Emerging privacy-preserving technologies help protect sensitive data during application executions. Recently, the secure two-party computing (TPC) scheme has demonstrated its potential, especially for the secure model inference of a deep learning application by protecting both the user input data and the model parameters. Nevertheless, existing TPC protocols incur excessive communications during the program execution, which lengthens the execution time. In this work, we propose the precomputing scheme, POPS, to address the problem, which is done by shifting the required communications from during the execution to the time prior to the execution. Particular, the multiplication triple generation is computed beforehand with POPS to remove the overhead at runtime. We have analyzed the TPC protocols to ensure that the precomputing scheme conforms the existing secure protocols. Our results show that POPS takes a step forward in the secure inference by delivering up to \(20\times \) and \(5\times \) speedups against the prior work for the microbenchmark and the convolutional neural network experiments, respectively.
Simple and eco-friendly electro deposition method was employed for the fabrication of Au–Ag bimetallic nanoparticles modified
glassy carbon electrode. Nano Au–Ag film modified glassy carbon electrode surface morphology has been examined using atomic
force microscopy. Electrodeposited Au–Ag bimetallic nanoparticles were found in the average size range of 15–50 nm. The electrochemical
investigations of nano Au–Ag/1-butyl-3-methylimidazolium tetrafluoroborate-nafion film have been carried out using cyclic
voltammetry and electrochemical impedance spectroscopy. The nano Au–Ag/1-butyl-3-methylimidazolium tetrafluoroborate-nafion
film modified glassy carbon electrode holds the good electrochemical behavior and stability in pH 7.0 phosphate buffer solutions.
The nano Au–Ag/1-butyl-3-methylimidazolium tetrafluoroborate-nafion modified glassy carbon electrode was successfully employed
for the detection of H2O2 in the linear range of 1–250 μM in lab samples, and 1 × 10−3–2 × 10−2 M in real samples, respectively. 相似文献
The present work describes the electrocatalytic behavior of phosphotungstate-doped glutaraldehyde-cross-linked poly-l-lysine (PLL-GA-PW) film electrode towards reduction of hydrogen peroxide (H2O2) in acidic medium. The modified electrode was prepared by means of electrostatically trapping the phosphotungstate anion into the cationic PLL-GA coating on glassy carbon electrode. The PLL-GA-PW film electrode showed excellent electrocatalytic activity towards H2O2 reduction in 0.1 M H2SO4. Under the optimized conditions, the electrochemical sensor exhibited a linear response for H2O2 concentration over the range 2.5 × 10−6 to 6.85 × 10−3 M with a sensitivity of 1.69 μA mM−1. The curvature in the calibration curve at high concentration is explained in terms of Michaelis-Menten (MM) saturation kinetics, and the kinetics parameters calculated by three different methods were compared. The PLL-GA-PW film electrode did not respond to potential interferents such as dopamine, ascorbic acid and uric acid. This unique feature of PLL-GA-PW film electrode allowed selective determination of H2O2. Finally, the proposed electrochemical sensor was successfully applied to determine H2O2 in commercially available antiseptic solution and soft-contact lenses cleaning solution and the method has been validated using independent estimation by classical potassium permanganate titration method. Major advantages of the method are simple electrode fabrication, stability and high selectivity towards hydrogen peroxide. 相似文献
Electrochemical deposition method was employed for the fabrication of rhodium–palladium (Rh–Pd) particles on the glassy carbon
electrode (GCE) and indium tin oxide (ITO) electrode surface. Surface morphological analysis of Rh–Pd film has been carried
out using scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Here, the electrodeposited Rh–Pd particles
were found in the average size range of 30–200 nm. The electrochemical activities of the Rh–Pd film have been investigated
using cyclic voltammetry (CV) and electrochemical impedance spectroscopic (EIS) analysis. The Rh–Pd particles-modified GCE
successfully detects the hydrogen peroxide (H2O2) (in pH 7.0 phosphate buffer solution (PBS)) in the linear range in the lab (10–460 μM) and real samples (10–340 μM). The
Rh–Pd particles-modified GCE possesses the good sensitivity and selectivity for the detection of H2O2 in lab and real samples. 相似文献
Two types of epinephrine and cyclized epinephrine quinone films have been prepared using cyclic voltammetry from the epinephrine in the strong acidic solutions and neutral aqueous solutions over different scanning potential ranges. The cyclic voltammogram of the epinephrine film is characterized by one redox couple at about +0.5 V (versus Ag|AgCl) and cyclized epinephrine quinone film exhibits one redox couples at about −0.15 V (versus Ag|AgCl) .In addition to cyclic voltammetry and an electrochemical quartz crystal microbalance (EQCM) were used to study the growth mechanism of the epinephrine and cyclized epinephrine quinone molecules. The electrocatalytic oxidation of catecholamines (dopamine and norepinephrine) and also ascorbic acid were investigated in acidic aqueous solutions using epinephrine films. The rotating ring-disk electrode technique was used to investigate the mechanism of electrochemical oxidation of dopamine and ascorbic acid. 相似文献
