Determination of Saturation Pressure and Enthalpy of Vaporization of Semi-Volatile Aerosols: The Integrated Volume Method. J. Aerosol Sci., 39: 876[Crossref], [Web of Science ®] , [Google Scholar]), we measured and compared the saturation pressure (P _sat ) at 298 K and enthalpy of vaporization (ΔH) of C-6 (adipic) and C-9 (azelaic) dicarboxylic acid aerosol generated using these techniques. We found that P _sat and ΔH exhibited no statistically significant difference across the tested aerosol generation methods, indicating that any residual solvent carried by the particles had no impact on the measurements. For adipic acid, we obtained P _sat of 3.3 × 10^?5 (±0.9 × 10^?5) Pa and ΔH of 132 (±8) kJ/mol with atomization, and P _sat of 4.2 × 10^{? 5} (±2.2 × 10^?5) Pa and ΔH of 126 (±21) kJ/mol with homogeneous condensation; for azelaic acid, we obtained P _sat of 1.4 × 10^?5 (±0.5 × 10^?5) Pa and ΔH of 145 (±15) kJ/mol with atomization, and P _sat of 0.9 × 10^{? 5} (±0.3 × 10^{? 5}) Pa and ΔH of 158 (±17) kJ/mol with homogeneous condensation. In addition, SEM images of the acids generated by the two methods showed no obvious difference in surface morphology.     

Characterization of Lithium Ion-Conducting Blend Biopolymer Electrolyte Based on CH–MC Doped with LiBF<Subscript>4</Subscript>

Lithium ion-conducting polymer blend electrolytes based on chitosan and methylcellulose complexed with lithium tetrafluoroborate (LiBF₄) were prepared by a solution-casting method. The features of complexation of the solid polymer electrolytes were studied using X-ray diffraction techniques. Electrical conductivity of the prepared films was measured as a function of frequency at a different temperature. The increased trend of the electrical conductivity with increasing temperature and salt concentration can be attributed to increasing the mobility and number of lithium ions, respectively. The polymer electrolyte system exhibited Arrhenius-type, temperature-dependence ion conductivity behavior. Optical properties such as optical band gap, tail due to localized states and complex refractive index were estimated for present polymer electrolyte system from optical absorption measurement in the wavelength region 190–1100 nm. It was found that the optical direct band gap values shifted to lower energies upon addition of LiBF₄ salt up to 40 wt% dopant concentration, and showed an increasing tendency for a further increase in dopant concentration. The high refractive index for this composition (2.44–2.63) at visible wavelengths eminently suitable for optical applications.     

Reach a nonlinear consensus for MAS via doubly stochastic quadratic operators

This technical note addresses the new nonlinear protocol class of doubly stochastic quadratic operators (DSQOs) for coordination of consensus problem in multi-agent systems (MAS). We derive the conditions for ensuring that every agent reaches consensus on a desired rate of the group's decision where the group decision value in its agent's initial statuses varies. Besides that, we investigate a nonlinear protocol sub-class of extreme DSQO (EDSQO) to reach a consensus for MAS to a common value with nonlinear low-complexity rules and fast time convergence if the interactions for each agent are not selfish. In addition, to extend the results to reach a consensus and to avoid the selfish case we specify a general class of DSQO for reaching a consensus under any given case of initial states. The case that MAS reach a consensus by DSQO is if each member of the agent group has positive interactions of DSQO (PDSQO) with the others. The convergence of both EDSQO and PDSQO classes is found to be directed towards the centre point. Finally, experimental simulations are given to support the analysis from theoretical aspect.     

Clouds and “throat hit”: Effects of liquid composition on nicotine emissions and physical characteristics of electronic cigarette aerosols

Electronic cigarettes (ECIGs) heat and vaporize a liquid mixture to produce an inhalable aerosol that can deliver nicotine to the user. The liquid mixture is typically composed of propylene glycol (PG) and vegetable glycerin (VG), in which are dissolved trace quantities of flavorants and, usually, nicotine. Due to their different chemical and thermodynamic properties, the proportions of PG and VG in the liquid solution may affect nicotine delivery and user sensory experience. In social media and popular culture, greater PG fraction is associated with greater “throat-hit,” a sensation that has been attributed in cigarette smokers to increased presence of vapor-phase nicotine. VG, on the other hand, is associated with thicker and larger exhaled “clouds.” In this study, we aim to investigate how PG/VG ratio influences variables that relate to nicotine delivery and plume visibility. Aerosols from varying PG/VG liquids were generated using a digitally controlled vaping instrument and a commercially available ECIG, and analyzed for nicotine content by GC-MS. Particle mass and number distribution were determined using a six-stage cascade impactor and a fast particle spectrometer (TSI EEPS), with tightly controlled dilution and sampling biases. A Mie theory model was used to compute the aerosol scattering coefficients in the visible spectrum. Decreasing the PG/VG ratio resulted in a decrease in total particulate matter (TPM) and nicotine yield (R² > 0.9, p < .0001). Measured particle count median diameter ranged between 44 and 97nm, and was significantly smaller for PG liquids. Although the particle mass concentration was lower, aerosols produced using liquids that contained VG had an order of magnitude greater light scattering coefficients. These findings indicate that PG/VG ratio is a strong determinant of both nicotine delivery and user sensory experience.

