Technical review: Improvement of mechanical properties and suitability towards armor applications – Alumina composites

Ceramic Matrix Composites (CMCs) have many interesting properties, mainly light weight, cost efficiency, low density, high compressive strength, high hardness and durability. Hence, they emerged as a boon to the development of personnel armors in the past. The current work aims to review various new methodologies adapted for the reinforcement of Alumina (Al₂O₃) CMCs in recent times, including some of the interesting results obtained with respect to mechanical properties, suitability of the synthesized composites for armor applications, and the upcoming reinforcement trends. Finally, studies related to reinforcement in Al₂O₃ CMCs, specifically towards armor applications have been consolidated to arrive at some of the important inferences for concluding reasonably.     

Electrocatalytic Reduction of CO2 to Ethylene by Molecular Cu‐Complex Immobilized on Graphitized Mesoporous Carbon

The electrochemical reduction of carbon dioxide (CO₂) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO₂ to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO₂ to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO₂ in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions.     

Measurement and modeling of the sidewall threshold voltage ofmesa-isolated SOI MOSFETs

Five-terminal silicon-on-insulator (SOI) MOSFETs have been characterized to determine the threshold voltage at the front, back, and sidewall as a function of the body bias. The threshold voltage shift with the body bias at the front and back interfaces can be explained by the standard bulk body effect equation. However, the threshold voltage shift at the sidewall is smaller than predicted by this equation and saturates at large body biases. This anomalous behavior is explained by two-dimensional charge sharing between the sidewall and the front and back interfaces. An analytical model that accounts for this charge sharing by a simple trapezoidal approximation of the depletion regions and correctly predicts the sidewall threshold voltage shift and its saturation is discussed. The model makes it possible to measure the sidewall threshold even when it is larger than the front threshold voltage     

Degradation of polyethylene terephthalate films in the presence of lubricants for HFC 134a: a critical issue for hermetic motor insulation systems

Earlier studies conducted in the use of sealed tubes with polyalkylene glycol lubricants and polyethylene terephthalete (PET) films revealed that the PET films exhibited embrittlement and (visual) degradation. This led to an investigation of PET embrittlement mechanisms with the new lubricants used with HFC 134a. The lubricants studied were three polypropylene glycols (the monol, the diol and the completely end-capped glycols), pentaerythritol ester and a blend of monol and ester. The effects of moisture content, temperature and lubricant structure were studied. All lubricants in this study were of viscosity grade ISO-32 (150 SUS). The results were compared to PET film embrittlement in the presence of CFC 12 and mineral oil. This study reconfirmed the earlier findings that the PET films must be dried to lower than 0.1 wt.% moisture content for use in hermetic systems. This paper discusses the effect of the moisture content of the lubricant and the effect of the lubricant structure on PET films. The dependence of the various mechanisms on temperature is shown. Esters and end-capped polyalkylene glycols are recommended for use with HFC 134a.     

Medium access control in ad hoc networks with MIMO links: optimization considerations and algorithms

we present a medium access control (MAC) protocol for ad hoc networks with multiple input multiple output (MIMO) links. MIMO links provide extremely high spectral efficiencies in multipath channels by simultaneously transmitting multiple independent data streams in the same channel. MAC protocols have been proposed in related work for ad hoc networks with other classes of smart antennas such as switched beam antennas. However, as we substantiate in the paper, the unique characteristics of MIMO links coupled with several key optimization considerations, necessitate an entirely new MAC protocol. We identify several advantages of MIMO links, and discuss key optimization considerations that can help in realizing an effective MAC protocol for such an environment. We present a centralized algorithm called stream-controlled medium access (SCMA) that has the key optimization considerations incorporated in its design. Finally, we present a distributed SCMA protocol that approximates the centralized algorithm and compare its performance against that of baseline protocols that are CSMA/CA variants.     

Structural health monitoring of railway tracks using IoT-based multi-robot system

Neural Computing and Applications - A multi-robot-based fault detection system for railway tracks is proposed to eliminate manual human visual inspection. A hardware prototype is designed to...     

Process Technology for the Production of Micronutrient Rich Red Palm Olein

Crude palm oil (CPO) is the richest natural source of carotenes that are destroyed in the conventional processing. There is a growing demand for nutritional products containing bioactive constituents externally fortified or preserved through modified process. A commercially viable process for the production of red palm olein (RPOn) rich in carotenes, tocols and sterols has been developed at pilot scale. The process developed involved neutralization of CPO followed by crystallization at controlled rate of cooling and deodorization of the resultant neutralized and winterized palm olein (WPOn) under controlled conditions of temperature and high vacuum. Analytical data related to micronutrients at each process step was monitored. The RPOn thus produced had not more than 0.25% of free fatty acids (FFA) and it retained more than 80% of the carotenes, about 85% of tocols and 65% of sterols originally present in the CPO. The physico-chemical characteristics of RPOn revealed that it is nutritionally of superior quality compared to that of the commercial refined bleached deodorized (RBD) palm olein currently available in the market. The carotenes, tocols and sterols profile of RPOn by HPLC showed that they were retained in their natural forms.     

Silo music and silo quake: granular flow-induced vibration

Acceleration and sound measurements during granular discharge from silos are used to show that silo music is a sound resonance produced by silo quake. In tall and narrow silos, the latter is produced by stick-slip friction between the wall and the granular material. For the discharge rates studied, the occurrence of flow pulsations is determined primarily by the surface properties of the granular material and the silo wall. The measurements show that the pulsating motion of the granular material drives the oscillatory motion of the silo.     

THE ROLE OF LATTICE OXYGEN IN THE DYNAMIC BEHAVIOR OF OXIDE CATALYSTS

The lattice of an oxide catalyst used for oxidation reactions can act as a reservoir for oxygen, storing and releasing it for reactions at the catalyst surface under appropriate conditions. The implication of this oxygen storage property of an oxide catalyst on its dynamic response characteristics has been investigated through an experimental study of 2-butene oxidation over vanadium oxide as a model reaction. Isothermal reaction rate measurements in a differential reactor and nonisothermal studies in a single pellet reactor have been carried out. Following a step increase in the feed butene concentration, isothermal reaction rate overshoot and pellet temperature overshoot were observed. These observations could be modelled in a qualitatively correct way by a very simple model accounting for the participation of lattice oxygen in the catalytic reactions under dynamic conditions. It is demonstrated through model simulations that the ignition characteristics of a catalyst pellet are significantly affected by the participation of the lattice oxygen, when steady state multiplicity is present.     

Zero-<Emphasis Type="Italic">trans</Emphasis> shortening using palm stearin and rice bran oil

Several pilot-scale trials reported in this paper, using palm stearin-rice bran oil (PS-RBO) blends, obviously did not contain trans FA (TFA), whereas the commercial products were found to contain 18–27% TFA. The effects of processing conditions such as rate of agitation, crystallization temperature, and composition of the blends on the crystal structure of shortenings were studied. The products were evaluated for their physicochemical characteristics using DSC, X-ray diffraction (XRD), HPLC, and FTIR techniques. The formulation containing 50% PS and 50% RBO showed melting and cooling characteristics similar to those of hydrogenated commercial “vanaspati” samples. Analysis of the FA composition revealed that the formulated shortenings contained 15–19% C_18∶2 PUFA. Tocopherol and tocotrienol contents of the experimental shortenings were in the range of 850–1000 ppm with oryzanol content up to 0.6%. XRD studies demonstrated that the crystal form in the shortenings was predominantly the most stable β′ form, and there was less of the undesirable β form.