The fabrication of monolayers composed of nordihydroguaiaretic acid (NDGA), and hybrid films composed of NDGA-flavin adenine dinucleotide (FAD) adsorbed films was performed in neutral aqueous solutions to produce electrochemically active thin films exhibiting one and two redox couples, respectively. An electrochemical quartz crystal microbalance and cyclic voltammetry were used to study the in situ growth of the NDGA and hybrid NDGA/FAD film monolayers. The NDGA modified film electrocatalytically oxidized NADH, ascorbic acid, dopamine, and N2H4 in neutral aqueous solutions. Well-separated voltammetric peaks were observed for dopamine and uric acid mixtures, and also for ascorbic acid and uric acid mixtures using the NDGA/GC modified electrode. When transferred to various aqueous buffered solutions, the two redox couples of the NDGA/FAD hybrid film and their formal potentials were observed to be pH-dependent. The electrocatalytic oxidation and reduction of NADH and NAD+ by a NDGA/FAD hybrid film in neutral aqueous solutions was carried out, and the electrocatalytic oxidation of NADH was performed using a NDGA/FAD hybrid film. 相似文献
Au–Ag bimetallic nanoparticles have been fabricated by one-step simple electrochemical deposition method using ionic liquid
as green electrolyte (1-butyl-3-methylimidazolium tetrafluoro borate). Fabricated Au–Ag bimetallic nanoparticles have been
characterized using cyclic voltammetry (CV), FE-SEM, UV–vis spectroscopy, and X-ray diffraction (XRD) studies. The electrodeposited
Au–Ag bimetallic nanoparticles were found in the size range of 16–30 nm, respectively. This type of Au–Ag bimetallic nanoparticles
could be directly applied for the optoelectronic and biosensing applications. 相似文献
Electrochemical analysis of ascorbic acid (AsA) in physiological condition using a new hybrid film modified electrode is described. Electrochemical polymerization of luminol in 0.1 M H2SO4 solution was carried out using ZnO nanoparticles (ZnO-NPs) coated glassy carbon electrode (GCE) as working electrode. This hybrid film coated electrode noted as poly(luminol)/ZnO-NPs hybrid film modified GCE (PLu/ZnO-NPs/GCE). The atomic force microscope (AFM) and scanning electron microscope (SEM) studies were demonstrated that PLu/ZnO-NPs hybrid film covered the electrode surface and the ZnO-NPs particle sizes were <100 nm. The visible blue colored organic–inorganic (PLu/ZnO-NPs) hybrid films were observed on the electrode surface. Electrochemical studies proved that PLu/ZnO-NPs hybrid film modified electrode is electroactive in the pH range from 1 to 11 and the poly(luminol) (PLu) redox peak was pH dependent with a slope of ?53 mV/pH. The PLu/ZnO-NPs modified electrodes electroactivity also investigated by catalyzing the oxidation of AsA, demonstrating its great potential applications in electroanalysis of AsA. The resulting, AsA electrochemical sensor exhibited a wide linear response range (from 1 × 10?6 to 3.6 × 10?4 M, r2 = 0.9989), lower detection limit (1 × 10?6 M) and fast response time (3 s) for AsA determination. Our results show that PLu/ZnO-NPs hybrid film provides a novel and efficient platform for the oxidation of AsA and realizing efficient electrocatalysis and that the materials have potential applications in the fabrication of electrochemical sensors. Analysis of commercial vitamin C samples using PLu/ZnO-NPs hybrid film modified electrode was demonstrated and the obtained results are good agreement with the labeled amount. 相似文献
Searchable encryption (SE) is considered important as it provides both confidentiality and searchability for the data stored in semi-trusted environments such as cloud. However, it is rarely deployed because most SE schemes are not native to cloud services as they require database modifications. In this paper, we present an SE scheme called Frequency-Eliminated Trapdoor-Character Hopping (FETCH) that, based on novel common-conditioned-subsequence-preserving (CCSP) techniques, is able to work natively with off-the-shelf databases and supports wildcard-based pattern search on encrypted data thereof. In fact, with the CCSP techniques, we transform the problem of wildcard SE searching into a problem of subsequence searching, which is solved fast in most databases and thus fits well with cloud services in general. Although in our security analysis, CCSP removes the possibility of obtaining theoretical indistinguishability between indexed items, we show that FETCH does provide adequate confidentiality protection and fares much better than other existing wildcard SE schemes in terms of query performance, storage overhead, and deployment complexity. In particular, FETCH is able to efficiently handle data sets whose size is multiple orders of magnitude larger than those that existing schemes can comfortably support. 相似文献