External Synchronization of 160-GHz Optical Beat Signal by Optical Phase-Locked Loop Technique

We have synchronized a 160-GHz optical beat signal with a 40-GHz reference optical pulse train by using an optical phase-locked loop (OPLL). The OPLL consists of an optical beat signal source, comprising a pair of three-electrode distributed feedback laser diodes that works as a voltage controlled oscillator, and an all-optical phase detector based on the two-photon absorption in a silicon avalanche photodiode. Phase-locking operation is confirmed through phase-error measurement and cross-correlation trace measurement. The residual timing jitter of the 160-GHz optical beat signal relative to the reference pulse train, in the bandwidth of 80 MHz, is measured to be as small as 126 fs     

Synthesis of terpene alcohols from isoprene oligomers

Various terpene alcohols were prepared from isoprene oligomers via two steps: epoxidation with peracetic acid and isomerisation with aluminium triisopropoxide. For example, 2-methylene-6-methyl-7-octene-1-o1 was prepared from 2,6-dimethyl-1,7-octadiene. From 2,6-dimethyl-2,7-octadiene, 3,3,6-trimethyl-1,5-heptadiene, 2,7-dimethyl-2,6-octadiene, 2,6-dimethyl-1,3,6-octatriene, 1-methyl-4-isopropenyl-1-cyclohexene, and 1,5-dimethyl-1,5-cyclooctadiene, the corresponding alcohols were obtained, respectively.     

Synthesis and Spectral Characterization of Difunctional Fullerenes

The oxidation of C₆₀ with m-chloroperbenzoic acid gave C₆₀O₂ with a high positional selectivity, as the ¹³C NMR analysis suggested. Diadducts C₆₀CCI₂O, C₆₀CCl₂(anthracene), C₆₀CCl₂[(CH₂CH₂)₂N₂], and C₆₀CCI₂[Pt-(PPh₃)₂] were synthesized, isolated, and characterized by negative ion FAB mass spectroscopy.     

Novel method for numerical analysis of electron trajectories in electrostatic fields of implicit functional forms

A novel method for calculating 2-dimensional electron trajectories is given, which is useful for the case when the electric fields are expressed by implicit functional forms which are not suited to a conventional electron-trajectory analysis. This method is applied to parallel-plate and parallel-cylinder deflection systems.     

Radiation-induced polymerization of ethylene in a pilot plant. I. Bulk process

Radiation-induced bulk polymerization of ethylene was carried out with use of a pilot plant with a 10 liter reactor at pressures of 225–400 kg/cm², temperatures of 30–95°C, ethylene feed rates of 5–28 kg/hr, and dose rate of 3.8 × 10⁵ rad/hr. Characteristics of the process are mild polymerization conditions and capability of producing medium density polyethylene in powder form. The spacetime yield and molecular weight of polymer were in the range of 3.5 to 13.1 g/liter hr and 2.2 × 10⁴ to 14 × 10⁴, respectively. The space-time yield increased with mean residence time and 2.4 powders of pressure, and decreased with temperature. Molecular weight changed similarly with the reaction conditions. These results were consistent with those of the bench plant experiment and the scale effect was small. Polymer deposit to the reactor wall limited a period of continuous operation of the plant. The amount of deposited polymer was increased with the square of reaction time. The rate of polymer deposit was proportional to polymer concentration and to the cube of pressure. The polymer deposit cannot be solved in the bulk process.     

Quantitative uronic acid analysis of the otoconial membrane of the guinea pig

Histochemical and biochemical studies have shown that the otoconial membrane, as well as the tectorial membrane and the cupula, contains glycoproteins and proteoglycans. However, uronic acids, which are essential elements of glycosaminoglycans (GAGs), have not so far been directly detected or quantitatively measured in inner ear samples. In the present study, we quantitatively analyzed the glucuronic acid (GlcA) content of the otoconial membrane of the guinea pig by methanolysis combined with reversed-phase high-performance liquid chromatography (RP-HPLC). The utricular otoconial membrane was treated with thermolysin to separate the supernatant (OM-sup; gelatinous layer) and precipitate (OM-ppt; otoconia). The samples were then subjected to methanolysis followed by brief TFA hydrolysis, incubated with 1-phenyl-3-methyl-5-pyrazolone for labeling, and then analyzed by RP-HPLC coupled with the detection of UV absorbance at 245 nm. The GlcA contents of OM-sup and OM-ppt were 2.1 and 5.8 pmol/100 ng protein, respectively. Based on this result, GlcA-containing GAGs estimated as (GlcA+monosulfo-N-acetylhexosamine)n would be 1.0% of protein in OM-sup and 2.61% of protein in OM-ppt, indicating that this type of glycoconjugate is a minor component in both fractions. It is, accordingly, presumed that both the gelatinous layer and otoconia of the otoconial membrane have totally different properties from those of the tectorial membrane and cartilaginous matrix, which contain abundant GAGs.