Copyright © 2017 American Association for Aerosol Research     

An Organic Electrochemical Transistor Integrated Photodetector for High Quality Photoplethysmogram Signal Acquisition

The organic photodiode (OPD) is a promising building block for solution-processable, flexible, lightweight, and miniaturized photodetectors, ideal for wearable applications. Despite the advances in materials used in OPDs, their photocurrent and light responsivity are limited, and alternative methods are required to boost the signal response. Herein, a miniaturized organic electrochemical transistor (OECT) is integrated with an OPD module to unlock the potential of OPDs to acquire physiological signals. In this integrated photodetector (IPD) system, the light intensity regulates the OPD voltage output that modulates the OECT channel current. The high transconductance of the OECT provides efficient voltage-to-current conversion, enhancing the signal-to-noise ratio on the sensing site. A microscale, p-type enhancement-mode OECT with high g_m and fast switching speed performs better in this application than depletion-mode OECT of the same geometry. The IPD achieves a photocurrent and responsivity 318 and 140 times higher than the standalone OPD, respectively. It is shown that with the IPD, the amplitude of the photoplethysmogram signals detected by the OPD is enhanced by a factor of 2.9 × 10³, highlighting its potential as a wearable biosensor and to detect weak, often uncaptured, light-based signals from living systems.     

Reducing execution profiles: techniques and benefits

The interest in leveraging data mining and statistical techniques to enable dynamic program analysis has increased tremendously in recent years. Researchers have presented numerous techniques that mine and analyze execution profiles to assist software testing and other reliability enhancing approaches. Previous empirical studies have shown that the effectiveness of such techniques is likely to be impacted by the type of profiled program elements. This work further studies the impact of the characteristics of execution profiles by focusing on their size; noting that a typical profile comprises a large number of program elements, in the order of thousands or higher. Specifically, the authors devised six reduction techniques and comparatively evaluated them by measuring the following: (1) reduction rate; (2) information loss; (3) impact on two applications of dynamic program analysis, namely, cluster‐based test suite minimization (App‐I), and profile‐based online failure and intrusion detection (App‐II). The results were promising as the following: (a) the average reduction rate ranged from 92% to 98%; (b) three techniques were lossless and three were slightly lossy; (c) reducing execution profiles exhibited a major positive impact on the effectiveness and efficiency of App‐I; and (d) reduction exhibited a positive impact on the efficiency of App‐II, but a minor negative impact on its effectiveness. Copyright © 2014 John Wiley & Sons, Ltd.     

The Fate of Epidermal Tight Junctions in the stratum corneum: Their Involvement in the Regulation of Desquamation and Phenotypic Expression of Certain Skin Conditions

We evaluated the presence of tight junction (TJ) remnants in the stratum corneum (SC) of in vitro reconstructed human epidermis and human skin explants subjected or not to an aggressive topical treatment with beta-lipohydroxy salicylic acid (LSA) for 24 h. LSA-treated samples showed an increased presence of TJ remnants in the two lowermost layers of the SC, as quantified with standard electron microscopy. The topical aggression-induced overexpression of TJ-like cell–cell envelope fusions may influence SC functions: (1) directly, through an enhanced cohesion, and (2) indirectly, by impeding accessibility of peripheral corneodesmosomes to extracellular hydrolytic enzymes and, thus, slowing down desquamation. Observations of ichthyotic epidermis in peeling skin disease (PSD; corneodesmosin deficiency; two cases) and ichthyosis hypotrichosis sclerosing cholangitis syndrome (IHSC/NISCH; absence of claudin-1; two cases) also demonstrated increased persistence of TJ-like intercellular fusions in pathological SC and contributed to the interpretation of the diseases’ pathological mechanisms.