Thermal analysis of cylinder head carbon deposits from single cylinder diesel engine fueled by palm oil–diesel fuel emulsions

This paper aims to evaluate the cylinder head carbon deposit from diesel engine fuelled by four samples of diesel fuel emulsions containing 0%; 5%; 10% and 15% vol. water and 20% Palm Oil Methyl Ester (POME) were subjected to thermogravimetric analysis (TGA/DSC) in air medium. The deposit build up processes were performed on a single-cylinder direct-injection diesel engine for period of 25 h for each set of test fuel under constant speed 2500 rpm. The TGA system was used and then correlated with elemental analysis as well as infrared spectra for microscopic observations. It has been found that, as the water increases in fuel, less aromatic and less reactive of deposits would be formed. Therefore, such method of analyses can be used as an indicator to verify the stability of carbon deposit inside the combustion chamber that could substantiate the applicability of a particular fuel to be accepted.     

Fabrication of Sub‐10 nm Metallic Lines of Low Line‐Width Roughness by Hydrogen Reduction of Patterned Metal–Organic Materials

The fabrication of very narrow metal lines by the lift‐off technique, especially below sub‐10 nm, is challenging due to thinner resist requirements in order to achieve the lithographic resolution. At such small length scales, when the grain size becomes comparable with the line‐width, the built‐in stress in the metal film can cause a break to occur at a grain boundary. Moreover, the line‐width roughness (LWR) from the patterned resist can result in deposited metal lines with a very high LWR, leading to an adverse change in device characteristics. Here a new approach that is not based on the lift‐off technique but rather on low temperature hydrogen reduction of electron‐beam patterned metal naphthenates is demonstrated. This not only enables the fabrication of sub‐10 nm metal lines of good integrity, but also of low LWR, below the limit of 3.2 nm discussed in the International Technology Roadmap for Semiconductors. Using this method, sub‐10 nm nickel wires are obtained by reducing patterned nickel naphthenate lines in a hydrogen‐rich atmosphere at 500 °C for 1 h. The LWR (i.e., 3 σ_LWR) of these nickel nanolines was found to be 2.9 nm. The technique is general and is likely to be suitable for fabrication of nanostructures of most commonly used metals (and their alloys), such as iron, cobalt, nickel, copper, tungsten, molybdenum, and so on, from their respective metal–organic compounds.     

去除牛粪厌氧生物转化过程中的H2S

The main aim of this research was the experimental study at lab scale to check the absorption technology for the in situ removal of H2S from biogas during anaerobic digestion process. The reagent FeCl3 was used to check the removal efficiency of H2S produced from dairy manure during anaerobic bioconversion process. The experiments were conducted under mesophilic conditions. The composition of biogas was analyzed by gas chromatography analyzer equipped with flame photometer and thermal conductivity detectors. Experimental results under the same conditions demonstrate that high concentration of H2S in the form of FeS can be removed totally from the biogas using FeCl3 dosing with in anaerobic batch digester.     

Synthesis and Characterization of Sulfanilamide-Based Nonionic Surfactants and Evaluation of Their Nano-Vesicular Drug Loading Application

Nonionic surfactants are highly stable and cost-effective and receiving acceptance for applications in many diverse fields including drug delivery, due to their distinctive properties. Here, we report on the synthesis and characterization of sulfanilamide-based nonionic surfactants for nanoscale vesicular drug loading applications. Nonionic surfactants were synthesized through alkylation of sulfanilamide with alkyl halides that possessed diverse degrees of lipophilicity. They were explored for their nanovesicular drug loading with Cefixime as a hydrophobic model drug. Drug-loaded nanovesicles were characterized for surface morphologies, size, size distribution, surface charge, and drug loading efficiency using atomic force microscopy (AFM), dynamic light scattering (DLS), and UV–visible spectrophotometry. All of the synthesized nonionic surfactants revealed their CMC values in 0.055–0.035 mM range depending upon the lipophilic chain length of surfactants. They caused a decreased hemoglobin release and low toxicity against cell culture. They self-assembled and loaded an increased amount of drug in the form of nanorange spherical shape niosomal vesicles. Results of the current study verify these synthesized nonionic surfactants are hemocompatible, nontoxic, and capable of self-assembling into nanorange niosomal vesicles. These niosomal vesicles can be suggested as safe and highly efficient nanocarriers for hydrophobic drug loading and delivery.     

An Investigation of Low Velocity Impact Properties of Rotationally Molded Skin–Foam–Skin Sandwich Structure

In this study, the low velocity impact properties of rotationally molded skin–foam–skin sandwich structures were investigated experimentally since there is a need for a greater understanding of the impact behavior of these composites in service to extend the range of their applications. Polyethylene rotationally molded sandwich structures were manufactured at various skin and core layer thickness combinations and tested using an instrumented low velocity drop weight impact testing machine at 20–100 J impact energy levels, at room temperature. This allowed the identification of the impact response, failure mode, and the effects of the skin and core layer thickness on impact resistance. Force–deflection curves, maximum force, contact time, maximum deflection versus impact energy curves were analyzed. Samples were seen to fail due to the indentation dart piercing the upper and lower skins, with crushing and consolidation seen in the core foamed layer. Delamination at the core/skin interface was not observed. It was found that fracture initiates from the lower skin and then continues to grow to the upper skin via the foamed core layer. The impact resistance was noted to increase with increasing skin and core layer thickness; though an increase in skin layer thickness had a greater contribution than an increase in the core layer thickness. POLYM. ENG. SCI., 60: 387–397, 2019. © 2019 Society of Plastics Engineers     

Multi-core real-time scheduling for generalized parallel task models

Multi-core processors offer a significant performance increase over single-core processors. They have the potential to enable computation-intensive real-time applications with stringent timing constraints that cannot be met on traditional single-core processors. However, most results in traditional multiprocessor real-time scheduling are limited to sequential programming models and ignore intra-task parallelism. In this paper, we address the problem of scheduling periodic parallel tasks with implicit deadlines on multi-core processors. We first consider a synchronous task model where each task consists of segments, each segment having an arbitrary number of parallel threads that synchronize at the end of the segment. We propose a new task decomposition method that decomposes each parallel task into a set of sequential tasks. We prove that our task decomposition achieves a resource augmentation bound of 4 and 5 when the decomposed tasks are scheduled using global EDF and partitioned deadline monotonic scheduling, respectively. Finally, we extend our analysis to a directed acyclic graph (DAG) task model where each node in the DAG has a unit execution requirement. We show how these tasks can be converted into synchronous tasks such that the same decomposition can be applied and the same augmentation bounds hold. Simulations based on synthetic workload demonstrate that the derived resource augmentation bounds are safe and sufficient.     

Development of friction force model for mineral oil basestock containing palm olein and antiwear additive

Palm oil is also another choice of vegetable that is being eyed as a potential vegetable oil in the lubricating area. This paper presents a study of the development of a fiction force model for mineral oil basestock containing palm olein, and antiwear amine phosphate as additive, tested on a four-ball tribotester. The model is developed using terms of wear load, speed and operating time. These variables were investigated using the design of experiments and utilization of the response surface methodology (RSM). Moreover, the effect of palm oil on wear scars of material tested was also discussed. This paper shows palm olein itself indeed is a good antiwear lubricant compared to mineral oil basestock (SN500), but the use of additives shows an increase in better lubrication as smaller wear scars are found out from using palm olein in the test runs.     

Thermal–structural analysis of bi-metallic conformal cooling for injection moulds

In injection moulding process, cooling time greatly affects the total cycle time. As thermal conductivity is one of the main factors for conductive heat transfer in cooling phase of IMP, a cooling channel made by higher thermal conductive material will allow faster extraction of heat from the molten plastic materials, thus resulting in shorter cycle time and higher productivity. The main objective of this paper is to investigate bi-metallic conformal cooling channel design with high thermal conductive copper tube insert for injection moulds. Thermal–structural finite element analysis has been carried out with ANSYS workbench simulation software for a mould with bi-metallic conformal cooling channels and the performance is compared with a mould with conventional straight cooling channels for an industrial plastic part. Experimental verification has been carried out for the two moulds using two different types of plastics, polypropylene (PP) and acrylonitrile butadiene styrene, in a mini injection moulding machine. Simulation and experimental results show that bi-metallic conformal cooling channel design gives better cycle time, which ultimately increases production rate as well as fatigue life of the mould.